Award Abstract # 2341653
Collaborative Research: GEO-CM: Rare earth element and yttrium extraction by biotic and abiotic hydrous manganese oxides associated with acidic mine drainage

NSF Org: EAR
Division Of Earth Sciences
Recipient: THE WASHINGTON AND LEE UNIVERSITY
Initial Amendment Date: August 1, 2024
Latest Amendment Date: August 1, 2024
Award Number: 2341653
Award Instrument: Standard Grant
Program Manager: Jonathan G Wynn
jwynn@nsf.gov
 (703)292-4725
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: August 15, 2024
End Date: July 31, 2027 (Estimated)
Total Intended Award Amount: $180,189.00
Total Awarded Amount to Date: $180,189.00
Funds Obligated to Date: FY 2024 = $180,189.00
History of Investigator:
  • Margaret Hinkle (Principal Investigator)
    hinklem@wlu.edu
Recipient Sponsored Research Office: Washington and Lee University
204 W WASHINGTON ST
LEXINGTON
VA  US  24450-2116
(540)458-8274
Sponsor Congressional District: 06
Primary Place of Performance: Washington and Lee University
204 W WASHINGTON ST
LEXINGTON
VA  US  24450-2116
Primary Place of Performance
Congressional District:
06
Unique Entity Identifier (UEI): MSVHQKG44VN5
Parent UEI:
NSF Program(s): XC-Crosscutting Activities Pro,
Geobiology & Low-Temp Geochem
Primary Program Source: 01002425DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 136Z
Program Element Code(s): 722200, 729500
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

With the projected growth in renewable energy and technology sectors along with their increasing reliance on critical minerals such as rare earth elements, yttrium, and manganese, identifying domestic sources of these critical minerals is essential. Large volumes of solid waste containing critical minerals are generated every year as a byproduct of acid mine drainage remediation. Within the United States, acid mine drainage remains an ongoing environmental issue. This research will examine the potential of adapting acid mine drainage remediation systems to produce critical minerals in economically viable concentrations. The research will support STEM education initiatives by providing training in the field and lab at both undergraduate and graduate levels, as well as hands-on activities in multiple introductory geoscience courses. This work will contribute to developing a more knowledgeable STEM workforce and a more efficient, economical, and environmentally sustainable approach for critical mineral recovery from unconventional domestic sources.

The research will investigate the impact of a variety of biogeochemical conditions (such as pH, sulfate concentrations, and the presence of microbes) on rare earth elements and yttrium (REYs) uptake by hydrous manganese (Mn) oxide minerals in acid mine drainage remediation systems. With research comprising both laboratory and field experiments, the results will provide a comprehensive understanding of REY-hydrous Mn oxide mineral interactions. Multiple microcharacterization techniques (including advanced spectroscopic techniques such as synchrotron-based X-ray absorption spectroscopy) along with sequential extractions will provide a comprehensive understanding of REY sorption behaviors and mobilization. These results will help identify the optimal conditions for concentrating REYs in acid mine drainage remediation systems for the recovery of these critical minerals from unconventional domestic sources, while remediating harmful metal-laden acid mine drainage.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

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