Award Abstract # 2334731
Effect of Condensed-Phase Photochemistry on Absorption Coefficients and Phase State of Atmospheric Organic Aerosol Particles

NSF Org: AGS
Division of Atmospheric and Geospace Sciences
Recipient: UNIVERSITY OF CALIFORNIA IRVINE
Initial Amendment Date: January 26, 2024
Latest Amendment Date: January 26, 2024
Award Number: 2334731
Award Instrument: Standard Grant
Program Manager: Sylvia Edgerton
sedgerto@nsf.gov
 (703)292-8522
AGS
 Division of Atmospheric and Geospace Sciences
GEO
 Directorate for Geosciences
Start Date: February 15, 2024
End Date: January 31, 2027 (Estimated)
Total Intended Award Amount: $797,203.00
Total Awarded Amount to Date: $797,203.00
Funds Obligated to Date: FY 2024 = $797,203.00
History of Investigator:
  • Sergey Nizkorodov (Principal Investigator)
    nizkorod@uci.edu
Recipient Sponsored Research Office: University of California-Irvine
160 ALDRICH HALL
IRVINE
CA  US  92697-0001
(949)824-7295
Sponsor Congressional District: 47
Primary Place of Performance: University of California-Irvine
1102 Natural Sciences II
IRVINE
CA  US  92697-2025
Primary Place of Performance
Congressional District:
47
Unique Entity Identifier (UEI): MJC5FCYQTPE6
Parent UEI: MJC5FCYQTPE6
NSF Program(s): Atmospheric Chemistry
Primary Program Source: 01002425DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s):
Program Element Code(s): 152400
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

The goal of this project is to better understand how photochemical reactions in the solid or liquid phase of organic compounds affect the key properties of organic aerosol in the atmosphere. The focus of this project is on secondary organic aerosol and/or biomass burning organic aerosol. This research is important to improve the modeling of photochemical reactions that occur inside atmospheric organic particles and cloud droplets containing dissolved organics. The results of this project will improve the understanding of how organic particles contribute to radiative forcing on climate both directly and indirectly and provide valuable information relevant to predicting the health effects of aged organic particulate matter in the urban environment.

The main objectives of this proposal are to: (1) compare mechanisms of photochemical processes for secondary organic aerosol (SOA) and biomass burning organic aerosol (BBOA) compounds in different matrices representative of the dilute aqueous environment found in cloud droplets, the concentrated aqueous environment in aerosol liquid water, and the organic phase of particles; (2) assess the relative importance of direct and indirect photochemical processes in irradiated SOA and BBOA; and (3) examine the effect of condensed-phase photochemical processes on absorption coefficients, viscosity and the phase behavior of SOA and BBOA materials. The project will be conducted through experiments carried out in a smog chamber or an oxidation flow reactor.

This effort will directly support the training of at least two graduate students and six undergraduate students. The results of this project will be disseminated through research meetings, peer-reviewed publications, the internet, and public media sources.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Dalton, Avery_B and Wingen, Lisa_M and Nizkorodov, Sergey_A "Isomeric Identification of the Nitroindole Chromophore in Indole + NO 3 Organic Aerosol" ACS Physical Chemistry Au , v.4 , 2024 https://doi.org/10.1021/acsphyschemau.4c00044 Citation Details
Liu, Sijia and Galeazzo, Tommaso and Valorso, Richard and Shiraiwa, Manabu and Faiola, Celia_L and Nizkorodov, Sergey_A "Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d -Limonene and -Myrcene" Environmental Science & Technology , 2024 https://doi.org/10.1021/acs.est.4c04870 Citation Details
Wong, Cynthia and Vuong, Jett and Nizkorodov, Sergey_A "Biogenic and Anthropogenic Secondary Organic Aerosols Become Fluorescent after Highly Acidic Aging" The Journal of Physical Chemistry A , v.128 , 2024 https://doi.org/10.1021/acs.jpca.4c04287 Citation Details

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