
NSF Org: |
DMR Division Of Materials Research |
Recipient: |
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Initial Amendment Date: | August 11, 2011 |
Latest Amendment Date: | May 22, 2013 |
Award Number: | 1105437 |
Award Instrument: | Continuing Grant |
Program Manager: |
Daryl Hess
dhess@nsf.gov (703)292-4942 DMR Division Of Materials Research MPS Directorate for Mathematical and Physical Sciences |
Start Date: | September 15, 2011 |
End Date: | August 31, 2015 (Estimated) |
Total Intended Award Amount: | $300,000.00 |
Total Awarded Amount to Date: | $300,000.00 |
Funds Obligated to Date: |
FY 2012 = $100,000.00 FY 2013 = $100,000.00 |
History of Investigator: |
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Recipient Sponsored Research Office: |
1523 UNION RD RM 207 GAINESVILLE FL US 32611-1941 (352)392-3516 |
Sponsor Congressional District: |
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Primary Place of Performance: |
1523 UNION RD RM 207 GAINESVILLE FL US 32611-1941 |
Primary Place of
Performance Congressional District: |
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Unique Entity Identifier (UEI): |
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Parent UEI: |
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NSF Program(s): | CONDENSED MATTER & MAT THEORY |
Primary Program Source: |
01001213DB NSF RESEARCH & RELATED ACTIVIT 01001314DB NSF RESEARCH & RELATED ACTIVIT |
Program Reference Code(s): |
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Program Element Code(s): |
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Award Agency Code: | 4900 |
Fund Agency Code: | 4900 |
Assistance Listing Number(s): | 47.049 |
ABSTRACT
TECHNICAL SUMMARY
This award supports integrated research, education and outreach activities in theoretical condensed matter physics. The goal of this project is to study and model: 1) carrier-carrier, 2) carrier-phonon and 3) carrier-photon interactions in narrow gap compound semiconductor heterostructures such as indium antimonide/aluminum indium antimonide quantum wells and carbon based nanostructures. These materials are promising for our next generation of high speed transistors and detectors. Although seemingly very different, they share common features, 1) an energy-wavevector relationship that is linear for large wavevector, and 2) high room temperature mobilities.
This project involves calculating and modeling the time-dependent optical and transport properties of semiconductor nanostructures. Foci include:
1.) Single-walled carbon nanotubes and graphene. While the unusual DC transport properties of these materials have been previously studied, their dynamical properties are proving to be equally interesting. Coherent phonons in carbon nanotubes, graphene and graphene nanoribbons will be modeled.
2.) Narrow gap InSb heterostructures. With their small effective masses and large g-factors, these materials are excellent candidates for fast transistors or novel spintronic devices. The time-dependent optical properties of these materials will be calculated and modeled to gain information about the electronic and magnetic states and transport properties. Close coupling between theory and experiment will provide an understanding of the carrier, spin, and phonon dynamics.
Graduate students on this project will be trained in forefront research topics in the nanosciences including the fields of semiconductor physics, quantum optics, nanotube and nanoribbon physics, and transport theory. The students will get a chance to participate and interact with researchers both in the U.S. and also internationally. Results of their work will help determine which materials are optimal for future high speed nano-electronic devices and detectors.
NON-TECHNICAL SUMMARY
This award integrates research, education and outreach in theoretical condensed matter physics. The motivation of the project is to study and understand properties of two new classes of nanostructured materials that are promising materials for the next generation of high speed transistors, and optical sources and detectors. These materials are: 1.) structures made of carbon that resemble ribbons or tubes of nanoscale dimensions - some ten thousand times smaller than the width of a human hair - called carbon nanotubes and carbon nanoribbons, 2.) graphene which is a single layer of carbon atoms which resembles chickenwire on the nanoscale with carbon atoms arranged at the vertices, and 3.) nanoscale structures made of a compound composed of elements indium and antimony, called indium antimonide.
While these materials at first seem may seem very different, they share several common properties. In particular, their electronic properties are very similar and at room temperature, electrons in graphene and indium antimonide nanostructures can move faster and more easily than electrons in almost any other material including silicon and gallium arsenide. This offers hope that transistors based on these two materials may one day replace transistors based on silicon technology, currently used in today's computers.
The PI will investigate how electrons in carbon and indium antimonide nanostructures interact and scatter with 1.) other electrons, 2.) atoms that are moving in the nanostructures and 3.) electromagnetic radiation. The interaction with electromagnetic radiation is particularly intriguing since results suggest that these materials might be used to generate and detect electromagnetic radiation in the tera Hertz part of the spectrum which lies between microwaves and infrared light. Tera Hertz radiation is non-ionizing; one day sources of this radiation may replace X-rays in medical imaging with fewer harmful side effects.
Graduate students on this project will be trained in forefront research topics in the nanosciences including the fields of semiconductor physics, quantum optics, nanotube and nanoribbon physics, and transport theory. The students will get a chance to participate and interact with researchers both in the U.S. and also internationally. Results of their work will help determine which materials are optimal for future high speed nano-electronic devices and detectors.
PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH
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PROJECT OUTCOMES REPORT
Disclaimer
This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.
This project focused on theoretical research in condensed matter physics aimed at understanding electronic, transport, and optical properties of two new classes of nanostructured materials that are promising materials for the next generation of high speed transistors, optical and infra-red detectors and devices for spintronic applications (where the electron spin rather than its charge is used in the device). These materials are: 1) carbon based nanostructures (i.e. carbon nanotubes, carbon nanoribbons, and graphene) and 2) nanostructures based on the semiconductors InSb (Indium Antimonide) and InAs (Indium Arsenide).
We investigated how electrons in carbon, InSb and InAs nanostructures interact and scatter with 1) other electrons, 2) atomic vibrations in the nanostructures (similar to sound waves) and 3) electromagnetic radiation. We compared our theoretical calculations with measurements made by different experimental groups (Kono group at Rice, Santos group at Oklahoma, Hayes group at Washington University, Khodaparast group at Virginia Tech., and Bowers group at Florida). Information gained from these studies will be useful for developing future new high-speed electronic and optical devices.
This project also contributed to the development of human resources in physics at the undergraduate, graduate and postdoctoral levels. Dr. Dipta Saha, now working for a software firm in Gainesville, received his Ph.D. with support from this grant. Graduate students on this project were trained in forefront research topics in nanoscience and nanotechnology including the fields of semiconductor physics, quantum optics, nanotube and nanoribbon physics, and transport theory. Training of the students and researchers has enhanced our future workforce in a high technology field.
Research Highlights:
1. Chirality dependence of coherent phonon amplitudes in single-wall carbon nanotubes.
We simulated the ultrafast dynamics of laser-induced coherent phonons in single-wall carbon nanotubes photoexcited by ultrafast laser pulses. We found that the RBM coherent phonon amplitudes are very sensitive to changes in excitation energy and depend strongly on the nanotube chirality and can start coherent RBM vibrations by either expanding or shrinking their diameters. A guide for experimentalists is shown in Fig. 1.
2. Ultrafast Generation of Fundamental and Multiple-order Phonon Excitations in Highly-Enriched Single-Wall (6,5) Carbon Nanotubes.
We investigated coherent phonons generated in highly enriched (6,5) single-wall carbon nanotubes. We found that many coherent phonon modes were present apart from the dominant coherent RBM mode. A total of 14 such modes were clearly resolved and identified as shown in figure 2a. The observed modes were compared with our theoretical calculations to identify the observed peaks and determine the frequencies of individual and combined modes (figure 2b.)
3. Electron and Hole Active Cyclotron Resonance in Graphene.
Graphene provides an ideal arena for studying interactions between phonons, electrons, holes, and spins in two-dimensional systems. Dynamical quantities such as circularly polarized cyclotron resonance can have unusual properties, which result from the linear E vs. k electronic dispersion relation.
We calculated the cyclotron resaonance and compared with experiment to find:
i) Even an undoped sample will exhibit cyclotron resonance due to the...
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