Award Abstract # 2025965
SBIR Phase II: Durable Superhydrophobic Smart Coating with Active Corrosion Protection

NSF Org: TI
Translational Impacts
Recipient: SYNMATTER LLC
Initial Amendment Date: September 2, 2020
Latest Amendment Date: July 6, 2023
Award Number: 2025965
Award Instrument: Cooperative Agreement
Program Manager: Benaiah Schrag
bschrag@nsf.gov
 (703)292-8323
TI
 Translational Impacts
TIP
 Directorate for Technology, Innovation, and Partnerships
Start Date: September 1, 2020
End Date: August 31, 2024 (Estimated)
Total Intended Award Amount: $991,881.00
Total Awarded Amount to Date: $991,881.00
Funds Obligated to Date: FY 2020 = $991,881.00
History of Investigator:
  • Xuejun Zhang (Principal Investigator)
    Jun@SynMatter.co
Recipient Sponsored Research Office: SynMatter, LLC
16914 DEER OAK LN
ORLANDO
FL  US  32828-6979
(321)947-6478
Sponsor Congressional District: 10
Primary Place of Performance: SynMatter, LLC
505 Odyssey Way
Merritt Island
FL  US  32953-8702
Primary Place of Performance
Congressional District:
08
Unique Entity Identifier (UEI): L4EBZEFG6AB4
Parent UEI: L4EBZEFG6AB4
NSF Program(s): SBIR Phase II
Primary Program Source: 01002021DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 123E, 5187, 8021
Program Element Code(s): 537300
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.084

ABSTRACT

The broader impact/commercial potential of this Small Business Innovation Research (SBIR) Phase II project is to dramatically improve the corrosion protection of metal assets vital to the energy and transportation industries. Corrosion contributes to the loss of structural integrity of metal structures, which poses a risk to human safety and the surrounding environment. Metal corrosion costs an estimated $2.5 T globally, with US costs representing roughly 25%. Durable, anticorrosive, highly water-repellent coatings using special materials can potentially double the lifetime of coatings on oil platforms and ships in a way that protects the environment. This extends maintenance cycles and reduces asset lifetime maintenance costs up to 50%. The high performance will also reduce the number of coating layers, reducing labor costs up to 25% per maintenance cycle. This technology will improve structural safety, reduce maintenance frequency, lengthen the operating lifetimes, improve environmental characteristics, and reduce the costs of operating and maintaining metal assets.

This Small Business Innovation Research Phase II project further translates coatings of superhydrophobic smart particles for high-performance anticorrosion paints. These superhydrophobic particles offer new on-demand release of corrosion inhibitors (active corrosion protection) and superhydrophobicity (passive corrosion protection) into one multi-functional material, unlike current state of practice. The platform nature of the technology enables inclusion of numerous types of corrosion inhibitors to safeguard delicate marine environments. Smart particles can then be incorporated into many existing coating systems to deliver a unique combination of durable, anticorrosive, and highly water-repellent coatings. This project will optimize production processes and conduct verification and validation tests.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

Metal corrosion costs the world approximately $2.5T (2016) every year, with the US alone spending around $635B (2018) annually to deal with the problem, a figure that doubles when including indirect costs. Corrosion also contributes to the loss of structural integrity of metal structures, which poses a risk to human safety and the surrounding environment. Protective coatings provide the first line of defense against the deleterious effects of corrosion. However, current solutions do not last long enough, especially in highly corrosive environments. Coating performance can be enhanced by incorporation of corrosion inhibitors. Current corrosion inhibitors are based on heavy metals, most notably chromates and zinc compounds, which are highly hazardous to humans and the environment and subject to ever more stringent regulations.

SynMatter, a minority, woman-owned small business, has invented, Smart Particles, a completely new class of environmentally benign, smart corrosion inhibitors, that deliver high anticorrosion performance to protective coatings. With the support of NSF Small Business Innovation Research funding, the company was able to substantially derisk the technology, demonstrate its commercial viability and show the high levels of corrosion protection performance that can be achieved.

This involved optimizing the synthesis, which lowered production costs by at least 25%. This optimized method was scaled ten-fold, demonstrating commercial production readiness. The company developed extensive expertise in incorporating Smart Particles into coatings and made approximately 280 different paint formulations with 9 different coatings, coated over 2000 panels of which 960 were tested in 36 different corrosion test runs.

Extensive corrosion testing was performed on coatings applied to metals, following ASTM standards. ASTM B117 salt spray testing was used to screen Smart Particles formulations and show intra-test performance. To demonstrate performance in real-life environments, accelerate industry adoption and for marketing, atmospheric exposure testing was conducted at NASA Kennedy Space Center’s Beachside Atmospheric Exposure Test Site, a world-leading and world-renowned independent corrosion test site whose test results are regarded highly in the coatings industry.

Results from this testing showed that Smart Particles enhance the corrosion protection performance and lifetime of multiple protective coating systems substantially. While it is notoriously difficult to quantify the performance of anticorrosion coatings, Smart Particles have the potential to increase their lifetime by up to two-fold. Doubling the lifetimes extends maintenance cycles and reduces asset lifetime maintenance costs by up to 50%. In the example of just one large offshore oil and gas platform, this could deliver tens of millions of dollars in savings to its owners.

As SynMatter was able to demonstrate in this project, Smart Particles will dramatically improve protective coatings which in turn will improve structural safety, reduce maintenance frequency and lengthen the operating lifetimes of metal assets that are essential to the US economy, and do so in human and environmentally friendly manner. Through extensive market research and customer discovery, SynMatter has identified a significant need for such new, high performance corrosion inhibitors in the protective coatings market. Based on the derisked technology and high performance, the next steps for the company involve partnering with manufacturers, distributors and end users to push Smart Particles products into the protective coatings market. The team thanks NSF for its trust, funding and support.

 


Last Modified: 06/12/2024
Modified by: Xuejun Zhang

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