Award Abstract # 1349091
Collaborative research: A multi-tracer (U, S, B, and Sr) approach to fingerprint and quantify anthropogenic salinity sources in the semi-arid Rio Grande watershed

NSF Org: EAR
Division Of Earth Sciences
Recipient: THE UNIVERSITY OF TEXAS AT EL PASO
Initial Amendment Date: May 13, 2014
Latest Amendment Date: May 13, 2014
Award Number: 1349091
Award Instrument: Standard Grant
Program Manager: Enriqueta Barrera
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: May 15, 2014
End Date: April 30, 2018 (Estimated)
Total Intended Award Amount: $239,034.00
Total Awarded Amount to Date: $239,034.00
Funds Obligated to Date: FY 2014 = $239,034.00
History of Investigator:
  • Lin Ma (Principal Investigator)
    lma@utep.edu
Recipient Sponsored Research Office: University of Texas at El Paso
500 W UNIVERSITY AVE
EL PASO
TX  US  79968-8900
(915)747-5680
Sponsor Congressional District: 16
Primary Place of Performance: University of Texas at El Paso
TX  US  79902-5816
Primary Place of Performance
Congressional District:
16
Unique Entity Identifier (UEI): C1DEGMMKC7W7
Parent UEI: C1DEGMMKC7W7
NSF Program(s): Geobiology & Low-Temp Geochem,
International Research Collab
Primary Program Source: 01001415DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 5918
Program Element Code(s): 729500, 729800
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Broader significance.

Elevated salt content (salinity) in the Rio Grande River, which serves as a critical source of irrigation water in the semi-arid southwestern US, has led to severe reductions in crop productivity and an accumulation of salts in soils. These pressing salinity problems have also been observed for other arid rivers worldwide. In this study, the research team will determine the sources of salinity in the Rio Grande. This study has implications for informing land and water management practices, and as such can contribute to ensuring maintance of U.S. agriculture and the longevity of freshwater supplies. Notably, this work is applicable to understanding processes affecting salinity in related systems worldwide. In addition to the potential utility of this work for US agriculture and water resources, this has impact scientifically in that it focuses on the development of a new geochemical tool for understanding near-surface / surface water flow paths and transit times. This tool can potentially be applied to water systems across the US and beyond, again providing information that may assist in water resource management in both natural and managed systems.

This project will integrate expertise and resources in environmental isotope research from four institutions at both national and international levels: U. of Texas El Paso (UTEP; minority serving public university), U. of Arizona, U. of Tennessee, and the Institut de Physique du Globe de Paris (IPGP). By training two graduate and three undergraduate students, the project will contribute to the training of a future US STEM workforce. Notably, a UTEP student will also gain international professional experience by working with the IPGP in France with a highly-regarded top research group in isotope geochemistry. In addition to this international experience, the student will receive training in isotope geochemistry methods and will bring this knowledge back to the US research team. This international collaborative component of the work will be supported by NSF International Science and Engineering. Outreach activities will also bring cutting-edge research topics such as interactions between human and water, soils, and environments, as well as local pressing environmental problems to the attention of U.S. high school students, teachers and general public in the rapidly growing and diverse El Paso region.


Technical description.

The research will revisit an important salinity issue in the semi-arid portion of the lower Rio Grande watershed in New Mexico and Texas. The goals of this project are: 1) to fingerprint and quantify salinity sources in the lower Rio Grande in New Mexico and Texas using emerging isotopic (uranium), traditional isotopic (boron, sulfur, strontium), and elemental (major dissolved ions) tracers, with a concerted effort on understanding impacts related to human activities; and 2) to understand the controlling factors on uranium and sulfur isotope variations in natural streams in the Jemez River Basin Critical Zone Observatory (JRB-CZO), a headwater region of the Rio Grande with limited human activities. The combination of the above isotopic and solute tracers has particular resolving powers in distinguishing salinity from agriculture, urban activities, and geologic sources. The gained insights will improve our understanding of human impacts on water quality and elemental cycles, one of the most pressing issues facing the Earth Sciences community. This study will also advance our understanding of the controlling factors on uranium and sulfur isotope variations in headwater streams in the Jemez River Basin. Such information will provide an important natural baseline to understand human-impacted waters. With the multi-tracer approach, we will achieve the following objectives: 1) to characterize the U, S, B and Sr isotope and major element signatures in anthropogenic and natural salinity sources in the Rio Grande watershed; 2) to establish both spatial and temporal variations of these tracers in the Rio Grande and to quantify the contributions from various salinity end members with mass balance constraints; 3) to link U and S isotope variations in natural streams to different water sources that have evolved via different flow paths controlled by climatic, geological and hydrologic conditions.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 22)
Cox, Christine and Jin, Lixin and Ganjegunte, Girisha and Borrok, David and Lougheed, Vanessa and Ma, Lin "Soil quality changes due to flood irrigation in agricultural fields along the Rio Grande in western Texas" Applied Geochemistry , v.90 , 2018 10.1016/j.apgeochem.2017.12.019 Citation Details
Coyte, Rachel M. and Jain, Ratan C. and Srivastava, Sudhir K. and Sharma, Kailash C. and Khalil, Abedalrazq and Ma, Lin and Vengosh, Avner "Large-Scale Uranium Contamination of Groundwater Resources in India" Environmental Science & Technology Letters , v.5 , 2018 10.1021/acs.estlett.8b00215 Citation Details
Coyte, R.M., Jain, R.C., Srivastava, S.K., Sharma, K.C., Khalil, A., Ma, L., and Vengosh, A. "(2018), Large-scale uranium contamination of groundwater resources in India." Environmental Science & Technology Letters , 2018 doi:10.1021/acs.estlett8b00215
Garcia, V. H. and Ma, L. and Ricketts, J. W. and Dosseto, A. "Record of Neotectonics and Deep Crustal Fluid Circulation Along the Santa Fe Fault Zone in Travertine Deposits of the Lucero Uplift, New Mexico, USA" Geochemistry, Geophysics, Geosystems , v.22 , 2021 https://doi.org/10.1029/2020GC009454 Citation Details
Hiebing, Matthew and Doser, Diane I. and Avila, Victor M. and Ma, Lin "Geophysical studies of fault and bedrock control on groundwater geochemistry within the southern Mesilla Basin, western Texas and southern New Mexico" Geosphere , v.14 , 2018 10.1130/GES01567.1 Citation Details
Hiebing, M., Doser, D., Avila, V., and Ma, L. "Geophysical studies of fault and bedrock control on groundwater geochemistry within the southern Mesilla Basin, West Texas and southern New Mexico" Geosphere , v.14 , 2018 , p.doi:10.11 doi:10.1130/ges01567.1
Huckle, David and Ma, Lin and McIntosh, Jennifer and Vázquez-Ortega, Angélica and Rasmussen, Craig and Chorover, Jon "U-series isotopic signatures of soils and headwater streams in a semi-arid complex volcanic terrain" Chemical Geology , v.445 , 2016 10.1016/j.chemgeo.2016.04.003 Citation Details
Huckle, D*., Ma, L., McIntosh, J., Rasmussen, C., Chorover, J. "Characterizing U-series isotope signatures in soils and headwater streams in a complex volcanic terrain" Chemical Geology , v.445 , 2016 , p.68
Huckle, D., Ma, L., McIntosh, J., Vazquez-Ortega, A., Rasmussen, C., and Chorover, J. "U-series isotopic signatures of soils and headwater streams in a semi-arid complex volcanic terrain." Chemical Geology , v.445 , 2016 , p.68
Nyachoti, S., Jin, L., Tweedie, C., and Ma, L. "Insight into factors controlling formation rates of pedogenic carbonates: a combined geochemical and isotopic approach in dryland soils of the US Southwest." Chemical Geology , 2017 doi:10.1016/j.chemgeo.2017.10.014
Nyachoti, Syprose and Jin, Lixin and Tweedie, Craig E. and Ma, Lin "Insight into factors controlling formation rates of pedogenic carbonates: A combined geochemical and isotopic approach in dryland soils of the US Southwest" Chemical Geology , v.527 , 2019 10.1016/j.chemgeo.2017.10.014 Citation Details
(Showing: 1 - 10 of 22)

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

This research team integrates expertise and resources in environmental isotope research from four institutions at both national and international levels: Univ. of Texas at El Paso (UTEP; a minority serving public university), Univ. of Arizona, Univ. of Tennessee at, and Institut de Physique du Globe de Paris to investigate the sources of elevated salinity in the Rio Grande River, a critical resource of irrigation water in the semi-arid southwestern U.S. The project has created a comprehensive dataset of major and trace element concentrations, U, Sr, B, S, O and H isotope ratios for Rio Grande river water, groundwater, agricultural canal and drains, urban water samples in the Lower Rio Grande, as well as stream, spring, bedrock, soils, dust and deep drill core samples in the Jemez Spring Critical Zone Observatory in the headwater regions of Rio Grande.

The researchers and students revisited the important salinity issue in the semi-arid portion of the lower Rio Grande watershed in New Mexico and western Texas, with a “multi-line evidence” approach, using emerging isotopic (U), traditional isotopic (B, S, Sr, O, and H), and elemental (major/trace dissolved ions) tracers. Elevated salinity in Lower Rio Grande watershed is the result of multiple salinity contributors from natural and anthropogenic processes: both upwelling of deep saline groundwater and inputs from agricultural activity play important roles to contribute highly spatial and temporal variable salt loads to Rio Grande; near large cities, urban impacts to Rio Grande water chemistry is also important. Furthermore, our project results highlight a unique and novel use of (234U/238U) isotope ratio to trace agricultural source of salinity in watersheds due to the presence of U-series equilibrium signature in phosphorous fertilizers. Such an anthropogenic isotope tracer, in combination with other tracers such as B, Sr, S, O, H isotope ratios, can effectively distinguish anthropogenic sources from natural sources. (234U/238U) ratios in natural headwater streams also show large variations that are correlated to changes in stream flow paths, residence times, and mixing process, revealing its high potential to use as a natural isotope tracer of water residence time in watersheds.

Our multi-tracer approach to identify salinity sources in the Rio Grande River has broader impacts in the arid southwest U.S. and around the world for many arid rivers similarly experiencing great pressures on fresh water resources. We also advance understanding and application of the novel U isotopic tracer for near-surface/surface water systems in both natural and human impacted areas. Our project impacts minority students in the STEM fields and supported a total of 6 graduate students at M.S./Ph.D. levels and 4 undergraduate students to pursue their degrees in the STEM fields. At all of the four participating institutions, we made a strong effort to provide valuable research and educational experiences to our UTEP students. Our outreach activities also exposed high school students/teachers and general public in the rapidly growing and diverse El Paso region to both cutting-edge Critical Zone research topics (e.g. water, soils, human and environments) and pressing environmental problems facing the local community.

 

 


Last Modified: 07/20/2018
Modified by: Lin Ma

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