Award Abstract # 0949191
Early Career: Acquisition of a gas source mass spectrometer, technical support, and outreach for research in paleoclimate

NSF Org: EAR
Division Of Earth Sciences
Recipient: UNIVERSITY OF CALIFORNIA, LOS ANGELES
Initial Amendment Date: March 16, 2011
Latest Amendment Date: February 16, 2012
Award Number: 0949191
Award Instrument: Standard Grant
Program Manager: David Lambert
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: March 15, 2011
End Date: February 28, 2014 (Estimated)
Total Intended Award Amount: $300,000.00
Total Awarded Amount to Date: $390,000.00
Funds Obligated to Date: FY 2011 = $300,000.00
FY 2012 = $90,000.00
History of Investigator:
  • Aradhna Tripati (Principal Investigator)
    atripati@g.ucla.edu
Recipient Sponsored Research Office: University of California-Los Angeles
10889 WILSHIRE BLVD STE 700
LOS ANGELES
CA  US  90024-4200
(310)794-0102
Sponsor Congressional District: 36
Primary Place of Performance: University of California-Los Angeles
10889 WILSHIRE BLVD STE 700
LOS ANGELES
CA  US  90024-4200
Primary Place of Performance
Congressional District:
36
Unique Entity Identifier (UEI): RN64EPNH8JC6
Parent UEI:
NSF Program(s): Instrumentation & Facilities,
Marine Geology and Geophysics,
Sedimentary Geo & Paleobiology
Primary Program Source: 01001112DB NSF RESEARCH & RELATED ACTIVIT
01001213DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s):
Program Element Code(s): 158000, 162000, 745900
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

0949191
Tripati

This award provides funding to acquire a gas-source, isotope-ratio mass spectrometer for the analysis of multiply substituted carbon dioxide isotopologues, which form the basis of the new carbonate ?clumped isotope? thermometer. Studies by the early career PI and collaborators during her postdoctoral research demonstrated that the instrumentation awarded here offers unparalleled opportunities for addressing a range of questions in paleoclimatology. For example, accurate constraints on past temperature are critical for documenting climate change and resolving its causes. Paleoclimate records also have the potential to inform us about the amplitude and regional pattern of climate change and about the processes responsible for such change. In addition to being essential to understanding the climate evolution of the Earth over a range of timescales, accurate records of temperature are relevant to outstanding questions in paleoceanography (constraining the density structure of the ocean in the past), biogeochemistry (the nature silicate weathering feedbacks), carbonate sedimentology (the burial and cementation history of reef carbonates), geobiology (the role of climate change in driving major speciation and extinction events in the Paleozoic), and tectonics (the elevation history of the Tibetan Plateau). The instrumentation will support the development of a state-of-the art lab at UCLA encouraging collaborative research projects with outside scientists, including state universities and non-Ph.D. granting institutions. The instrument will be integrated into research activities in the classroom, and utilized intensively by students in thesis research.

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PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 11)
Eagle, R., Eiler, J., A. Tripati, Ries, J., Freitas, P., Hiebenthal, C., Wanamaker Jr., A., Taviani, M., Elliot, M., Richardson, C., Marenssi, S., Nakamura, K., Ramirez, P., Roy, K. "The influence of temperature and seawater carbonate saturation state on 13C-18O bond ordering in bivalve mollusks" Biogeosciences , v.10 , 2013 , p.4591 doi:10.5194/bgd-10-157-2013
Eagle, R., Risi, C., Mitchell, J., Neelin, D., Eiler, J., Seibt, U., Li., G., A. Tripati "High regional climate sensitivity over continental China inferred from glacial-recent changes in temperature and the hydrologic cycle" Proceedings of the National Academy of Sciences , v.110 , 2013 , p.8813
Frantz, C., Petryshyn, V., Marenco, P., Tripati, A., Berelson, W., Corsetti, F. "Dramatic local environmental change during the Early Eocene Climatic Optimum detected using high-resolution analyses of Green River Formation stromatolites" Palaeogeography, Palaeoclimatology, Palaeoecology , v.405 , 2014 , p.1
Hill, P., Tripati, A., Schauble, E. "Theoretical constraints on the effects of pH, salinity, and temperature on clumped isotope signatures of dissolved inorganic carbon species and carbonate minerals" Geochimica et Cosmochimica Acta , v.125 , 2014 , p.610
Loyd S., Corsetti F., Eiler J., and Tripati A. "Determining the diagenetic conditions of concretion formation: Assessing temperatures and pore-waters using clumped isotopes" Journal of Sedimentary Research, , v.82 , 2012 , p.1006
Loyd, S., Dickson, J.A.D., Scholle, P., Tripati, A. "Extensive, uplift-related and non-fault-controlled spar precipitation in the Permian Capitan Formation" Sedimentary Geology , v.298 , 2013 , p.17
Loyd, Sean J.; Corsetti, Frank A.; Eiler, John M.; Tripati, Aradhna K. "DETERMINING THE DIAGENETIC CONDITIONS OF CONCRETION FORMATION: ASSESSING TEMPERATURES AND PORE WATERS USING CLUMPED ISOTOPES" JOURNAL OF SEDIMENTARY RESEARCH , v.82 , 2012 , p.1006-1016
R. Eagle, J. Eiler, A. Tripati, J. Ries, P. Freitas, C. Hiebenthal, A. Wanamaker Jr., M. Taviani, M. Elliot, S. Marenssi, K. Nakmura, P. Ramirez, K. Roy "The in?uence of temperature andseawater carbonate saturation state on13C-18O bond ordering in bivalve mollusks" Biogeosciences Discussions , v.10 , 2013 , p.157-194
Robert A. Eagle, Camille Risi, Jonathan L. Mitchell, John M. Eiler, Ulrike Seibt, J. David Neelin, Gaojun Li, and Aradhna K. Tripati "High regional climate sensitivity over continental China constrained by glacial-recent changes in temperature and the hydrological cycle" Proceedings of the National Academy of Sciences , v.110 , 2013 , p.8813-8818
Tang, J., Dietzel, M., Fernandez, A., Tripati, A., Rosenheim, B. "Evaluation of kinetic effects on clumped isotope fractionation during inorganic calcite precipitation" Geochimica et Cosmochimica Acta , v.134 , 2014 , p.120
Tripati, A. Sahany, S., Pittman, D., Eagle, R., Neelin, D., Mitchell, J., Beaufort, L. "Modern and glacial tropical snowlines controlled by sea surface temperature and atmospheric mixing" Nature Geoscience , v.7 , 2014 , p.205
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PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

This project supported the acquisition of instrumentation that forms the core of a state-of-the-art lab, one of the first in the world with the capability of measuring a rare isotopic species to sufficiently high precision that we can undertake studies of the geologic record of climate change. It provided novel, world-class instrumentation that is being heavily utilized by geoscientists that otherwise would not have access to such facilities. In doing so, this funding has promoted access for scientists from institutions all over the country to one of the most exciting developments in isotope geochemistry that has broad relevance throughout the geosciences.

The instrumentation was used to conduct research, to collect data for student thesis projects, to pursue collaborative and interdisciplinary projects, and to produce high-quality scientific results to address a number of outstanding questions. It has been used to conduct scientific research on the chemistry of minerals, the role of greenhouse gases on climate change, and the evolution of life.  Our findings are novel and relevant to isotope geochemistry, climate modeling, Earth’s climate and oceanic history, glaciology, geobiology, natural resources (both energy exploration and water resources), and sedimentary geology. We have generated a substantial amount of new calibration data that allow us to better understand calcification and mineral-formation processes in modern systems. We have documented new processes that are important to interpreting data fro geological systems. We have studied the climate history of the western US, the midwestern US, central China, and Indonesia, and examined water cycling and temperature. We have generated datasets on rocks that are relevant to petroleum geology and sedimentary geology. We have measured dinosaur eggshells and teeth to determine body temperatures in extinct organisms.

We have taught and trained a number of K-12 students, teachers, undergraduates, graduate students, and postdoctoral researchers. We have engaged the public, conducted community outreach to diverse groups, and exposed parents and children to cutting-edge science and technology. We have provided numerous scholarships to K-12 students, teachers, and undergraduates. We have heavily recruited Hispanic, Afro-Caribbean, Native American, and other minority groups to our laboratory. We have developed partnerships with local schools (K-12), CSU, and community colleges.

The project provided opportunities for graduate students, postdoctoral researchers, and undergraduates to perform research and to acquire new skills in the geosciences, including in geochemistry, geobiology, sedimentary geology, and paleoclimate. The instrument was used to train undergraduates (21 undergraduates at UCLA, 1 undergraduate from CSULA, 2 undergraduates from Imperial College), graduate (3 graduate students from UCLA, 18 graduate students from other universities), and postdoctoral researchers (5 postdoctoral researchers at UCLA, 1 from another university), high school students (7 students in total), high school teachers (3 in total), and for outreach to K-12 students and their families. It has been used for training and educational purposes in multiple courses including three undergraduate courses at UCLA, and an international graduate course in geobiology. We also have had several school groups visit the laboratory and learn about the instrumentation (including from Central High School, Markham Middle School, Marymount High School). 

The results have been published in peer-reviewed scientific journals, including 8 papers, one of which discussed climate change and was featured on NPR. 6 manuscripts are in review or submitted, and 7 manuscripts are in preparation. 


Last Modified: 06/02/2014
Modified by: Aradhna Tripati

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