
NSF Org: |
EAR Division Of Earth Sciences |
Recipient: |
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Initial Amendment Date: | April 16, 2010 |
Latest Amendment Date: | March 13, 2012 |
Award Number: | 0911685 |
Award Instrument: | Continuing Grant |
Program Manager: |
Thomas Torgersen
EAR Division Of Earth Sciences GEO Directorate for Geosciences |
Start Date: | April 15, 2010 |
End Date: | June 30, 2015 (Estimated) |
Total Intended Award Amount: | $270,179.00 |
Total Awarded Amount to Date: | $270,179.00 |
Funds Obligated to Date: |
FY 2011 = $96,434.00 FY 2012 = $87,982.00 |
History of Investigator: |
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Recipient Sponsored Research Office: |
6100 MAIN ST Houston TX US 77005-1827 (713)348-4820 |
Sponsor Congressional District: |
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Primary Place of Performance: |
6100 MAIN ST Houston TX US 77005-1827 |
Primary Place of
Performance Congressional District: |
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Unique Entity Identifier (UEI): |
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Parent UEI: |
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NSF Program(s): | Hydrologic Sciences |
Primary Program Source: |
01001112DB NSF RESEARCH & RELATED ACTIVIT 01001213DB NSF RESEARCH & RELATED ACTIVIT |
Program Reference Code(s): |
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Program Element Code(s): |
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Award Agency Code: | 4900 |
Fund Agency Code: | 4900 |
Assistance Listing Number(s): | 47.050 |
ABSTRACT
Soil charcoal has been shown to play a key role in the dynamics of nutrients in soils [e.g. Liang et al., 2006], but our understanding of the effects of charcoal on soil physical and chemical properties is quite limited. Particularly absent are both data and a conceptual framework to explain observed charcoal alteration of soil hydrologic properties. Understanding the effects of charcoal on soil is increasingly important because humans are changing soil charcoal content both unintentionally and intentionally, the first driven by fire management practices and land use change, and the second by intentional amendment of soil with charcoal to improve crop performance and sequester carbon.
We hypothesize that charcoal affects soil hydrologic properties through alteration of soil grain size, charge density, and hydrophobicity. We predict that grain size will change mechanical interactions (e.g., pore size, tortuosity), while charge density will change physico-chemical interactions which impact strength, soil water potential, and flow pathways. Hydrophobicity is a function of both surface chemistry and surface area (controlled partly by grain size and porosity), and will respond with changes in these properties. Charcoal grain size decreases and surface charge density increases with in situ weathering so the impacts will be vary significantly with time as charcoal is incorporated into the soil clay fraction, which itself can be altered by the release of inorganic materials during charcoal weathering.
We are conducting a series of experiments designed to determine the mechanisms through which charcoal affects hydrologically-relevant physical and chemical properties of soils. We are performing experiments with natural and laboratory soils mixed with charcoal, measuring (1) soil hydrophobicity, (2) surface and bulk chemistry of soils and charcoals, (3) saturated permeability, (4) soil water potential, and (5) soil tensile strength. Our ultimate goal is to develop a conceptual model of the soil-charcoal-water system.
PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH
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PROJECT OUTCOMES REPORT
Disclaimer
This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.
Charcoal is a natural component of almost all soils, and when it is present in high concentrations it provides important benefits, increasing soils' ability to store water, and sometimes changing soil texture and soil biology in ways that are helpful for both agricultural and natural ecosystems. Prior to this grant, little was understood about the physical mechanisms that allowed charcoal to provide helpful ecosystem services like soil water storage and soil carbon storage. Even without this information, many businesses and environmental groups were going forward with soil charcoal amendment (called biochar when made commercially and sustainably for intentional soil use). Businesses, farmers, and environmentalists hope that biochar will improve soil performance and sequester carbon.
Prior to the work done in this grant, very large variations had been observed in soil hydrological properties when charcoal was added, with sometimes opposite results occurring in different soils, or with different charcoals. The focus of this grant was the development of generalizable models to help better understand how charcoal acts to change soil properties, especially properties associated with water and carbon.
This research project focused on charcoal physical properties. We were particularly interested in soil hydraulic conductivity (a measure of the rate at which water drains through soils), because this property plays such an important role in retaining water in soil in environments prone to drought, and conversely in removing water from landscapes prone to flooding. We showed that charcoal amendment can both increase and decrease soil saturated hydraulic conductivity, with the direction of change dependent on the amending soil, the size of the charcoal particles, and the internal porosity of the charcoal particles. Separately we characterized how charcoal internal porosity varies with production conditions (biomass source and pyrolysis temperature). These results suggest that it will be possible for businesses to produce biochar in particle sizes and porosities targeted for specific needs, like helping farms survive drought and helping urban environments reduce flooding.
Two other physical properties that we studied were charcoal density and porosity, because the density and porosity of charcoal are key controllers of its landscape and hydrologic behavior. Density is important because materials with densities less than 1 g/cm3 are prone to floating and may be lost from soils to rivers after heavy rainfall. Porosity (the percent of a sample’s volume that is open space) is important because charcoal's internal pores create space for water and microbes, and can sometimes act to divert and/or slow water flow through soils. We showed that charcoals made from wood have porosities ranging from 55-85% (Brewer et al., 2014), and that charcoal density varies widely.
In this grant we accomplished the following:
1. Developed fast, cheap, safe techniques to measure charcoal density and porosity,
2. characterized these properties in the lab and in the field,
3. related them to saturated hydraulic conductivity and soil water potential, and
4. examined how they varied with environmental conditions.
We have collaborated with four local businesses and two energy companies during this project.
To date this proposal has resulted in 15 published papers, with 2 additional papers in review and 3 in preparation.
Brewer, C. E., Chuang, V. J., Masiello, C. A., Gonnermann, H., Gao, X., Dugan, B., et al. (2014). New approaches to measuring biochar density and porosity. Biomass and Bioenergy, 66(c), 176–185. http://doi.org/10.1016/j.biombioe.2014.03.059.
Last Modified: 12/31/2015
Modified by: Caroline A M...
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