Award Abstract # 2045277
CAREER: Integrating geology and metallurgy for efficient, sustainable production of critical elements for the green economy

NSF Org: EAR
Division Of Earth Sciences
Recipient: UNIVERSITY OF ARIZONA
Initial Amendment Date: February 8, 2021
Latest Amendment Date: August 25, 2024
Award Number: 2045277
Award Instrument: Continuing Grant
Program Manager: Jennifer Wade
jwade@nsf.gov
 (703)292-4739
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: June 1, 2021
End Date: May 31, 2026 (Estimated)
Total Intended Award Amount: $506,875.00
Total Awarded Amount to Date: $506,875.00
Funds Obligated to Date: FY 2021 = $349,100.00
FY 2024 = $157,775.00
History of Investigator:
  • Isabel Barton (Principal Investigator)
    fay1@email.arizona.edu
Recipient Sponsored Research Office: University of Arizona
845 N PARK AVE RM 538
TUCSON
AZ  US  85721
(520)626-6000
Sponsor Congressional District: 07
Primary Place of Performance: University of Arizona
888 N Euclid Ave
Tucson
AZ  US  85719-4824
Primary Place of Performance
Congressional District:
07
Unique Entity Identifier (UEI): ED44Y3W6P7B9
Parent UEI:
NSF Program(s): Petrology and Geochemistry,
XC-Crosscutting Activities Pro,
EnvS-Environmtl Sustainability
Primary Program Source: 01002122DB NSF RESEARCH & RELATED ACTIVIT
01002425DB NSF RESEARCH & RELATED ACTIVIT

01002526DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 1045
Program Element Code(s): 157300, 722200, 764300
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

The transition to a sustainable, low-carbon economy depends on viable long-term supplies of energy metals such as uranium, vanadium, copper, and cobalt. However, producing these metals from domestic sources is becoming more difficult as easy-to-mine deposits are exhausted; what remains are lower-grade ores with complex mineralogy. Current extractive processes are designed for simpler ores and are inefficient, sometimes ineffective, with the more complicated remaining resources. This project will instead develop a geometallurgical approach to mining and extracting energy metals and other critical elements. This consists of tailoring extractive processes to the detailed mineralogy and composition of individual ore zones, enabling more efficient extraction of energy metals and less mine waste. This will help to maintain a sustainable supply of the metals that support low-carbon energy in the future. Ancillary benefits from this project include an education and outreach program that will broaden engagement with mineral resources topics among teachers and the public.


This project will integrate geological data and metallurgical experiments to develop tailored geometallurgical approaches to the extraction of critical energy metals, starting with uranium, vanadium, and cobalt. These metals are vital to low-carbon energy generation and the green economy, but their supply is threatened by low ore deposit grades, complex mineralogy, and gaps in the understanding of how mineral properties control metallurgical behavior. Research will begin with detailed characterization of ore properties and ore mineral distribution in the globally important sediment-hosted ores of U, V, and Co. A series of leaching experiments will illuminate the connections between ore mineral properties (crystallinity, composition) and fluid-mineral reactions, enabling optimized extraction design. The initial results will be used to develop geometallurgical models of optimized extraction parameters for ore zones in the Colorado Plateau U and V deposits, where this approach will be tested. This will reset the traditional paradigm, which compartmentalizes geological from metallurgical insights, and will provide a model for extension to other critical mineral resources worldwide.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Barton, Isabel "Paradox Basin Uranium-Vanadium Deposits: History and Significance of Geological Research" Mining, Metallurgy & Exploration , v.41 , 2024 https://doi.org/10.1007/s42461-024-01025-y Citation Details
Barton, Isabel and Barton, Mark "Paradox Basin Uranium-Vanadium Deposits: Comparative Mineralogy and Paragenesis" Mining, Metallurgy & Exploration , v.41 , 2024 https://doi.org/10.1007/s42461-024-01128-6 Citation Details
Barton, Isabel and Drexler, Maxwell and Radwany, Molly and Zanetta, Pierre-Marie "Leaching metals from phyllosilicate ores" Proceedings of Hydrometallurgy 2023 , 2023 Citation Details
Barton, Isabel F and North, Robert M "Geometallurgy of the Tenke-Fungurume sediment-hosted copper-cobalt district, D.R. Congo" Minerals Engineering , v.218 , 2024 https://doi.org/10.1016/j.mineng.2024.108993 Citation Details
Drexler, Maxwell and Barton, Isabel and Zanetta, Pierre-Marie "Vanadium in phyllosilicate ores: Occurrence, crystal chemistry, and leaching behavior" Minerals Engineering , 2023 https://doi.org/10.1016/j.mineng.2023.108205 Citation Details
Radwany, Molly R. and Barton, Isabel F. "The process mineralogy of leaching sandstone-hosted uranium-vanadium ores" Minerals Engineering , v.187 , 2022 https://doi.org/10.1016/j.mineng.2022.107811 Citation Details
Zanetta, Pierre-Marie and Drexler, Maxwell S and Barton, Isabel F and Zega, Thomas J "Vanadium Electronic Configuration Determination From L2,3 Transition in V-oxide Compounds and Roscoelite" Microscopy and Microanalysis , v.29 , 2023 https://doi.org/10.1093/micmic/ozac057 Citation Details

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