Award Abstract # 1638307
Improving Characterization of Aerosol Optical Properties: Combined Measurements of Angle-resolved Scattering and Ultraviolet-visible Absorption

NSF Org: AGS
Division of Atmospheric and Geospace Sciences
Recipient: UNIVERSITY OF GEORGIA RESEARCH FOUNDATION, INC.
Initial Amendment Date: July 27, 2016
Latest Amendment Date: July 27, 2016
Award Number: 1638307
Award Instrument: Standard Grant
Program Manager: Sylvia Edgerton
sedgerto@nsf.gov
 (703)292-8522
AGS
 Division of Atmospheric and Geospace Sciences
GEO
 Directorate for Geosciences
Start Date: August 1, 2016
End Date: July 31, 2020 (Estimated)
Total Intended Award Amount: $489,811.00
Total Awarded Amount to Date: $489,811.00
Funds Obligated to Date: FY 2016 = $489,811.00
History of Investigator:
  • Geoffrey Smith (Principal Investigator)
    gsmith@chem.uga.edu
Recipient Sponsored Research Office: University of Georgia Research Foundation Inc
310 E CAMPUS RD RM 409
ATHENS
GA  US  30602-1589
(706)542-5939
Sponsor Congressional District: 10
Primary Place of Performance: University of Georgia
140 Cedar St.
Athens
GA  US  30602-1589
Primary Place of Performance
Congressional District:
10
Unique Entity Identifier (UEI): NMJHD63STRC5
Parent UEI:
NSF Program(s): Atmospheric Chemistry
Primary Program Source: 01001617DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s):
Program Element Code(s): 152400
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

This project focuses on the development of new instrumentation for measuring the optical properties of atmospheric aerosol. These instruments will provide measurements of light scattering and absorption by aerosols and enable better characterization of soot particles and particles containing black and brown carbon. A better understanding of the optical properties of atmospheric aerosol is needed for more accurate ground-based and satellite retrievals of data on atmospheric aerosols and for developing improved global climate models.

This research will: (1) build a portable 3-wavelength polar nephelometer to measure light scattering by particles as a function of angle and light polarization; (2) expand the capabilities for measuring ambient aerosol absorption by adding a near-IR channel to a photoacoustic spectrophotometer (PAS), building a UV PAS instrument, and constructing a thermodenuder to better measure the black and brown carbon components of absorption, and (3) more accurately measure the optical properties of soot (black and black carbon) and especially those properties associated with aerosol coatings.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Cheng, Zezhen and Atwi, Khairallah and Hajj, Omar El and Ijeli, Ifeoma and Fischer, D. Al and Smith, Geoffrey and Saleh, Rawad "Discrepancies between brown carbon light-absorption properties retrieved from online and offline measurements" Aerosol Science and Technology , 2020 https://doi.org/10.1080/02786826.2020.1820940 Citation Details
Fierce, Laura and Onasch, Timothy B. and Cappa, Christopher D. and Mazzoleni, Claudio and China, Swarup and Bhandari, Janarjan and Davidovits, Paul and Fischer, D. Al and Helgestad, Taylor and Lambe, Andrew T. and Sedlacek, Arthur J. and Smith, Geoffrey D "Radiative absorption enhancements by black carbon controlled by particle-to-particle heterogeneity in composition" Proceedings of the National Academy of Sciences , v.117 , 2020 10.1073/pnas.1919723117 Citation Details
Fischer, D. Al and Smith, Geoffrey D. "A portable, four-wavelength, single-cell photoacoustic spectrometer for ambient aerosol absorption" Aerosol Science and Technology , v.52 , 2018 10.1080/02786826.2017.1413231 Citation Details
Fischer, D. Al and Smith, Geoffrey D. "Can ozone be used to calibrate aerosol photoacoustic spectrometers?" Atmospheric Measurement Techniques , v.11 , 2018 10.5194/amt-11-6419-2018 Citation Details
Phillips, Sabrina M. and Bellcross, Aleia D. and Smith, Geoffrey D. "Light Absorption by Brown Carbon in the Southeastern United States is pH-dependent" Environmental Science & Technology , v.51 , 2017 10.1021/acs.est.7b01116 Citation Details
Phillips, Sabrina M. and Smith, Geoffrey D. "Spectroscopic comparison of water- and methanol-soluble brown carbon particulate matter" Aerosol Science and Technology , 2017 10.1080/02786826.2017.1334109 Citation Details

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

The major goals of this project were to develop instruments and tools for better characterizing how aerosol particles absorb and scatter sunlight in the atmosphere.  A more complete understanding of these interactions make possible more accurate modeling of the earth's atmospheric system, better satellite retrievals of important atmosperic constituents and predicitons of the effects that various policy decisions have on the atmosphere.

A major accomplishment of this project was the development and characterization of two unique instruments for measuring aerosol absorption directly without the complications arising from collecting particles on filters.  These two instruments include seven different wavelengths of light spanning the UV and visible region of the spectrum.  This broad spectral capability allows for a more complete measure of aerosol absorption by sunlight.

Another major accomplishment of this project was the construction of a polar nephelometer, which is an instrument to measure how much aerosol particles scatter light in different directions.  Such measurements are important because they allow for a more accurate determination of how aerosols impact radiative balance in the atmosphere.

A third instrument to measure aerosol extinction was also built, tested and deployed during this project.  This instrument operates over the UV-visible region of the spectrum simultaneously measuring extinction at 200 wavelengths.  The wealth of information provided makes it possible to accurately represent the full extinction spectrum from which various particle properties can be inferred.

Over the course of this project, we have used measurements from all three of these types of instruments to more carefully study both atmospheric aerosols and laboratory-generated particles that are important in the atmosphere.  For example, we have studied ammonium sulfate particles and have been able to make more accurate measurements of their refractive index, a key parameter needed to accurately model them in atmospheric chemistry and physics models.  We have also measure the refractive index of polystyrene latex spheres, manufactured particles that are commonly used to calibrate and validate a host of instruments; our measurements have reduced uncertainty on this important parameter.  In addition, we have used our measurements of ambient aerosols to develop a new particle classification system based on machine learning methods, which should aid others attempting to classify particles using both ground-based and satellite-based optical measurements.

 


Last Modified: 10/02/2020
Modified by: Geoffrey D Smith

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