Award Abstract # 2407264
Isotopic fractionation between gaseous and dissolved Carbon in silicate melts; assessing the C content and d13C signature of Earth's Upper Mantle

NSF Org: EAR
Division Of Earth Sciences
Recipient: THE TRUSTEES OF COLUMBIA UNIVERSITY IN THE CITY OF NEW YORK
Initial Amendment Date: November 22, 2024
Latest Amendment Date: November 22, 2024
Award Number: 2407264
Award Instrument: Standard Grant
Program Manager: Jennifer Wade
jwade@nsf.gov
 (703)292-4739
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: December 1, 2024
End Date: November 30, 2026 (Estimated)
Total Intended Award Amount: $281,066.00
Total Awarded Amount to Date: $281,066.00
Funds Obligated to Date: FY 2025 = $281,066.00
History of Investigator:
  • Yves Moussallam (Principal Investigator)
    yves.moussallam@ldeo.columbia.edu
Recipient Sponsored Research Office: Columbia University
615 W 131ST ST
NEW YORK
NY  US  10027-7922
(212)854-6851
Sponsor Congressional District: 13
Primary Place of Performance: Columbia University
61 Route 9W
Palisades
NY  US  10964-1707
Primary Place of Performance
Congressional District:
17
Unique Entity Identifier (UEI): F4N1QNPB95M4
Parent UEI:
NSF Program(s): CESEV-Chem Evo of Earth & Volc
Primary Program Source: 01002526DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s):
Program Element Code(s): 330Y00
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Understanding the Earth's interior remains a top research priority in the geosciences. How much carbon is in the Earth's mantle, how much goes in and how much comes out - these questions remain unanswered despite decades of dedicated research. Yet the answers to these questions have profound implications for how the Earth's interior must function and how our planet has evolved over geological time. This project aims to precisely quantify the carbon content and its isotopic signature (?13C) in the upper mantle to constrain how much of the Earth's carbon is contained in the upper mantle and in which regions of the mantle it accumulates. This research will not only advance our fundamental knowledge of Earth's interior but also support education by training a graduate student in state-of-the-art experimental and analytical techniques.

The project seeks to determine the carbon content and ?13C signature of the upper mantle through a two-pronged approach. First, the researchers will experimentally determine the mass-dependent isotopic fractionation of carbon during the degassing of silicate melts. High-pressure/high-temperature experiments will be conducted using internally heated pressure vessels and piston-cylinder apparatuses to simulate conditions in the upper mantle. These experiments will measure the isotopic fractionation coefficients (?) as a function of melt composition, temperature, and pressure. Second, the team will directly measure ?13C in deep mantle melts using melt inclusions from volcanoes such as Etna, Erebus, and El Hierro. By combining experimental data with natural observations, the researchers will back-calculate the original carbon content and isotopic signature of the mantle. The project will utilize recent advances in secondary ion mass spectrometry. The results will provide a comprehensive understanding of the carbon cycle in the upper mantle, contributing to our knowledge of Earth's deep carbon reservoirs and their impact on global geodynamics.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

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