Award Abstract # 2206655
Evolution in Secondary Organic Aerosol Formation in Urban Atmosphere

NSF Org: AGS
Division of Atmospheric and Geospace Sciences
Recipient: THE REGENTS OF THE UNIVERSITY OF COLORADO
Initial Amendment Date: June 14, 2022
Latest Amendment Date: June 14, 2022
Award Number: 2206655
Award Instrument: Standard Grant
Program Manager: Sylvia Edgerton
sedgerto@nsf.gov
 (703)292-8522
AGS
 Division of Atmospheric and Geospace Sciences
GEO
 Directorate for Geosciences
Start Date: July 15, 2022
End Date: June 30, 2026 (Estimated)
Total Intended Award Amount: $941,275.00
Total Awarded Amount to Date: $941,275.00
Funds Obligated to Date: FY 2022 = $941,275.00
History of Investigator:
  • Joost de Gouw (Principal Investigator)
    joost.degouw@colorado.edu
  • Jose Jimenez (Co-Principal Investigator)
Recipient Sponsored Research Office: University of Colorado at Boulder
3100 MARINE ST
Boulder
CO  US  80309-0001
(303)492-6221
Sponsor Congressional District: 02
Primary Place of Performance: University of Colorado at Boulder
CO  US  80303-1058
Primary Place of Performance
Congressional District:
02
Unique Entity Identifier (UEI): SPVKK1RC2MZ3
Parent UEI:
NSF Program(s): Atmospheric Chemistry
Primary Program Source: 01002223DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 102Z
Program Element Code(s): 152400
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

This project is focused on an investigation of the atmospheric chemistry processes that lead to the formation of secondary organic aerosol (SOA) in the urban atmosphere. The research will address the key precursors or gases that lead to the formation of SOA and their sources and volatility ranges. The information developed will help to predict the evolution of urban SOA that leads to air pollution and the design of effective mitigation strategies.

The science questions that will be addressed are: (1) What are the most important SOA precursors in urban air? (2) What are the sources of the most important SOA precursors? (3) What are the SOA formation pathways for the most important precursors? (4) Has SOA chemistry changed over the past decade? and (5) Can the description of urban SOA in chemistry-transport models be improved?

A 6-week field campaign will be conducted in the Los Angeles area in Summer 2022. Comparison of the data with previous studies, including the CalNex study in 2010, will show how the SOA precursors and chemistry have evolved over the last decade. The project includes training for several graduate and undergraduate students.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Chen, Wei and Hu, Weiwei and Tao, Zi and Cai, Yiyu and Cai, Mingfu and Zhu, Ming and Ye, Yuqing and Zhou, Huaishan and Jiang, Hongxing and Li, Jun and Song, Wei and Zhou, Jiayi and Huang, Shan and Yuan, Bin and Shao, Min and Feng, Qiandan and Li, Ying and "Quantitative Characterization of the Volatility Distribution of Organic Aerosols in a Polluted Urban Area: Intercomparison Between Thermodenuder and Molecular Measurements" Journal of Geophysical Research: Atmospheres , v.129 , 2024 https://doi.org/10.1029/2023JD040284 Citation Details
Franklin, Emily B and Yee, Lindsay D and Wernis, Rebecca and Isaacman-VanWertz, Gabriel and Kreisberg, Nathan and Weber, Robert and Zhang, Haofei and Palm, Brett B and Hu, Weiwei and Campuzano-Jost, Pedro and Day, Douglas A and Manzi, Antonio and Artaxo, "Chemical Signatures of Seasonally Unique Anthropogenic Influences on Organic Aerosol Composition in the Central Amazon" Environmental Science & Technology , v.57 , 2023 https://doi.org/10.1021/acs.est.2c07260 Citation Details
Jensen, Andrew R and Koss, Abigail R and Hales, Ryder B and de_Gouw, Joost A "Measurements of volatile organic compounds in ambient air by gas-chromatography and real-time Vocus PTR-TOF-MS: calibrations, instrument background corrections, and introducing a PTR Data Toolkit" Atmospheric Measurement Techniques , v.16 , 2023 https://doi.org/10.5194/amt-16-5261-2023 Citation Details
Jensen, A R and Morris, M A and Schulze, B C and Bradley, A C and Anderson, L D and Jenks, O J and Dresser, W D and Ball, K and Ward, R X and Day, D A and Crounse, J D and Meinardi, S and Barletta, B and Blake, D R and Seinfeld, J H and Wennberg, P O and "Emissions and Chemistry of Volatile Organic Compounds in the Los Angeles Basin in Summer 2022" Journal of Geophysical Research: Atmospheres , v.129 , 2024 https://doi.org/10.1029/2024JD041812 Citation Details
Jeon, Sohyeon and Walker, Michael J and Sueper, Donna T and Day, Douglas A and Handschy, Anne V and Jimenez, Jose L and Williams, Brent J "A searchable database and mass spectral comparison tool for the Aerosol Mass Spectrometer (AMS) and the Aerosol Chemical Speciation Monitor (ACSM)" Atmospheric Measurement Techniques , v.16 , 2023 https://doi.org/10.5194/amt-16-6075-2023 Citation Details
Jo, Duseong S and Nault, Benjamin A and Tilmes, Simone and Gettelman, Andrew and McCluskey, Christina S and Hodzic, Alma and Henze, Daven K and Nawaz, Muhammad Omar and Fung, Ka Ming and Jimenez, Jose L "Global Health and Climate Effects of Organic Aerosols from Different Sources" Environmental Science & Technology , v.57 , 2023 https://doi.org/10.1021/acs.est.3c02823 Citation Details
Morris, Melissa A and Pagonis, Demetrios and Day, Douglas A and de_Gouw, Joost A and Ziemann, Paul J and Jimenez, Jose L "Absorption of volatile organic compounds (VOCs) by polymer tubing: implications for indoor air and use as a simple gas-phase volatility separation technique" Atmospheric Measurement Techniques , v.17 , 2024 https://doi.org/10.5194/amt-17-1545-2024 Citation Details
Schueneman, Melinda K and Day, Douglas A and Kim, Dongwook and Campuzano-Jost, Pedro and Yun, Seonsik and DeVault, Marla P and Ziola, Anna C and Ziemann, Paul J and Jimenez, Jose L "A multi-instrumental approach for calibrating real-time mass spectrometers using high-performance liquid chromatography and positive matrix factorization" Aerosol Research , v.2 , 2024 https://doi.org/10.5194/ar-2-59-2024 Citation Details
Chen, Tianshu and Gilman, Jessica and Kim, SiWan and Lefer, Barry and Washenfelder, Rebecca and Young, Cora J and Rappenglueck, Bernhard and Stevens, Philip S and Veres, Patrick R and Xue, Likun and de_Gouw, Joost "Modeling the Impacts of Volatile Chemical Product Emissions on Atmospheric Photochemistry and Ozone Formation in Los Angeles" Journal of Geophysical Research: Atmospheres , v.129 , 2024 https://doi.org/10.1029/2024JD040743 Citation Details
Brewer, J F and Jacob, D J and Jathar, S H and He, Y and Akherati, A and Zhai, S and Jo, D S and Hodzic, A and Nault, B A and CampuzanoJost, P and Jimenez, J L and Park, R J and Oak, Y J and Liao, H "A Scheme for Representing Aromatic Secondary Organic Aerosols in Chemical Transport Models: Application to Source Attribution of Organic Aerosols Over South Korea During the KORUSAQ Campaign" Journal of Geophysical Research: Atmospheres , v.128 , 2023 https://doi.org/10.1029/2022JD037257 Citation Details

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