Award Abstract # 1555388
CAREER: Elasticity and Lattice Dynamics of Iron Alloys under Earth's Core Conditions

NSF Org: EAR
Division Of Earth Sciences
Recipient: UNIVERSITY OF HAWAII
Initial Amendment Date: February 11, 2016
Latest Amendment Date: May 18, 2021
Award Number: 1555388
Award Instrument: Continuing Grant
Program Manager: Eva Zanzerkia
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: February 15, 2016
End Date: January 31, 2022 (Estimated)
Total Intended Award Amount: $570,000.00
Total Awarded Amount to Date: $596,039.00
Funds Obligated to Date: FY 2016 = $123,753.00
FY 2017 = $112,375.00

FY 2018 = $111,845.00

FY 2019 = $110,092.00

FY 2020 = $111,935.00

FY 2021 = $26,039.00
History of Investigator:
  • Bin Chen (Principal Investigator)
    binchen@hawaii.edu
Recipient Sponsored Research Office: University of Hawaii
2425 CAMPUS RD SINCLAIR RM 1
HONOLULU
HI  US  96822-2247
(808)956-7800
Sponsor Congressional District: 01
Primary Place of Performance: University of Hawaii
1680 East West Road #602
Honolulu
HI  US  96822-2327
Primary Place of Performance
Congressional District:
01
Unique Entity Identifier (UEI): NSCKLFSSABF2
Parent UEI:
NSF Program(s): Petrology and Geochemistry,
Geophysics,
XC-Crosscutting Activities Pro
Primary Program Source: 01001617DB NSF RESEARCH & RELATED ACTIVIT
01001718DB NSF RESEARCH & RELATED ACTIVIT

01001819DB NSF RESEARCH & RELATED ACTIVIT

01001920DB NSF RESEARCH & RELATED ACTIVIT

01002021DB NSF RESEARCH & RELATED ACTIVIT

01002122DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 097Z, 102Z, 1031, 1045, 9150
Program Element Code(s): 157300, 157400, 722200
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Residing at the center of the Earth, the core is the innermost but extremely dynamic region of our planet. Over the last two decades, geophysicists have expended tremendous effort in deciphering the compositional makeup, thermal structure, and seismic features of the Earth's core. Understanding the nature and dynamics of the core can deeply enhance our abilities in understanding the magnetic field generation process, the thermo-chemical evolution of the Earth's deep interior, and the formation of the Earth as a habitable planet. This Faculty Early Career Development (CAREER) program aims to investigate the elasticity and lattice dynamics of iron alloys as candidates for the inner core under high pressure and temperature conditions of the core, using multiscale state-of-the-art experimental facilities. The outcome of the proposed research is a new set of fundamental mineral physics data on density, sound velocities, and single-crystal elasticity of iron alloys under previously uncharted pressure-temperature regimes, essential for us to provide further constraints on the core's composition and dynamics. The experimental results are to be integrated to a comprehensive mineral physics database for the core, cultivating collaborations with sister disciplines such as seismology, geodynamics and geochemistry, and ultimately enhancing our profound understanding of nature and dynamics of the Earth's deepest interior. Furthermore, the involvement of student researchers in the proposed research and the development of a research and teaching facility for high-pressure mineral and materials science will initiate the 'pipeline' that helps influence and attract diverse student population, particularly traditionally underrepresented minorities, into Earth science and build diverse geoscience workforce.

This proposal aims to systematically measure high pressure-temperature elastic and vibrational properties of candidate iron alloys for the inner core, using synchrotron-based X-ray spectroscopies combined with resistively- and laser-heated diamond anvil cell techniques, so as to address the following scientific questions: (1) How do pressure and temperature affect the elastic and vibrational properties of iron alloys under core conditions? (2) What are the alloying effects of candidate light elements on the elasticity of iron under core conditions? (3) What are the single crystal elasticities of iron alloys approaching the core conditions, for the interpretation of the inner core's seismic anisotropy and fine-scale seismic? (4) Finally, what are the likely lighter alloying components in the inner core and what would that imply for the thermochemical evolution of the core and the planet? The integrated education and outreach objective is to train a new generation of independent solid Earth geoscientists in laboratory- and synchrotron-based facilities and to offer inquiry-base learning opportunities and experience to K-16 students through the implementation of a 'Multi-Anvil Press Laboratory' (MAPLab) teaching module to geosciences curricula. The results of the project will be widely disseminated on a timely manner through national and international meetings, public lectures and outreach, and news media.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 39)
Ding, X., Harlov, D. E., Chen, B., & Sun, W "Fluids, Metals, and Mineral/Ore Deposits" Geofluids , v.2018 , 2018 , p.1452409 10.1155/2018/1452409
Chen, B. and Li, J. "Carbon in the Core, in Deep Earth: Physics and Chemistry of the Lower Mantle and Core (eds H. Terasaki and R. A. Fischer)" Geophysical monograph , 2016 Citation Details
Chen, Bin Y. and Lai, Xiaojing and Li, Jie and Liu, Jiachao and Zhao, Jiyong and Bi, Wenli and Ercan Alp, E. and Hu, Michael and Xiao, Yuming "Experimental constraints on the sound velocities of cementite Fe3C to core pressures" Earth and Planetary Science Letters , v.494 , 2018 10.1016/j.epsl.2018.05.002 Citation Details
Chen, B., X. Lai, J. Li, J. Liu, J. Zhao, W. Bi, E. E. Alp, M. Y. Hu, and Y. Xiao "Experimental Constraints on the Sound Velocities of Cementite Fe3C to Core Pressures" Earth Planet. Sci. Lett. , v.494 , 2018 , p.164 10.1016/j.epsl.2018.05.002
Gao J, Yuan X, Chen B, Liu Z, Su W "High-pressure phase transformation of carbonate malachite Cu2(CO3)(OH)2 driven by [CuO6] regularization and [CO3] rotation" Geoscience Frontiers , v.12 , 2020 , p.965-973 10.1016/j.gsf.2020.07.006
Huang, Shengxuan and Wu, Xiang and Chariton, Stella and Prakapenka, Vitali B. and Liang, Lin and Zhang, Dongzhou and Yang, Yan and Chen, Bin and Qin, Shan "Experimental Constraints on the Fate of Subducted Sedimentary Nitrogen in the Reduced Mantle" Journal of Geophysical Research: Solid Earth , v.127 , 2022 https://doi.org/10.1029/2022JB025169 Citation Details
Huang, Shengxuan and Wu, Xiang and Zhu, Feng and Lai, Xiaojing and Li, Jie and Neill, Owen K. and Qin, Shan and Rapp, Robert and Zhang, Dongzhou and Dera, Przemyslaw and Chariton, Stella and Prakapenka, Vitali B. and Chen, Bin "High-{{Pressure Phase Stability}} and {{Thermoelastic Properties}} of {{Iron Carbonitrides}} and {{Nitrogen}} in the {{Deep Earth}}" Journal of Geophysical Research: Solid Earth , v.126 , 2021 , p.e2021JB02 10.1029/2021JB021934
Lai, X., B. Chen, J. Wang, Y. Kono, and F. Zhu "Polyamorphic transformation in Fe-Ni-C liquids: Implications for chemical evolution of terrestrial planets" J. Geophys. Res.-Solid Earth , 2017 10.1002/2017JB014835
Lai, Xiaojing and Chen, Bin and Wang, Jianwei and Kono, Yoshio and Zhu, Feng "Polyamorphic Transformations in Fe-Ni-C Liquids: Implications for Chemical Evolution of Terrestrial Planets: Fe-Ni-C liquid structural change" Journal of Geophysical Research: Solid Earth , v.122 , 2017 10.1002/2017JB014835 Citation Details
Lai, Xiaojing and Zhu, Feng and Gao, Jing and Greenberg, Eran and Prakapenka, Vitali B. and Meng, Yue and Chen, Bin "Melting of the FeCH System and Earth's Deep CarbonHydrogen Cycle" Geophysical Research Letters , v.49 , 2022 https://doi.org/10.1029/2022GL098919 Citation Details
Lai, Xiaojing and Zhu, Feng and Zhang, Jin S. and Zhang, Dongzhou and Tkachev, Sergey and Prakapenka, Vitali B. and Chen, Bin "An Externally-Heated Diamond Anvil Cell for Synthesis and Single-Crystal Elasticity Determination of Ice-VII at High Pressure-Temperature Conditions" Journal of Visualized Experiments , 2020 10.3791/61389 Citation Details
(Showing: 1 - 10 of 39)

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

The presence of light elements in the Earth’s core is considered the “culprit” for the so-called “core density deficit”, accounting for the anomalous seismic signals and observations of the Earth’s core. Light elements in the core may also provide the crucial energy for sustaining the geodynamo that is responsible for the planet’s magnetic field and thus its habitability. The main research goals of the project are to provide further constraints on the composition of the Earth’s core, by acquiring critical mineral physics data on the density, sound velocities, and elasticity of iron alloys under the previously uncharted pressure-temperature regime. The integrated educational goals are to train the involved graduate and undergraduate researchers in multi-scale experimental facilities and develop a Multi-Anvil Press Laboratory (MAPLab) teaching and training module for the high-pressure geoscience curriculum and the public outreach to K-16 students and instructors. 

Understanding the composition and dynamics of Earth’s core is key for the quest to properly model the formation and evolution of the core and the whole planet. Over the course of the project, the principal investigator (PI) Chen’s group has studied the effect of C, P, H, and N on the phase stability and elastic properties of iron alloys at pressure-temperature conditions approaching Earth’s core. In particular, the group has determined sound velocities and thermoelastic properties of three potential inner core phases, Fe3C, Fe3P, and Fe7C3 compressed to core pressures in DACs using synchrotron X-ray techniques combined in diamond anvil cell. The observed shear softening of those phases revealed that the non-magnetic carbide and phosphorite phases demonstrate markedly low shear-wave velocity under core pressures, further revealing the effect of carbon and phosphor and the magnetic transition on the elastic properties of iron. The presence of carbon and phosphor in the inner core to form iron alloys was found to account for the large velocity discrepancy by effectively reducing the shear-wave velocity and elevating the Poisson’s ratio to be comparable with the seismologically determined values for the inner core. In addition, the effect of H and C on the melting of iron and the effect of nitrogen on the thermoelastic properties of iron carbide have been investigated to understand the C, H, and N cycles in deep Earth.

PI Chen has commissioned the MAPLab facility at the University of Hawaii at Manoa, which is among the very few multi-anvil press laboratories in the country that are being actively used for research and education. The MAPLab has been established as a multi-user facility for high extreme materials research, teaching and outreach. MAPLab facility has been used for class projects, summer research experiences for undergraduate and high school students, and outreach to the general public.

The broader impacts of the project include the technical development of externally-heated diamond anvil cell that can reach extraordinary high temperatures in a controlled environment, and pushing the pressure limit for large volume press experiments using multi-anvil apparatuses. Those developmental efforts will enable new research on extreme materials science and benefit the high-pressure scientific community.


Last Modified: 06/24/2022
Modified by: Bin Chen

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