
NSF Org: |
EAR Division Of Earth Sciences |
Recipient: |
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Initial Amendment Date: | February 11, 2016 |
Latest Amendment Date: | May 18, 2021 |
Award Number: | 1555388 |
Award Instrument: | Continuing Grant |
Program Manager: |
Eva Zanzerkia
EAR Division Of Earth Sciences GEO Directorate for Geosciences |
Start Date: | February 15, 2016 |
End Date: | January 31, 2022 (Estimated) |
Total Intended Award Amount: | $570,000.00 |
Total Awarded Amount to Date: | $596,039.00 |
Funds Obligated to Date: |
FY 2017 = $112,375.00 FY 2018 = $111,845.00 FY 2019 = $110,092.00 FY 2020 = $111,935.00 FY 2021 = $26,039.00 |
History of Investigator: |
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Recipient Sponsored Research Office: |
2425 CAMPUS RD SINCLAIR RM 1 HONOLULU HI US 96822-2247 (808)956-7800 |
Sponsor Congressional District: |
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Primary Place of Performance: |
1680 East West Road #602 Honolulu HI US 96822-2327 |
Primary Place of
Performance Congressional District: |
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Unique Entity Identifier (UEI): |
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Parent UEI: |
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NSF Program(s): |
Petrology and Geochemistry, Geophysics, XC-Crosscutting Activities Pro |
Primary Program Source: |
01001718DB NSF RESEARCH & RELATED ACTIVIT 01001819DB NSF RESEARCH & RELATED ACTIVIT 01001920DB NSF RESEARCH & RELATED ACTIVIT 01002021DB NSF RESEARCH & RELATED ACTIVIT 01002122DB NSF RESEARCH & RELATED ACTIVIT |
Program Reference Code(s): |
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Program Element Code(s): |
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Award Agency Code: | 4900 |
Fund Agency Code: | 4900 |
Assistance Listing Number(s): | 47.050 |
ABSTRACT
Residing at the center of the Earth, the core is the innermost but extremely dynamic region of our planet. Over the last two decades, geophysicists have expended tremendous effort in deciphering the compositional makeup, thermal structure, and seismic features of the Earth's core. Understanding the nature and dynamics of the core can deeply enhance our abilities in understanding the magnetic field generation process, the thermo-chemical evolution of the Earth's deep interior, and the formation of the Earth as a habitable planet. This Faculty Early Career Development (CAREER) program aims to investigate the elasticity and lattice dynamics of iron alloys as candidates for the inner core under high pressure and temperature conditions of the core, using multiscale state-of-the-art experimental facilities. The outcome of the proposed research is a new set of fundamental mineral physics data on density, sound velocities, and single-crystal elasticity of iron alloys under previously uncharted pressure-temperature regimes, essential for us to provide further constraints on the core's composition and dynamics. The experimental results are to be integrated to a comprehensive mineral physics database for the core, cultivating collaborations with sister disciplines such as seismology, geodynamics and geochemistry, and ultimately enhancing our profound understanding of nature and dynamics of the Earth's deepest interior. Furthermore, the involvement of student researchers in the proposed research and the development of a research and teaching facility for high-pressure mineral and materials science will initiate the 'pipeline' that helps influence and attract diverse student population, particularly traditionally underrepresented minorities, into Earth science and build diverse geoscience workforce.
This proposal aims to systematically measure high pressure-temperature elastic and vibrational properties of candidate iron alloys for the inner core, using synchrotron-based X-ray spectroscopies combined with resistively- and laser-heated diamond anvil cell techniques, so as to address the following scientific questions: (1) How do pressure and temperature affect the elastic and vibrational properties of iron alloys under core conditions? (2) What are the alloying effects of candidate light elements on the elasticity of iron under core conditions? (3) What are the single crystal elasticities of iron alloys approaching the core conditions, for the interpretation of the inner core's seismic anisotropy and fine-scale seismic? (4) Finally, what are the likely lighter alloying components in the inner core and what would that imply for the thermochemical evolution of the core and the planet? The integrated education and outreach objective is to train a new generation of independent solid Earth geoscientists in laboratory- and synchrotron-based facilities and to offer inquiry-base learning opportunities and experience to K-16 students through the implementation of a 'Multi-Anvil Press Laboratory' (MAPLab) teaching module to geosciences curricula. The results of the project will be widely disseminated on a timely manner through national and international meetings, public lectures and outreach, and news media.
PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH
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PROJECT OUTCOMES REPORT
Disclaimer
This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.
The presence of light elements in the Earth’s core is considered the “culprit” for the so-called “core density deficit”, accounting for the anomalous seismic signals and observations of the Earth’s core. Light elements in the core may also provide the crucial energy for sustaining the geodynamo that is responsible for the planet’s magnetic field and thus its habitability. The main research goals of the project are to provide further constraints on the composition of the Earth’s core, by acquiring critical mineral physics data on the density, sound velocities, and elasticity of iron alloys under the previously uncharted pressure-temperature regime. The integrated educational goals are to train the involved graduate and undergraduate researchers in multi-scale experimental facilities and develop a Multi-Anvil Press Laboratory (MAPLab) teaching and training module for the high-pressure geoscience curriculum and the public outreach to K-16 students and instructors.
Understanding the composition and dynamics of Earth’s core is key for the quest to properly model the formation and evolution of the core and the whole planet. Over the course of the project, the principal investigator (PI) Chen’s group has studied the effect of C, P, H, and N on the phase stability and elastic properties of iron alloys at pressure-temperature conditions approaching Earth’s core. In particular, the group has determined sound velocities and thermoelastic properties of three potential inner core phases, Fe3C, Fe3P, and Fe7C3 compressed to core pressures in DACs using synchrotron X-ray techniques combined in diamond anvil cell. The observed shear softening of those phases revealed that the non-magnetic carbide and phosphorite phases demonstrate markedly low shear-wave velocity under core pressures, further revealing the effect of carbon and phosphor and the magnetic transition on the elastic properties of iron. The presence of carbon and phosphor in the inner core to form iron alloys was found to account for the large velocity discrepancy by effectively reducing the shear-wave velocity and elevating the Poisson’s ratio to be comparable with the seismologically determined values for the inner core. In addition, the effect of H and C on the melting of iron and the effect of nitrogen on the thermoelastic properties of iron carbide have been investigated to understand the C, H, and N cycles in deep Earth.
PI Chen has commissioned the MAPLab facility at the University of Hawaii at Manoa, which is among the very few multi-anvil press laboratories in the country that are being actively used for research and education. The MAPLab has been established as a multi-user facility for high extreme materials research, teaching and outreach. MAPLab facility has been used for class projects, summer research experiences for undergraduate and high school students, and outreach to the general public.
The broader impacts of the project include the technical development of externally-heated diamond anvil cell that can reach extraordinary high temperatures in a controlled environment, and pushing the pressure limit for large volume press experiments using multi-anvil apparatuses. Those developmental efforts will enable new research on extreme materials science and benefit the high-pressure scientific community.
Last Modified: 06/24/2022
Modified by: Bin Chen
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