Award Abstract # 1215551
Early-concept grant for exploratory research (EAGER) proposal: Accessing the potential of clumped isotope thermometry to constrain temperatures in the Arctic during the Pliocene

NSF Org: OPP
Office of Polar Programs (OPP)
Recipient: UNIVERSITY OF CALIFORNIA, LOS ANGELES
Initial Amendment Date: March 21, 2012
Latest Amendment Date: March 21, 2012
Award Number: 1215551
Award Instrument: Standard Grant
Program Manager: William J. Wiseman, Jr.
OPP
 Office of Polar Programs (OPP)
GEO
 Directorate for Geosciences
Start Date: April 1, 2012
End Date: March 31, 2014 (Estimated)
Total Intended Award Amount: $235,903.00
Total Awarded Amount to Date: $235,903.00
Funds Obligated to Date: FY 2012 = $235,903.00
History of Investigator:
  • Aradhna Tripati (Principal Investigator)
    atripati@g.ucla.edu
  • Robert Eagle (Co-Principal Investigator)
Recipient Sponsored Research Office: University of California-Los Angeles
10889 WILSHIRE BLVD STE 700
LOS ANGELES
CA  US  90024-4200
(310)794-0102
Sponsor Congressional District: 36
Primary Place of Performance: University of California-Los Angeles
595 Charles E. Young Dr. East
Los Angeles
CA  US  90095-1567
Primary Place of Performance
Congressional District:
36
Unique Entity Identifier (UEI): RN64EPNH8JC6
Parent UEI:
NSF Program(s): ANT Earth Sciences,
ANS-Arctic Natural Sciences
Primary Program Source: 0100XXXXDB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 1079, 7916
Program Element Code(s): 511200, 528000
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.078

ABSTRACT

The specific goal of this research is to identify whether carbonate ?clumped isotope? thermometry can be applied to mollusks to accurately and precisely reconstruct temperatures in the Arctic. Previous work has shown that the occurrence of multiple rare isotope substitutions in carbonate minerals, also referred to as the ?clumping? of heavy isotopes into bonds with each other, is temperature dependent. This temperature proxy is also independent of the del-18O of water and the del-13C of dissolved inorganic carbon. Initial studies of biologically-precipitated calcite and aragonite by the PI and co-PI and collaborators indicate that the measurements of 13C-18O bond abundance should allow one to make a relatively assumption-free determination of the temperature at which a mineral formed. Although this new proxy looks promising, calibration of the clumped isotope thermometer at low temperatures (i.e., below 15°C) is limited. Therefore the utility of this proxy for climate reconstructions in the Arctic is unclear. This project will determine the accuracy and precision of the technique when applied to biological samples grown at Arctic temperatures and, consequently, the ability of this technique to assess paleo ocean temperatures in polar regions.

The instrumental record of temperature only goes back in time a few hundred years, at most. In order to understand the natural variability of temperature, either locally or globally, we require much longer records. To develop such records, we rely on proxy measurements for temperature. Use of such proxies requires assumptions and often imposes large error bars on the estimated temperature. This project will determine the usefulness of a new proxy in the polar regions.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Eagle, R., Eiler, J.M., Tripati, A.K., Ries, J.B., Freitas, P.S., Hiebenthal, C., Wanamaker, A.D., Taviani, M., Elliot, M., Richardson, C.A., Marenssi, S., Nakamura, K., Ramirez, P., and Roy, K. "The influence of temperature and seawater carbonate saturation state on 13C-18O bond ordering in bivalve mollusks." Biogeosciences Discuss. , v.10 , 2012 , p.157
Eagle, R., Eiler, J., Tripati, A., Ries, J., Freitas, P., Hiebenthal, C., Wanamaker Jr., A., Taviani, M., Elliot, M., Richardson, C., Marenssi, S., Nakamura, K., Ramirez, P., Roy, K. "The influence of temperature and seawater carbonate saturation state on 13C-18O bond ordering in bivalve mollusks" Biogeosciences , 2013 doi:10.5194/bgd-10-157-2013
Ferguson, J.E., Johnson, K.R., Santos, G., Meyer, L., Tripati, A. "Investigating ?13C and ?14C within Mytilus californianus shells as proxies of upwelling intensity" Geochemistry, Geophysics, Geosystems , 2013 doi:10.1002/ggge.20090
Gabitov, R., Rollion-Bard, C., Tripati A., Sadekov, A. "In situ study of boron content and ?11B fractionation between calcite and fluid at different crystal growth rates" Geochimica et Cosmochimica Acta , 2014 http://dx.doi.org/10.1016/j.gca.2014.04.014
Hill, P., Tripati, A., Schauble, E., "Theoretical constraints on the effects of pH, salinity, and temperature on clumped isotope signatures of dissolved inorganic carbon species and carbonate minerals" Geochimica et Cosmochimica Acta , 2014 doi.org/10.1016/j.gca.2013.06.018
Tang, J., Dietzel, M., Fernandez, A., Tripati, A., Rosenheim, B. "Evaluation of kinetic effects on clumped isotope fractionation during inorganic calcite precipitation" Geochimica et Cosmochimica Acta , v.134 , 2014 , p.120

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

The Arctic is exhibiting some of the most dramatic climate changes of any region on the planet in response to rising greenhouse gas levels. Climate change in this region has the potential to have far-reaching consequences. Many studies, including the Intergovernmental Panel on Climate Change (IPCC) reports, have highlighted past time intervals such as the early Pliocene as an analogue for the climate that could result from elevated greenhouse gas levels in the future. New reconstructions of Arctic temperatures are needed to constrain the extent to which global warming is amplified at high latitudes and to help assess the sensitivity of Earth’s climate to changing carbon dioxide levels.

Therefore the aim of this project was to conduct exploratory work on an untested but potentially transformative isotopic tool for the applied study of Arctic climate evolution.  This project set out to show that the technique can be usefully applied in the temperature range relevant for studying the climate history of polar environments when applied to a range of different carbonate materials.

We identified taxa that can be used for Arctic paleoclimate reconstructions, and determined the relationship between temperature and isotopic composition for modern samples. We also examined what methodologies should be used for sample preparation, and investigated the uncertainties associated with the method. The results were presented at scientific conferences and published in peer-reviewed journal articles.

This project supported several undergraduates from diverse backgrounds, as well as graduate students and a postdoctoral researcher who contributed to the project. We also discussed this work during outreach activities to school children and to the public. 


Last Modified: 06/03/2014
Modified by: Aradhna Tripati

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