Award Abstract # 0953733
CAREER: Magnetocaloric Effect in Metallic Nanostructures

NSF Org: DMR
Division Of Materials Research
Recipient: UNIVERSITY OF SOUTH FLORIDA
Initial Amendment Date: February 10, 2010
Latest Amendment Date: March 28, 2014
Award Number: 0953733
Award Instrument: Continuing Grant
Program Manager: Gary Shiflet
DMR
 Division Of Materials Research
MPS
 Directorate for Mathematical and Physical Sciences
Start Date: April 1, 2010
End Date: February 28, 2015 (Estimated)
Total Intended Award Amount: $586,060.00
Total Awarded Amount to Date: $586,060.00
Funds Obligated to Date: FY 2010 = $114,259.00
FY 2011 = $112,600.00

FY 2012 = $116,074.00

FY 2013 = $113,280.00

FY 2014 = $0.00
History of Investigator:
  • Casey Miller (Principal Investigator)
    cwmsch@rit.edu
Recipient Sponsored Research Office: University of South Florida
4202 E FOWLER AVE
TAMPA
FL  US  33620-5800
(813)974-2897
Sponsor Congressional District: 15
Primary Place of Performance: University of South Florida
4202 E FOWLER AVE
TAMPA
FL  US  33620-5800
Primary Place of Performance
Congressional District:
15
Unique Entity Identifier (UEI): NKAZLXLL7Z91
Parent UEI:
NSF Program(s): CONDENSED MATTER PHYSICS,
METAL & METALLIC NANOSTRUCTURE
Primary Program Source: 01001011DB NSF RESEARCH & RELATED ACTIVIT
01001112DB NSF RESEARCH & RELATED ACTIVIT

01001213DB NSF RESEARCH & RELATED ACTIVIT

01001314DB NSF RESEARCH & RELATED ACTIVIT

01001415DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 1045, 1187, 7237, 7644, 9161, AMPP
Program Element Code(s): 171000, 177100
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.049

ABSTRACT

TECHNICAL SUMMARY: This research will advance understanding of the magnetocaloric effect through the fabrication and characterization of novel nanoscale heterostructures composed of magnetic metals. Geometric confinement and physical proximity will be used to perturb and understand the structure-property relationships governing the entropy at relevant phase transitions. Investigations will include composition gradients, finite size effects, tailored interfaces, and magnetic anisotropies. Physical properties of the artificially structured materials will be characterized by means ranging from standard magnetometry and diffraction techniques to synchrotron and neutron probes available through collaborations with US National Laboratories. These studies will help enable the design of materials with enhanced entropic properties, which will ultimately be relevant for highly efficient magnetic refrigeration.

NON-TECHNICAL SUMMARY: By fabricating otherwise standard materials in exotic nanostructures that do not exist in nature, it is possible to make new materials with properties superior to those of the individual materials. This will be accomplished by bringing the materials in contact at the nanoscale. Physical properties will be characterized using synchrotron and neutron scattering techniques at US National Laboratories and/or user facilities. Discoveries will be relevant to the emerging field of magnetocalorics, which has the potential for developing extremely high efficiency refrigeration using environmentally friendly refrigerants. The teaching and training of undergraduate and graduate students will be integrated into cutting edge interdisciplinary nanomagnetism research. Students will develop a network of future mentors, colleagues, and employers by disseminating work at conferences, participating in collaborations, and interacting with US National Laboratories. A scientific literature learning module will be formulated to increase undergraduates? scientific literacy, enable an easy and early transition into active research labs, and increase the quality of the undergraduate experience. USF's interdisciplinary Science, Technology, and Mathematics Education research cluster will help extend this module to other disciplines in order to reach a broad audience with interests ranging from the hard sciences to the health sciences.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Dogan Kaya, Pavel N. Lapa, Priyanga Jayathilaka, Hillary Kirby, Casey W. Miller andIgor V. Roshchin "Controlling exchange bias in FeMn with Cu" J. Appl. Phys. , v.113 , 2013 , p.17D717
Dustin D. Belyea Tiffany S. Santos and Casey W. Miller "Magnetocaloric effect in epitaxial La0.56Sr0.44MnO3 alloy and digital heterostructures" Journal of Applied Physics , v.111 , 2012 , p.07A935
H.F. Kirby, T.M.Eggers, P.B.Jayathilaka, S.M.Campbell, Casey W. Miller "Exchange bias of mu-metal thin films" Journal ofMagnetismandMagneticMaterials , v.324 , 2012 , p.4151?4154
H. Kirby, D. Belyea, J. Willman, and C. W. Miller "Effects of preparation conditions on the magnetocaloric properties of Gd thin films" J. Vac. Sci. Techol. A , v.31 , 2013 , p.031506 10.1116/1.4795817
M. S. Lucas, D. Belyea, C. Bauer, N. Bryant,E. Michel, Z. Turgut, S. O. Leontsev, J. Horwath, S. L. Semiatin, M. E. McHenry, and C. W. Miller "Thermomagnetic analysis of FeCoCrxNi alloys: Magnetic entropy of high-entropy alloys" J. Applied Physics , v.113 , 2012 , p.17A923 10.1063/1.4798340

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