Award Abstract # 1655152
Acquisition of New Excimer Laser Ablation System for a High Resolution ICPMS Facility

NSF Org: EAR
Division Of Earth Sciences
Recipient: THE UNIVERSITY CORPORATION
Initial Amendment Date: September 6, 2017
Latest Amendment Date: September 13, 2018
Award Number: 1655152
Award Instrument: Continuing Grant
Program Manager: David Lambert
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: September 15, 2017
End Date: August 31, 2022 (Estimated)
Total Intended Award Amount: $299,134.00
Total Awarded Amount to Date: $299,134.00
Funds Obligated to Date: FY 2017 = $270,208.00
FY 2018 = $28,926.00
History of Investigator:
  • Robinson Cecil (Principal Investigator)
    robinson.cecil@csun.edu
  • Joshua Schwartz (Co-Principal Investigator)
Recipient Sponsored Research Office: The University Corporation, Northridge
18111 NORDHOFF ST
NORTHRIDGE
CA  US  91330-0001
(818)677-1403
Sponsor Congressional District: 32
Primary Place of Performance: The University Corporation, Northridge
CA  US  91330-8266
Primary Place of Performance
Congressional District:
32
Unique Entity Identifier (UEI): LAGNHMC58DF3
Parent UEI:
NSF Program(s): Instrumentation & Facilities,
XC-Crosscutting Activities Pro
Primary Program Source: 01001718DB NSF RESEARCH & RELATED ACTIVIT
01001819DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s):
Program Element Code(s): 158000, 722200
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

This award will support the acquisition of a new laser ablation system to be used in tandem with an existing high resolution mass spectrometer in the CSU-Northridge Department of Geological Sciences. The mass spectrometry facility at CSU-Northridge is a newly developed laboratory used primarily for analyzing isotopic ratios and the concentrations of low abundance elements in earth materials. A laser ablation system couples with the mass spectrometer and provides a way of directly sampling micrometer-scale parts of minerals and / or rocks, which is important for determining the specific timing and growth conditions of the targeted material. The laser ablation - mass spectrometry facility at CSU-Northridge is used primarily for determining ages of a variety of minerals, which has a broad range of applications across many geoscience disciplines. Some examples of those applications include: dating of igneous rocks and constraints on the timing and growth rate of continental crust; dating of metamorphism and constraints on the deformation of crust; dating of minerals in sedimentary rocks and constraints on the evolution of landscapes. Addition of the new laser supported by this award will allow the PIs to build a unique and high demand laboratory easily accessible to Los Angeles area academic institutions, many of which are minority-serving. This proposal also includes funding for a summer research initiative aimed at supporting traditionally underserved students, giving them an opportunity to receive training and mentorship using our state-of-the-art facility in a small-group setting.

This support will allow the PIs to replace an aging (> 13-year old) laser ablation system with a new 193 nm ArF excimer laser ablation system. It will be coupled with an existing single collector sector field inductively coupled plasma mass spectrometer (SF-ICPMS), and used primarily for accessory mineral geochronology and in-situ trace element analysis. This new instrumentation, together with permanent, full-time technical support provided by the University, will allow the PIs to develop a regional facility that will generate precise, high-quality data with new efficiencies that allow for high sample throughput and the analysis of, for example, high n-number detrital zircon datasets. Trace element analysis, which was previously not possible because of laser signal instability, will be used on its own (rastering over glasses fused from a variety of bulk rocks), and in concert with Pb/U age data to link chemical conditions to timing of accessory mineral growth.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 11)
Barzola, Matías G. and Tibaldi, Alina M. and Otamendi, Juan E. and Cristofolini, Eber A. and Schwartz, Joshua J. and Benito, María P. and Armas, Paula "P-T-t path reconstruction in a syn-deformational migmatization event along the north-central portion of Sierra de Comechingones, Córdoba, Argentina" Journal of South American Earth Sciences , v.112 , 2021 https://doi.org/10.1016/j.jsames.2021.103534 Citation Details
Buriticá, Luisa F. and Schwartz, Joshua J. and Klepeis, Keith A. and Miranda, Elena A. and Tulloch, Andy J. and Coble, Matthew A. and Kylander-Clark, Andrew R.C. "Temporal and spatial variations in magmatism and transpression in a Cretaceous arc, Median Batholith, Fiordland, New Zealand" Lithosphere , v.11 , 2019 https://doi.org/10.1130/L1073.1 Citation Details
Carty, Kendra and Schwartz, Joshua J and Wiesenfeld, John and Klepeis, Keith A and Stowell, Harold H and Tulloch, Andy J and Barnes, Calvin G "The Generation of Arc Andesites and Dacites in the Lower Crust of a Cordilleran Arc, Fiordland, New Zealand" Journal of Petrology , v.62 , 2021 https://doi.org/10.1093/petrology/egab043 Citation Details
Cecil, M. Robinson and Gehrels, George E. and Rusmore, Margaret E. and Woodsworth, Glenn J. and Stowell, Harold H. and Yokelson, Intan N. and Homan, Emily and Kitajima, Kouki and Valley, John W. "Mantle control on magmatic flare-ups in the southern Coast Mountains batholith, British Columbia" Geosphere , v.17 , 2021 https://doi.org/10.1130/GES02361.1 Citation Details
Klepeis, Keith A. and Schwartz, Joshua J. and Miranda, Elena and Lindquist, Peter and Jongens, Richard and Turnbull, Rose and Stowell, Harold "The Initiation and Growth of Transpressional Shear Zones Through Continental Arc Lithosphere, Southwest New Zealand" Tectonics , v.41 , 2022 https://doi.org/10.1029/2021TC007097 Citation Details
LaMaskin, Todd A. and Rivas, Jonathan A. and Barbeau, David L. and Schwartz, Joshua J. and Russell, John A. and Chapman, Alan D. "A crucial geologic test of Late Jurassic exotic collision versus endemic re-accretion in the Klamath Mountains Province, western United States, with implications for the assembly of western North America" GSA Bulletin , v.134 , 2021 https://doi.org/10.1130/B35981.1 Citation Details
Ma, Chong and VanDervoort, Dane S. and Steltenpohl, Mark G. and Schwartz, Joshua J. "Formation and orogen-parallel transport of the Dadeville Complex, Alabama, USA: Implications for the Taconian orogeny in the southern Appalachians" American Journal of Science , v.319 , 2019 https://doi.org/10.2475/07.2019.03 Citation Details
Medaris, L. Gordon and Singer, Brad S. and Jicha, Brian R. and Malone, David H. and Schwartz, Joshua J. and Stewart, Esther K. and Van Lankvelt, Amanda and Williams, Michael L. and Reiners, Peter W. "Early Mesoproterozoic evolution of midcontinental Laurentia: Defining the geon 14 Baraboo orogeny" Geoscience Frontiers , v.12 , 2021 https://doi.org/10.1016/j.gsf.2021.101174 Citation Details
Richter, Fabiana and Pearson, Jozi and Vilkas, Marius and Heermance, Richard V. and Garzione, Carmala N. and Cecil, M. Robinson and Jepson, Gilby and Moe, Annelisa and Xu, Jianhong and Liu, Langtao and Chen, Jie "Growth of the southern Tian Shan-Pamir and its impact on central Asian climate" GSA Bulletin , 2022 https://doi.org/10.1130/B36471.1 Citation Details
Ringwood, M. Schwartz "Phanerozoic Record of mantle-dominated arc magmatic surges in the Zealandia Cordillera" Geology , v.49 , 2021 https://doi.org/10.1130/G48916.1 Citation Details
Turnbull, R.E. and Schwartz, J.J. and Fiorentini, M.L. and Jongens, R. and Evans, N.J. and Ludwig, T. and McDonald, B.J. and Klepeis, K.A. "A hidden Rodinian lithospheric keel beneath Zealandia, Earth's newly recognized continent" Geology , v.49 , 2021 https://doi.org/10.1130/G48711.1 Citation Details
(Showing: 1 - 10 of 11)

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

A Teledyne Analyte G2 excimer laser ablation (LA) system was purchased for use with an existing high resolution inductively coupled plasma mass spectrometer (ICPMS) in the Geological Sciences department at California State University, Northridge (CSUN). This system was acquired in order to efficiently and precisely measure isotopic ratios in accessary minerals, with the goals of routinely collecting high-quality U-Pb geochronologic and trace geochemical data. Our laser ablation ICPMS facility is unique in the Los Angeles area and was acquired in large part to support the research activities of CSUN students, as well as students from other institutions in the Los Angeles basin, many of whom are from groups underrepresented in the Earth Sciences.

Intellectual Merit: The energy production, good beam focusing, and enhanced signal stability of the acquired laser ablation system has allowed the PIs to increase sample throughput, reduce spot size, and ablate for shorter durations. These capabilities have in turn allowed for better spatial resolution and development of grain mapping techniques, down-hole measurements, and targeted analysis of mineral growth domains. With the new laser system, the PIs have improved methods of U-Pb dating of zircon and titanite, and have developed new methods for trace element geochemical analysis of zircon, garnet, amphibole and pyroxene. These geochronologic and geochemical approaches are used broadly by the PIs and their students. The overall impact of this instrumentation is therefore similarly broad, as the laser ablation system has contributed to almost every collaborative project, student investigation, and research proposal developed by the PIs.

Broader Impacts: Since installing our new laser ablation system, it has been used to support the theses of 14 Masters students, and research experiences for over 20 undergraduate students at CSUN. The laser ablation ICPMS facility also benefitted an additional 13 BS and MS students over two years in a pilot PLASMA (Projects in Laser Ablation Spectrometry for Minority Achievement) Institute. Students were recruited who were working with advisors at their home institutions on projects for which detrital and / or igneous geochronologic data were needed. The PIs helped these students with sample preparation, data collection, and data interpretation, and provided group workshops on U-Pb geochronology, mass spectrometry, and data visualization. A PLASMA Institute is currently being implemented by PI Schwartz as part of a separate NSF award. In addition to research opportunities, the LA-ICPMS facility is also used for instructional purposes in upper division petrology and geochronology courses taught by the PIs.

The ability to routinely collect geochronologic and geochemical data with the LA-ICPMS has led to new collaborations between the PIs and researchers at universities and government agencies. These collaborations have broadened the scope of the research being carried out in the facility and have provided financial support for operations. Development of this laboratory has also been leveraged to obtain additional instrumentation through competitive awards at NSF and DOE, including a quadrupole mass spectrometer and a field emission scanning electron microscope. The laser ablation system has become a building block onto which a larger geoanalytical facility at CSUN is being constructed. Since acquiring the laser ablation system, the PIs have been awarded four additional research awards; all of which depend on datasets generated using the LA-ICPMS. Published geochronologic and geochemical datasets coming out of the laser ablation laboratory have been made available in public-access databases, thereby enhancing their impact. A total of 20 peer-reviewed papers, and over 30 conference abstracts, have been published by the PIs using data generated in with this laser ablation system. It is difficult to overstate the impact that this instrumentation has had on technique development, advancing research objectives, and supporting students at CSUN and elsewhere.

 


Last Modified: 03/17/2023
Modified by: Robinson Cecil

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