Award Abstract # 1750497
Collaborative Research: Atmospheric Mixed Phase Chemistry for Improved Climate Predictions: Field Measurements and Modeling of the Southern Oxidant and Aerosol Study

NSF Org: AGS
Division of Atmospheric and Geospace Sciences
Recipient: UNIVERSITY OF CALIFORNIA IRVINE
Initial Amendment Date: September 13, 2017
Latest Amendment Date: September 13, 2017
Award Number: 1750497
Award Instrument: Standard Grant
Program Manager: Sylvia Edgerton
sedgerto@nsf.gov
 (703)292-8522
AGS
 Division of Atmospheric and Geospace Sciences
GEO
 Directorate for Geosciences
Start Date: June 1, 2017
End Date: December 31, 2017 (Estimated)
Total Intended Award Amount: $50,052.00
Total Awarded Amount to Date: $50,052.00
Funds Obligated to Date: FY 2016 = $50,052.00
History of Investigator:
  • Ann Marie Carlton (Principal Investigator)
    agcarlto@uci.edu
Recipient Sponsored Research Office: University of California-Irvine
160 ALDRICH HALL
IRVINE
CA  US  92697-0001
(949)824-7295
Sponsor Congressional District: 47
Primary Place of Performance: University of California-Irvine
141 Innovation Drive
Irvine
CA  US  92617-3213
Primary Place of Performance
Congressional District:
47
Unique Entity Identifier (UEI): MJC5FCYQTPE6
Parent UEI: MJC5FCYQTPE6
NSF Program(s): Atmospheric Chemistry
Primary Program Source: 01001617DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s):
Program Element Code(s): 152400
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

This project will investigate processes associated with the natural emissions of biogenic volatile organic compounds (BVOCs) that lead to the formation of secondary organic aerosol (SOA). Of particular interest is the assessment of organic compounds derived from BVOC oxidation that are water-soluble, CCN-active and react readily with the OH radical in controlled laboratory experiments to create low-volatility products that may form secondary aerosol via multiphase organic chemistry. Continuous measurements of SOA chemical and physical properties will be made during the Southern Oxidant and Aerosol Study (SOAS) to be conducted near Centreville Alabama in the summer of 2013. This study will focus on the role of particle phase liquid water and particle pH in determining SOA mass. The data will be analyzed to elucidate the linkages between bio- and anthropogenic emissions on multiphase chemistry, and estimate the magnitude of the contribution of multiphase pathways to SOA.

This research is needed in order to improve understanding of local and global climate and air quality. The results may help explain whether the anomalous temperature trend in the Southeast, which has not warmed like other regions in response to global climate change, is due to interactions among biogenic and anthropogenic emissions that can affect regional climate through formation of secondary organic aerosol. During the field campaign, there will be many activities supporting science communication and education.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 12)
A.G. CarltonB.J. Turpin "Particle organic partitioning potential is highest in the Eastern US and driven by anthropogenic water" Atmospheric Chemistry and Physics , v.13 , 2013 , p.12073 10.5194/acp-13-10203-2013
Annmarie G. Carlton, Joost de Gouw, Jose L. Jimenez, Jesse L. Ambrose, Alexis R. Attwood,Steven Brown, Kirk R. Bak er, Charles Brock , Ronald C. Cohen, Sylvia Edgerton, Caroline Farka s,Delphine Farmer, Allen H. Goldstein, Lynne Gratz, Alex Guenther, Sh "SYNTHESIS OF THE SOUTHEASTATMOSPHERE STUDIESInvestigating Fundamental AtmosphericChemistry Questions" Bulletin of the American Meteorlogical Society , v.99 , 2018 10.1175/BAMS-D-16-0048.1
C. A. BrockN. L. WagnerB. E. AndersonA. R. AttwoodA. BeyersdorfP. Campuzano-JostA. G. CarltonD. A. DayG. S. DiskinT. D. GordonJ. L. JimenezD. A. LackJ. LiaoM. Z. MarkovicA. M. MiddlebrookN. L. NgA. E. PerringM. S. RichardsonJ. P. Schwarz "Aerosol optical properties in the southeastern United States in summer ? Part 1: Hygroscopic growth" Atmospheric Chemistry and Physics , v.16 , 2016 , p.4987 doi:10/5194/acp-16-2016
Havala O. T. PyeBenjamin N. MurphyLu XuNga L. NgAnnmarie G. CarltonHongyu GuoRodney WeberPetros VasilakosK. Wyat AppelSri Hapsari BudisulistioriniJason D. SurrattAthanasios NenesWeiwei HuJose L. JimenezGabriel Isaacman-VanWertzPawel K. Misz "On the implications of aerosol liquid water and phase separation for organic aerosol mass" Atmospheric Chemistry and Physics , v.17 , 2017 , p.343 10.5194/acp-17-343-2017
H. Guo L. Xu A. Bougiatioti K. M. Cerully S. L. Capps J. R. Hite A. G. Carlton S.-H. LeeM. H. Bergin N. L. Ng A. Nenes R. J. Weber "Particle water and pH in the southeastern United States." Atmospheric Chemistry and Physics , v.15 , 2015 , p.5211 10.5194/acp-15-5211-2015
Neha Sareen Eleanor M. Waxman Barbara J. Turpin Rainer Volkamer Annmarie G. Carlton "Potential of aerosol liquid water to facilitate organic aerosol formation: assessing knowledge gaps about precursors and partitioning" Environmental Science and Technology , v.51 , 2017 , p.3327 10.1021/acs.est.6b04540
N. HodasA. SullivanK. SkogR. KeutschJ.L. CollettS. DecsesariM.C. Facchini A.G. Carlton A. LaaksonenB.J. Turpin "Aerosol Liquid Water Driven by Anthropogenic Nitrate: Implications for Lifetimes of Water-Soluble Organic Gases and Potential for Secondary Organic Aerosol Formation" Environmental Science & Technology , v.48 , 2014 , p.11127 10.1021/es5025096
N SareenAG CarltonJD SurrattA GoldB LeeFD Lopez-HilfikerC MohrJA ThorntonZF ZhangYB LimBJ Turpin "Identifying precursors and aqueous organic aerosol formation pathways during the SOAS campaign" Atmospheric Chemistry and Physics , v.16 , 2016 , p.14409 10.5194/acp-16-14409-2016
?Thien Khoi V. Nguyen Qi Zhang Jose L. Jimenez Maxwell Pike Annmarie G. Carlton "Liquid water: ubiquitous contributor to aerosol mass" Environmental Science and Technology Letters , v.3 , 2016 , p.247 10.1021/acs.estlett.6b00167
Thien Khoi V. Nguyen Virendra P. Ghate Annmarie G. Carlton "Reconciling satellite aerosol optical thickness and surface fine particle mass through aerosol liquid water" Geophysical Research Letters , v.43 , 2016 , p.11903 10.1002/2016GL070994
T.K.V. NguyenM.D. PettersS.R. SudaH. GuoR.J. WeberA.G. Carlton "Trends in particle phase liquid water during the Southern Oxidant Aerosol Study?" Atmospheric Chemistry and Physics , v.14 , 2014 , p.10911 10.5194/acp-14-10911-2014
(Showing: 1 - 10 of 12)

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

Project Outcomes for the past 12 months

 

The primary recent outcome for this project for the past 12 months is scientific and technical leadership for the publication of an overview article that synthesizes findings from the Southern Oxidant and Aerosol Study (SOAS) with information derived from other field campaigns that also occurred in the Eastern and Southeastern U.S. concurrently. The article is entitled "Synthesis of the southeast atmosphere studies: investigating fundamental atmospheric chemistry questions" in the Bulletin of the American Meteorology Society (BAMS) in the March 2018 issue. BAMS is the flagship magazine of the American Meteorological Society. The journal publishes articles of broad interest in significance for the weather, water and climate community. Because our SOAS campaign primarily involved atmospheric chemists, we purposefully worked to reach out to the broader atmospheric sciences community by publishing in BAMS.  

The manuscript describes key findings regarding science topics that span across all of the campaigns: 1.) atmosphere-biosphere interactions, 2.) anthropogenic emissions in the U.S. and trends in ambient data, 3.)  atmospheric nitrogen chemistry during the day and night, 4.) mercury cycling in the atmosphere, 5.) development of new gas- and multiphase chemical mechanisms, 6.) the organic aerosol budget in the U.S. and 7.) discussion of climate-relevant properties of the atmospheric aerosol.

The Document Object Identifier for this manuscript is doi:10.1175./BAMS-D-16-0048.1.

 


Last Modified: 04/01/2018
Modified by: Ann Marie G Carlton

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