Award Abstract # 2029730
Collaborative Research: Formation of Sulfur Aerosols in Fairbanks, Alaska

NSF Org: AGS
Division of Atmospheric and Geospace Sciences
Recipient: GEORGIA TECH RESEARCH CORP
Initial Amendment Date: November 3, 2020
Latest Amendment Date: November 3, 2020
Award Number: 2029730
Award Instrument: Standard Grant
Program Manager: Sylvia Edgerton
sedgerto@nsf.gov
 (703)292-8522
AGS
 Division of Atmospheric and Geospace Sciences
GEO
 Directorate for Geosciences
Start Date: November 15, 2020
End Date: October 31, 2025 (Estimated)
Total Intended Award Amount: $411,945.00
Total Awarded Amount to Date: $411,945.00
Funds Obligated to Date: FY 2021 = $411,945.00
History of Investigator:
  • Rodney Weber (Principal Investigator)
    rweber@eas.gatech.edu
Recipient Sponsored Research Office: Georgia Tech Research Corporation
926 DALNEY ST NW
ATLANTA
GA  US  30318-6395
(404)894-4819
Sponsor Congressional District: 05
Primary Place of Performance: Georgia Institute of Technology
225 North Avenue
Atlanta
GA  US  30332-0002
Primary Place of Performance
Congressional District:
05
Unique Entity Identifier (UEI): EMW9FC8J3HN4
Parent UEI: EMW9FC8J3HN4
NSF Program(s): Atmospheric Chemistry
Primary Program Source: 01002122DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s):
Program Element Code(s): 152400
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

This project is part of the broader effort, the Alaskan Layered Pollution and Chemical Analysis (ALPACA) research initiative and will also contribute to the NSF-funded SNAP-TEC (Sustainably Navigating Arctic Pollution through Engaging Communities) project that includes an intensive field campaign planned for the year 2022. The goal of ALPACA is to better understand the chemical processing of air pollution during the cold and dark conditions in the wintertime in the Arctic. The objectives of SNAP-TEC are to improve the understanding of wintertime Arctic outdoor and indoor air pollution to assist in the sustainable development of the Arctic and improve air quality for Arctic peoples. Data from this project will become available to the public and other investigators who will be able to utilize it in assessing how to mitigate poor air quality in the wintertime in the Arctic.

Additional instrumentation will be deployed to improve the understanding of sulfur oxidation chemistry in the understudied high-latitude environment in Fairbanks, that is greatly impacted by both climate change and poor air quality. The PIs will investigate the formation routes and properties of hydroxymethane sulfonate (HMS) (HOCH2SO3-) in the atmosphere of Fairbanks. The PIs plan to collect online measurements of formaldehyde (HCHO) and PM2.5 inorganic sulfate and HMS with a PILS-IC (Particle-Into-Liquid Sampler coupled to an Ion Chromatograph). Measurements of gas and particle inorganic species that affect particle water and pH also will be measured, since HMS is formed through aqueous phase reactions that are sensitive to particle pH. Steady-state box model simulations will be conducted utilizing the data generated to examine the main chemical drivers of HMS formation in Fairbanks winter. This effort will examine the sensitivity of HMS formation to ambient HCHO and SO2 concentrations, meteorological conditions, aerosol liquid water, particle pH, and ionic strength.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Campbell, James R and Jr, Michael Battaglia and Dingilian, Kayane K and Cesler-Maloney, Meeta and Simpson, William R and Robinson, Ellis S and DeCarlo, Peter F and Temime-Roussel, Brice and DAnna, Barbara and Holen, Andrew L and Wu, Judy and Pratt, Kerri "Enhanced aqueous formation and neutralization of fine atmospheric particles driven by extreme cold" Science Advances , v.10 , 2024 https://doi.org/10.1126/sciadv.ado4373 Citation Details
Dingilian, Kayane and Hebert, Elliana and Battaglia, Jr., Michael and Campbell, James_R and Cesler-Maloney, Meeta and Simpson, William and St_Clair, Jason_M and Dibb, Jack and Temime-Roussel, Brice and DAnna, Barbara and Moon, Allison and Alexander, Beck "Hydroxymethanesulfonate and Sulfur(IV) in Fairbanks Winter During the ALPACA Study" ACS ES&T Air , v.1 , 2024 https://doi.org/10.1021/acsestair.4c00012 Citation Details
Moon, Allison and Jongebloed, Ursula and Dingilian, Kayane_K and Schauer, Andrew_J and Chan, Yuk-Chun and Cesler-Maloney, Meeta and Simpson, William_R and Weber, Rodney_J and Tsiang, Ling and Yazbeck, Fouad and Zhai, Shuting and Wedum, Alanna and Turner, "Primary Sulfate Is the Dominant Source of Particulate Sulfate during Winter in Fairbanks, Alaska" ACS ES&T Air , v.1 , 2023 https://doi.org/10.1021/acsestair.3c00023 Citation Details
Robinson, Ellis S and Battaglia_Jr, Michael and Campbell, James R and Cesler-Maloney, Meeta and Simpson, William and Mao, Jingqiu and Weber, Rodney J and DeCarlo, Peter F "Multi-year, high-time resolution aerosol chemical composition and mass measurements from Fairbanks, Alaska" Environmental Science: Atmospheres , v.4 , 2024 https://doi.org/10.1039/D4EA00008K Citation Details
Simpson, William R. and Mao, Jingqiu and Fochesatto, Gilberto J. and Law, Kathy S. and DeCarlo, Peter F. and Schmale, Julia and Pratt, Kerri A. and Arnold, Steve R. and Stutz, Jochen and Dibb, Jack E. and Creamean, Jessie M. and Weber, Rodney J. and Willi "Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment" ACS ES&T Air , v.1 , 2024 https://doi.org/10.1021/acsestair.3c00076 Citation Details
Yang, Yuhan and Battaglia, Michael A. and Mohan, Magesh Kumaran and Robinson, Ellis S. and DeCarlo, Peter F. and Edwards, Kasey C. and Fang, Ting and Kapur, Sukriti and Shiraiwa, Manabu and Cesler-Maloney, Meeta and Simpson, William R. and Campbell, James "Assessing the Oxidative Potential of Outdoor PM 2.5 in Wintertime Fairbanks, Alaska" ACS ES&T Air , v.1 , 2024 https://doi.org/10.1021/acsestair.3c00066 Citation Details
Yang, Yuhan and Battaglia, Michael A. and Robinson, Ellis S. and DeCarlo, Peter F. and Edwards, Kasey C. and Fang, Ting and Kapur, Sukriti and Shiraiwa, Manabu and Cesler-Maloney, Meeta and Simpson, William R. and Campbell, James R. and Nenes, Athanasios "IndoorOutdoor Oxidative Potential of PM 2.5 in Wintertime Fairbanks, Alaska: Impact of Air Infiltration and Indoor Activities" ACS ES&T Air , v.1 , 2024 https://doi.org/10.1021/acsestair.3c00067 Citation Details

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