Award Abstract # 0925624
Hybrid Organic-Inorganic Infrared Light-Emitting Devices using Group IV Semiconductor Nanoparticles

NSF Org: ECCS
Division of Electrical, Communications and Cyber Systems
Recipient: REGENTS OF THE UNIVERSITY OF MINNESOTA
Initial Amendment Date: July 30, 2009
Latest Amendment Date: July 30, 2009
Award Number: 0925624
Award Instrument: Standard Grant
Program Manager: Dominique Dagenais
ddagenai@nsf.gov
 (703)292-2980
ECCS
 Division of Electrical, Communications and Cyber Systems
ENG
 Directorate for Engineering
Start Date: September 1, 2009
End Date: August 31, 2013 (Estimated)
Total Intended Award Amount: $349,998.00
Total Awarded Amount to Date: $349,998.00
Funds Obligated to Date: FY 2009 = $349,998.00
ARRA Amount: $349,998.00
History of Investigator:
  • Russell Holmes (Principal Investigator)
    rholmes@umn.edu
  • Uwe Kortshagen (Co-Principal Investigator)
Recipient Sponsored Research Office: University of Minnesota-Twin Cities
2221 UNIVERSITY AVE SE STE 100
MINNEAPOLIS
MN  US  55414-3074
(612)624-5599
Sponsor Congressional District: 05
Primary Place of Performance: University of Minnesota-Twin Cities
2221 UNIVERSITY AVE SE STE 100
MINNEAPOLIS
MN  US  55414-3074
Primary Place of Performance
Congressional District:
05
Unique Entity Identifier (UEI): KABJZBBJ4B54
Parent UEI:
NSF Program(s): EPMD-ElectrnPhoton&MagnDevices
Primary Program Source: 01R00910DB RRA RECOVERY ACT
Program Reference Code(s): 0000, 101E, 103E, 6890, OTHR
Program Element Code(s): 151700
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.041

ABSTRACT

This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5)

The objective of this research is to realize efficient infrared electroluminescence using a hybrid organic-inorganic light-emitting device based on emissive group IV semiconductor nanoparticles including Si, Ge and Si1-xGex.

Intellectual Merit: Group IV semiconductor nanoparticles have the potential to be efficient and tunable photon sources in the infrared. To date, these systems have not been extensively studied in light-emitting devices. In this work, performance will be maximized by engineering the device architecture, processing conditions, and nanoparticle passivation length. Device performance will be correlated to nanoparticle film morphology using various microscopies. With an improved understanding of architecture and film morphology for Si-based light-emitting devices, other novel group IV systems will be investigated in order to provide multiple infrared light-emitters. The focus on group IV systems will broaden the study of nanoparticles for photonic device applications, and will also contribute to the basic understanding of radiative and non-radiative processes in these materials.

Broader Impact: The PIs have identified as a priority the education of high school, undergraduate and graduate students on issues relating to the synthesis of nanoscale systems and their optoelectronic properties. Programs are proposed including summer research experience for high school students and teachers, research opportunities for undergraduate students through programs at the University of Minnesota, and the integration of research results into undergraduate and graduate classes in Chemical Engineering and Materials Science and Mechanical Engineering. Results will be disseminated to industrial partners through the Industrial Partnership for Research in Interfacial and Materials Engineering, where both PIs are active participants.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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B.H. Jones, K.-Y. Cheng, R.J. Holmes, and T.P. Lodge "Nanoporous Poly(3,4-ethylenedioxythiophene) derived from polymeric bicontinuous microemulsion templates" Macromolecules , v.45 , 2012 , p.599
B.H. Jones, K.-Y. Cheng, R.J. Holmes, and T.P. Lodge "Nanoporous polyethylene thin films templated by polymeric bicontinuous microemulsions: Evolution of morphology on non-neutral substrates" ACS Appl. Mater. Interfaces , v.3 , 2011 , p.4101
B.H. Jones, K.-Y. Cheng, R.J. Holmes, T.P. Lodge "Nanoporous Poly(3,4-ethylenedioxythiophene) derived from polymeric bicontinuous microemulsion templates" Macromolecules , v.45 , 2012 , p.599
B.H. Jones, K.-Y. Cheng, R.J. Holmes, T.P. Lodge "Nanoporous polyethylene thin films templated by polymeric bicontinuous microemulsions: Evolution of morphology on non-neutral substrates" ACS Appl. Mater. Interfaces , v.3 , 2011 , p.4101
K.-Y. Cheng, R. Anthony, U.R. Kortshagen, R.J. Holmes "High efficiency silicon nanocrystal light-emitting devices" Nano Letters , v.11 , 2011 , p.1952
K.-Y. Cheng, R. Anthony, U.R. Kortshagen, R.J. Holmes "High-efficiency silicon nanocrystal light-emitting Devices" Nano Letters , v.11 , 2011 , p.5
K.-Y. Cheng, R. Anthony, U.R. Kortshagen, R.J. Holmes "Hybrid silicon nanocrystal-organic light-emitting devices for infrared electroluminescence" Nano Letters , v.10 , 2010 , p.1154
K.-Y. Cheng, R. Anthony, U.R. Kortshagen, R.J. Holmes "Hybrid silicon nanocrystal-organic light-emitting devices for infrared electroluminescence" Nano Letters , v.10 , 2010 , p.1154
R. Anthony, K.-Y. Cheng, Z.C. Holman, R.J. Holmes and U.R. Kortshagen "An all-gas-phase approach for the fabrication of silicon nanocrystal light-emitting devices" Nano Letters , v.12 , 2012 , p.2822
R.J. Anthony, K.-Y. Cheng, Z.C. Holman, R.J. Holmes, U.R. Kortshagen "An all-gas-phase approach for the fabrication of silicon nanocrystal light-emitting devices" Nano Letters , v.12 , 2012 , p.2822

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