Award Abstract # 1105437
Carrier, Phonon and THz Dynamics in Narrow Gap and Carbon Based Nanostructures

NSF Org: DMR
Division Of Materials Research
Recipient: UNIVERSITY OF FLORIDA
Initial Amendment Date: August 11, 2011
Latest Amendment Date: May 22, 2013
Award Number: 1105437
Award Instrument: Continuing Grant
Program Manager: Daryl Hess
dhess@nsf.gov
 (703)292-4942
DMR
 Division Of Materials Research
MPS
 Directorate for Mathematical and Physical Sciences
Start Date: September 15, 2011
End Date: August 31, 2015 (Estimated)
Total Intended Award Amount: $300,000.00
Total Awarded Amount to Date: $300,000.00
Funds Obligated to Date: FY 2011 = $100,000.00
FY 2012 = $100,000.00

FY 2013 = $100,000.00
History of Investigator:
  • Christopher Stanton (Principal Investigator)
    stanton@phys.ufl.edu
Recipient Sponsored Research Office: University of Florida
1523 UNION RD RM 207
GAINESVILLE
FL  US  32611-1941
(352)392-3516
Sponsor Congressional District: 03
Primary Place of Performance: University of Florida
1523 UNION RD RM 207
GAINESVILLE
FL  US  32611-1941
Primary Place of Performance
Congressional District:
03
Unique Entity Identifier (UEI): NNFQH1JAPEP3
Parent UEI:
NSF Program(s): CONDENSED MATTER & MAT THEORY
Primary Program Source: 01001112DB NSF RESEARCH & RELATED ACTIVIT
01001213DB NSF RESEARCH & RELATED ACTIVIT

01001314DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 6863, 7569, 7574, 9161, AMPP
Program Element Code(s): 176500
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.049

ABSTRACT

TECHNICAL SUMMARY

This award supports integrated research, education and outreach activities in theoretical condensed matter physics. The goal of this project is to study and model: 1) carrier-carrier, 2) carrier-phonon and 3) carrier-photon interactions in narrow gap compound semiconductor heterostructures such as indium antimonide/aluminum indium antimonide quantum wells and carbon based nanostructures. These materials are promising for our next generation of high speed transistors and detectors. Although seemingly very different, they share common features, 1) an energy-wavevector relationship that is linear for large wavevector, and 2) high room temperature mobilities.

This project involves calculating and modeling the time-dependent optical and transport properties of semiconductor nanostructures. Foci include:

1.) Single-walled carbon nanotubes and graphene. While the unusual DC transport properties of these materials have been previously studied, their dynamical properties are proving to be equally interesting. Coherent phonons in carbon nanotubes, graphene and graphene nanoribbons will be modeled.

2.) Narrow gap InSb heterostructures. With their small effective masses and large g-factors, these materials are excellent candidates for fast transistors or novel spintronic devices. The time-dependent optical properties of these materials will be calculated and modeled to gain information about the electronic and magnetic states and transport properties. Close coupling between theory and experiment will provide an understanding of the carrier, spin, and phonon dynamics.

Graduate students on this project will be trained in forefront research topics in the nanosciences including the fields of semiconductor physics, quantum optics, nanotube and nanoribbon physics, and transport theory. The students will get a chance to participate and interact with researchers both in the U.S. and also internationally. Results of their work will help determine which materials are optimal for future high speed nano-electronic devices and detectors.


NON-TECHNICAL SUMMARY

This award integrates research, education and outreach in theoretical condensed matter physics. The motivation of the project is to study and understand properties of two new classes of nanostructured materials that are promising materials for the next generation of high speed transistors, and optical sources and detectors. These materials are: 1.) structures made of carbon that resemble ribbons or tubes of nanoscale dimensions - some ten thousand times smaller than the width of a human hair - called carbon nanotubes and carbon nanoribbons, 2.) graphene which is a single layer of carbon atoms which resembles chickenwire on the nanoscale with carbon atoms arranged at the vertices, and 3.) nanoscale structures made of a compound composed of elements indium and antimony, called indium antimonide.

While these materials at first seem may seem very different, they share several common properties. In particular, their electronic properties are very similar and at room temperature, electrons in graphene and indium antimonide nanostructures can move faster and more easily than electrons in almost any other material including silicon and gallium arsenide. This offers hope that transistors based on these two materials may one day replace transistors based on silicon technology, currently used in today's computers.

The PI will investigate how electrons in carbon and indium antimonide nanostructures interact and scatter with 1.) other electrons, 2.) atoms that are moving in the nanostructures and 3.) electromagnetic radiation. The interaction with electromagnetic radiation is particularly intriguing since results suggest that these materials might be used to generate and detect electromagnetic radiation in the tera Hertz part of the spectrum which lies between microwaves and infrared light. Tera Hertz radiation is non-ionizing; one day sources of this radiation may replace X-rays in medical imaging with fewer harmful side effects.

Graduate students on this project will be trained in forefront research topics in the nanosciences including the fields of semiconductor physics, quantum optics, nanotube and nanoribbon physics, and transport theory. The students will get a chance to participate and interact with researchers both in the U.S. and also internationally. Results of their work will help determine which materials are optimal for future high speed nano-electronic devices and detectors.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 25)
Bhowmick, M.; Merritt, T. R.; Khodaparast, G. A.; Wessels, Bruce W.; McGill, Stephen A.; Saha, D.; Pan, X.; Sanders, G. D.; Stanton, C. J. "Time-resolved differential transmission in MOVPE-grown ferromagnetic InMnAs" PHYSICAL REVIEW B , v.85 , 2012 , p.125313
D. Saha ; R. Wood ; J. T. Tokarski ; L. A. McCarthy ; C. R. Bowers ; E. L. Sesti ; S. E. Hayes ; P. L. Kuhns ; S. A. McGill ; A. R. Reyes ; G. D. Sanders ; C. J. Stanton "Modeling optically pumped NMR and spin polarization in GaAs/AlGaAs quantum wells" SPIE NanoScience+ Engineering - Proc. SPIE 9167, Spintronics VII , v.9167 , 2014 , p.91670N 10.1117/12.2061101
G. D. Sanders, A. R. T. Nugraha, R. Saito, and C. J. Stanton "Coherent radial breathing like phonons in graphene nanoribbons" Phys. Rev. B , v.85 , 2012 , p.205401
Khodaparast, GA and Matsuda, YH and Saha, D and Sanders, GD and Stanton, CJ and Saito, H and Takeyama, S and Merritt, TR and Feeser, C and Wessels, BW and others "Cyclotron resonance in ferromagnetic InMnAs and InMnSb" Physical Review B , v.88 , 2013 , p.235204 http://dx.doi.org/10.1103/PhysRevB.88.235204
Khodaparast, Giti A.; Bhowmick, Mithun; Feeser, Caitlin; Wessels, Bruce W.; Saha, Dipta; Sanders, Gary D.; Stanton, Christopher J.; Drouhin, HJ; Wegrowe, JE; Razeghi, M "Time-resolved Spectroscopy of MOVPE-grown III-Mn-V Ferromagnetic Semiconductors" SPINTRONICS V , v.8461 , 2012 , p.84611O
Kim, J. -H.; Nugraha, A. R. T.; Booshehri, L. G.; Haroz, E. H.; Sato, K.; Sanders, G. D.; Yee, K. -J.; Lim, Y. -S.; Stanton, C. J.; Saito, R.; Kono, J. "Coherent phonons in carbon nanotubes and graphene" CHEMICAL PHYSICS , v.413 , 2013 , p.55-80
Layla G. Booshehri, Charles H. Mielke, Dwight G. Rickel, Scott A. Crooker, Qi Zhang, Lei Ren, Erik H. Hároz, Avinash Rustagi, Christopher J. Stanton, Zhong Jin, Zhengzong Sun, Zheng Yan, James M. Tour, and Junichiro Kono "Circular polarization dependent cyclotron resonance in large-area graphene in ultrahigh magnetic fields" Phys. Rev. B , v.85 , 2012 , p.205407
Lim, Yong-Sik and Nugraha, Ahmad RT and Cho, Sung-Jae and Noh, Min-Young and Yoon, Eun-Jin and Liu, Huaping and Kim, Ji-Hee and Telg, Hagen and Ha?roz, Erik H and Sanders, Gary D and others "Ultrafast Generation of Fundamental and Multiple-Order Phonon Excitations in Highly Enriched (6, 5) Single-Wall Carbon Nanotubes" Nano letters , v.14 , 2014 , p.1426--143 10.1021/nl404536b
M. Bhowmick, T. R. Merritt, G. A. Khodaparast, Bruce W. Wessels, Stephen A. McGill, D. Saha, X. Pan, G. D. Sanders, and C. J. Stanton "Time-resolved differential transmission in MOVPE-grown ferromagnetic InMnAs" Phys. Rev. B , v.85 , 2012 , p.125313
Noe, G. T.; Haugan, H. J.; Brown, G. J.; Sanders, G. D.; Stanton, C. J.; Kono, J. "Coherent phonon dynamics in short-period InAs/GaSb superlattices" SUPERLATTICES AND MICROSTRUCTURES , v.52 , 2012 , p.1071-1077
Nugraha, Ahmad RT and Rosenthal, EI and Hasdeo, Eddwi H and Sanders, Gary D and Stanton, Christopher J and Dresselhaus, Mildred S and Saito, Riichiro "Excitonic effects on coherent phonon dynamics in single-wall carbon nanotubes" Physical Review B , v.88 , 2013 , p.075440 http://dx.doi.org/10.1103/PhysRevB.88.075440
(Showing: 1 - 10 of 25)

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

This project focused on theoretical research in condensed matter physics aimed at understanding electronic, transport, and optical properties of two new classes of nanostructured materials that are promising materials for the next generation of high speed transistors, optical and infra-red detectors  and  devices for spintronic applications (where the electron spin rather than its charge is used in the device). These materials are: 1) carbon based nanostructures (i.e. carbon nanotubes, carbon nanoribbons, and graphene) and 2) nanostructures based on the semiconductors InSb (Indium Antimonide) and InAs (Indium Arsenide).

We investigated how electrons in carbon, InSb and InAs nanostructures interact and scatter with 1) other electrons, 2) atomic vibrations in the nanostructures (similar to sound waves) and 3) electromagnetic radiation. We compared our theoretical calculations with measurements made by different experimental groups (Kono group at Rice, Santos group at Oklahoma,  Hayes group at Washington University, Khodaparast group at Virginia Tech., and Bowers group at Florida). Information gained from these studies will be useful for developing future new high-speed electronic and optical devices.

This project also contributed to the development of human resources in physics at the undergraduate, graduate and postdoctoral levels. Dr. Dipta Saha, now working for a software firm in Gainesville, received his Ph.D. with support from this grant.  Graduate students on this project were trained in forefront research topics in nanoscience and nanotechnology including the fields of semiconductor physics, quantum optics, nanotube and nanoribbon physics, and transport theory. Training of the students and researchers has enhanced our future workforce in a high technology field.

Research Highlights:

1.  Chirality dependence of coherent phonon amplitudes in single-wall carbon nanotubes.

We simulated the ultrafast dynamics of laser-induced coherent phonons in single-wall carbon nanotubes photoexcited by ultrafast laser pulses.  We found that the RBM coherent phonon amplitudes are very sensitive to changes in excitation energy and depend strongly on the nanotube chirality and can start coherent RBM vibrations by either expanding or shrinking their diameters. A guide for experimentalists is shown in Fig. 1.

2. Ultrafast Generation of Fundamental and Multiple-order Phonon Excitations in Highly-Enriched Single-Wall (6,5)  Carbon Nanotubes.

We investigated coherent phonons generated in highly enriched (6,5) single-wall carbon nanotubes. We found that many coherent phonon modes were present apart from the dominant coherent RBM mode. A total of 14 such modes were clearly resolved and identified as shown in figure 2a.   The observed modes were compared with our theoretical calculations to identify the observed peaks and determine the frequencies of individual and combined modes (figure 2b.)

3.  Electron and Hole Active Cyclotron Resonance in Graphene.

Graphene provides an ideal arena for studying interactions between phonons, electrons, holes, and spins in two-dimensional systems. Dynamical quantities such as circularly polarized cyclotron resonance can have unusual properties, which result from the linear E  vs. k electronic dispersion relation. 

We calculated the cyclotron resaonance and  compared with experiment  to find:

i) Even  an undoped sample will exhibit cyclotron resonance due to the...

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