Award Abstract # 2041979
Collaborative Research: Atmospheric Formation and Implications of Secondary Organic Aerosol from Glycols and Glycol Ethers

NSF Org: AGS
Division of Atmospheric and Geospace Sciences
Recipient: COLORADO STATE UNIVERSITY
Initial Amendment Date: April 1, 2021
Latest Amendment Date: May 17, 2024
Award Number: 2041979
Award Instrument: Standard Grant
Program Manager: Sylvia Edgerton
sedgerto@nsf.gov
 (703)292-8522
AGS
 Division of Atmospheric and Geospace Sciences
GEO
 Directorate for Geosciences
Start Date: May 1, 2021
End Date: April 30, 2026 (Estimated)
Total Intended Award Amount: $526,946.00
Total Awarded Amount to Date: $588,507.00
Funds Obligated to Date: FY 2021 = $534,774.00
FY 2024 = $53,733.00
History of Investigator:
  • Shantanu Jathar (Principal Investigator)
    shantanu.jathar@colostate.edu
  • Delphine Farmer (Co-Principal Investigator)
Recipient Sponsored Research Office: Colorado State University
601 S HOWES ST
FORT COLLINS
CO  US  80521-2807
(970)491-6355
Sponsor Congressional District: 02
Primary Place of Performance: Colorado State University
200 W. Lake St.
Fort Collins
CO  US  80521-4593
Primary Place of Performance
Congressional District:
02
Unique Entity Identifier (UEI): LT9CXX8L19G1
Parent UEI:
NSF Program(s): SPECIAL EMPHASIS PROGRAM,
Atmospheric Chemistry
Primary Program Source: 01002122DB NSF RESEARCH & RELATED ACTIVIT
01002425DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 019Z, 4444, 1524, 5935
Program Element Code(s): 061900, 152400
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

The goal of this research is to improve the representation of volatile chemical products (VCPs) within models that predict the formation and transport of fine particles in the atmosphere. The use of VCPs such as consumer products, pesticides, paints, and surface coatings can result in the emissions of volatile organic compounds (VOC) that lead to the formation of ozone and secondary organic aerosol (SOA). The results of this research will provide policymakers with better information to make informed decisions to mitigate the air quality, climate, and human health impacts from aerosols.

In this project, the PIs plan to perform chamber experiments to comprehensively characterize the gas- and particle-phase oxidation products from the photochemical oxidation of glycols and glycol ethers. This research will advance knowledge about the fate of VCPs in the atmosphere and help to: (1) understand the role of carbon number, molecular structure, and NOx on atmospherically relevant formation of SOA from glycols and glycol ethers; (2) elucidate the composition and formation pathways for gas- and particle-phase products from photooxidation of glycols and glycol ethers; (3) determine the chemical mechanisms and parameterizations needed to represent SOA and ozone formation from VCPs in atmospheric models; and (4) identify the contribution and influence of VCP emissions on the SOA and oxidant burden in the urban atmosphere using a chemical transport model (WRF-Chem).

Scientists in this project will partner with the Outreach and Education Center at Colorado State University to develop and share hands-on STEM kits for educators and middle school students to learn about atmospheric chemistry.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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He, Yicong and Bilsback, Kelsey R and Shrivastava, Manish and Zaveri, Rahul A and Shilling, John E and Seinfeld, John H and Zhao, Bin and Wang, Shuxiao and Cappa, Christopher D and Pierce, Jeffrey R and Jathar, Shantanu H "Kinetic Modeling of Secondary Organic Aerosol in a Weather-Chemistry Model: Parameterizations, Processes, and Predictions for GOAmazon" ACS ES&T Air , v.2 , 2025 https://doi.org/10.1021/acsestair.4c00240 Citation Details

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