Award Abstract # 1455352
CAREER: Taking the hydrochemical pulse of the critical zone in small catchments of the Andes-Amazon

NSF Org: EAR
Division Of Earth Sciences
Recipient: UNIVERSITY OF SOUTHERN CALIFORNIA
Initial Amendment Date: April 16, 2015
Latest Amendment Date: April 16, 2015
Award Number: 1455352
Award Instrument: Standard Grant
Program Manager: Laura Lautz
llautz@nsf.gov
 (703)292-7775
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: May 1, 2015
End Date: September 30, 2021 (Estimated)
Total Intended Award Amount: $498,906.00
Total Awarded Amount to Date: $498,906.00
Funds Obligated to Date: FY 2015 = $498,906.00
History of Investigator:
  • A Joshua West (Principal Investigator)
    joshwest@usc.edu
Recipient Sponsored Research Office: University of Southern California
3720 S FLOWER ST FL 3
LOS ANGELES
CA  US  90033
(213)740-7762
Sponsor Congressional District: 34
Primary Place of Performance: University of Southern California
3651 Trousdale Pkwy, ZHS 117
Los Angeles
CA  US  90089-0740
Primary Place of Performance
Congressional District:
37
Unique Entity Identifier (UEI): G88KLJR3KYT5
Parent UEI:
NSF Program(s): Hydrologic Sciences,
International Research Collab
Primary Program Source: 01001516DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 1045, 5926
Program Element Code(s): 157900, 729800
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Water's journey -- from precipitation through soils and groundwater to streams and rivers -- determines the quantity and quality of this economically and environmentally essential resource. Along its path, water mediates chemical reactions that transform rock into soil and that release nutrients, providing the sustenance for ecosystems. Basic scientific questions remain about how quickly water travels and what route it takes through watersheds. Answering these questions is vital for understanding the generation and maintenance of natural resources in Earth's critical zone. Recently developed analytical techniques and theoretical advances promise new insight from the chemical signatures carried by water. This project will develop an integrated research and education program to contribute such insight through detailed hydrochemical study in five small catchments in the Andes-Amazon of Peru. This study site provides a rare opportunity to gain widely applicable mechanistic understanding because of existing infrastructure, complementary ongoing research, and unique natural topographic gradients.

Building on prior work in the Madre de Dios river basin, this project will focus on the transition from the steep, mountainous Andes to the lowland Amazon. Mountain-to-floodplain transitions are common hydrologic features but are poorly represented in existing observatories. The research will identify how hydrochemical processes vary over this transition and will explore mechanisms for observed variations. The project will center around three themes: (i) water residence times; (ii) concentration-discharge relationships of rock-derived solutes; and (iii) relationships between water sources for plants, catchment hydrology, and the availability of rock-derived nutrients. These themes will be explored using new hydrometric and high-frequency hydrochemical measurements. Samples will be collected from precipitation, streamwater, soilwater, and groundwater and analyzed for solute concentrations and water isotope ratios. The hydrochemical studies will be complemented by investigations of mineral distributions in soil, saprolite, and bedrock. New data will be interpreted in the context of topographic, denudation rate, plant root, and ecosystem nutrient datasets from other studies in the region. Water and soil sample collection, chemical analyses, and data interpretation will form part of a "Critical Zone Summer School" that comprises the core of the integrated research and education plan and will train upper-level undergraduate and beginning graduate students who will lead the next generation in this cross-disciplinary research area. This project will further broaden the reach of the "critical zone" conceptual framework through collaboration with landscape architects and through additional outreach and educational activities both in the US and in Peru.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 15)
Baronas, J. Jotautas and Torres, Mark A. and Clark, Kathryn E. and West, A. Joshua "Mixing as a driver of temporal variations in river hydrochemistry: 2. Major and trace element concentration dynamics in the Andes-Amazon transition: MAJOR AND TRACE ELEMENT C-Q MIXING" Water Resources Research , v.53 , 2017 10.1002/2016WR019729 Citation Details
Baronas, J.J., Torres, M.A., Clark, K.E., and West, A.J. "Mixing as a driver of temporal variations in river hydrochemistry: 2. Major and trace element concentration dynamics in the Andes-Amazon transition" Water Resources Research , v.53 , 2017 , p.3120 10.1002/2016WR019729
Baronas, J.J., Torres, M.A., West, A.J., Rouxel, O., Georg, B., Bouchez, J., Gaillardet, J., and Hammond, D.E. "Ge and Si isotope signatures in rivers: A quantitative multi-proxy approach" Earth and Planetary Science Letters , v.503 , 2018 , p.194 10.1016/j.epsl.2018.09.022
Baronas, J. J., West, A. J., Burton, K. W., Hammond, D. E., Opfergelt, S., & Pogge von Strandmann, P. A. E, James, R. H., Rouxel, O. J. "Ge and Si Isotope Behavior During Intense Tropical Weathering and Ecosystem Cycling" Global Biogeochemical Cycles , v.34 , 2020 , p.e2019GB00 10.1029/2019GB006522
Burt, E.I.; Bill, M.; Conrad, M.E.; Ccahuana Quispe, A.J.; Christensen, J.N.; Hilton, R.G.; Dellinger, M.; West, A.J. "Conservative transport of dissolved sulfate across the Rio Madre de Dios floodplain in Peru" Geology , 2021 10.1130/G48997.1
Clark, K.E., Hilton, R.G., West, A.J., Robles Caceres, A., Grocke, D.R., Marthews, T.R., Ferguson, R.I., Asner, G.P., New, M., and Malhi, Y. "Erosion of organic carbon from the Andes and its effects on ecosystem carbon dioxide balance" Journal of Geophysical Research ? Biogeosciences , v.122 , 2017 , p.449 10.1002/2016JG003615
Hilton, R.G. and West, A.J. "Mountains, erosion, and the carbon cycle" Nature Reviews in Earth and Environment , v.1 , 2020 , p.284 10.1038/s43017-020-0058-6
Saatchi, S., Longo, M., Xu, L., Yang, Y. [55 other authors listed alphabetically including West, A.J.] Brumby, S., and Elmore, A. "Detecting Vulnerability of Humid Tropical Forests to Multiple Stressors" One Earth , v.4 , 2021 , p.988 https://doi.org/10.1016/j.oneear.2021.06.002
Torres, M.A., Baronas, J.J., Clark, K.E., Feakins, S.F., and West, A.J. "Mixing as a driver of temporal variations in river hydrochemistry: 1. Insights from conservative tracers in the Andes-Amazon transition" Water Resources Research , v.53 , 2017 , p.3102 10.1002/2016WR019733
Torres, M.A., Moosdorf, N., Hartmann, J., Adkins, J., and West, A.J. "Glacial weathering, sulfide oxidation, and global carbon cycle feedbacks" Proceedings of the National Academy of Sciences , v.114 , 2017 , p.8716 10.1073/pnas.1702953114
Torres, Mark A. and Baronas, J. Jotautas and Clark, Kathryn E. and Feakins, Sarah J. and West, A. Joshua "Mixing as a driver of temporal variations in river hydrochemistry: 1. Insights from conservative tracers in the Andes-Amazon transition: ANDES-AMAZON TRIBUTARY MIXING" Water Resources Research , v.53 , 2017 10.1002/2016WR019733 Citation Details
(Showing: 1 - 10 of 15)

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

The water in streams and rivers started as rain and snow falling on the land surface. Yet a raindrop does not find its way immediately into a river, instead taking a journey that may include passing through vegetation, soil, and potentially rock underneath the soil, before emerging back in streams. This process of water transit controls how much freshwater is available, and when – including whether rivers continue to flow during periods of drought, or conversely if water makes its way too quickly to rivers during storms, causing flooding. At the same time, the time that water takes passing through soils and rocks controls the chemical reactions that take place between water and rock. These chemical reactions release nutrients that sustain ecosystems, and they pull carbon dioxide from the atmosphere into dissolved form in water. Many studies have investigated water transit times (the time it takes for water that fell as rain to emerge as streamflow) and their consequences around the world. Yet the tropics are under-represented in such studies, and the Amazon Basin in particular is poorly characterized – especially considering its major role as the world’s largest river system.

This award supported a multi-year investigation of water transit times, and associated chemical and ecological processes, across the transition from the Andes mountains to the Amazon floodplain in the Rio Madre de Dios River watershed of southeastern Peru. The study focused on eight small watersheds, each with areas close to or less than one square kilometer, spanning from steep high mountain terrain in the Andes to low-relief floodplain terraces. This transition defines the headwater of the Amazon River system and allows for testing of hypotheses about how mountain topography controls the storage and release of water, and related geochemical processes.

Approximately one thousand rain and stream water samples were collected and analyzed for the isotope composition of O and H in water, which was used to estimate water transit times using a modified version of established data analysis approaches. Results revealed that the lowland streams carry a low proportion of young water (less than a few months old), except during storms when they rapidly fill with recent rainfall. Additional chemical analyses of nutrient elements in stream waters showed that this storm-driven streamflow may be important in driving the loss of key nutrient elements from the forest, potentially linking forest health with the climate-associated storm frequency.

In the mountainous catchments in this study, water transit times were highly variable, highlighting the multiple factors that control the pathways of water in steep landscapes. Perhaps counter-intuitively, the steepest watersheds were not associated with the highest proportion of young water in streamflow. However, even where young water fractions in streamflow were low, the results from this study suggest that plants in this tropical environment are typically utilizing relatively recent rainfall as their water source.

This project supported the research of five graduate and four undergraduate students at USC, including a lead PhD student who produced many of the core findings from the research. A new field course in tropical hydrology and biogeochemistry was developed and taught twice in Peru, once online, and once in Colorado.


Last Modified: 07/08/2022
Modified by: A Joshua West

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