Award Abstract # 0911685
The Effect of Charcoal on Soil Hydrologic Properties Under Natural and Elevated Concentrations

NSF Org: EAR
Division Of Earth Sciences
Recipient: WILLIAM MARSH RICE UNIVERSITY
Initial Amendment Date: April 16, 2010
Latest Amendment Date: March 13, 2012
Award Number: 0911685
Award Instrument: Continuing Grant
Program Manager: Thomas Torgersen
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: April 15, 2010
End Date: June 30, 2015 (Estimated)
Total Intended Award Amount: $270,179.00
Total Awarded Amount to Date: $270,179.00
Funds Obligated to Date: FY 2010 = $85,763.00
FY 2011 = $96,434.00

FY 2012 = $87,982.00
History of Investigator:
  • Caroline Masiello (Principal Investigator)
    masiello@rice.edu
  • Brandon Dugan (Co-Principal Investigator)
Recipient Sponsored Research Office: William Marsh Rice University
6100 MAIN ST
Houston
TX  US  77005-1827
(713)348-4820
Sponsor Congressional District: 09
Primary Place of Performance: William Marsh Rice University
6100 MAIN ST
Houston
TX  US  77005-1827
Primary Place of Performance
Congressional District:
09
Unique Entity Identifier (UEI): K51LECU1G8N3
Parent UEI:
NSF Program(s): Hydrologic Sciences
Primary Program Source: 01001011DB NSF RESEARCH & RELATED ACTIVIT
01001112DB NSF RESEARCH & RELATED ACTIVIT

01001213DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 1579
Program Element Code(s): 157900
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Soil charcoal has been shown to play a key role in the dynamics of nutrients in soils [e.g. Liang et al., 2006], but our understanding of the effects of charcoal on soil physical and chemical properties is quite limited. Particularly absent are both data and a conceptual framework to explain observed charcoal alteration of soil hydrologic properties. Understanding the effects of charcoal on soil is increasingly important because humans are changing soil charcoal content both unintentionally and intentionally, the first driven by fire management practices and land use change, and the second by intentional amendment of soil with charcoal to improve crop performance and sequester carbon.
We hypothesize that charcoal affects soil hydrologic properties through alteration of soil grain size, charge density, and hydrophobicity. We predict that grain size will change mechanical interactions (e.g., pore size, tortuosity), while charge density will change physico-chemical interactions which impact strength, soil water potential, and flow pathways. Hydrophobicity is a function of both surface chemistry and surface area (controlled partly by grain size and porosity), and will respond with changes in these properties. Charcoal grain size decreases and surface charge density increases with in situ weathering so the impacts will be vary significantly with time as charcoal is incorporated into the soil clay fraction, which itself can be altered by the release of inorganic materials during charcoal weathering.
We are conducting a series of experiments designed to determine the mechanisms through which charcoal affects hydrologically-relevant physical and chemical properties of soils. We are performing experiments with natural and laboratory soils mixed with charcoal, measuring (1) soil hydrophobicity, (2) surface and bulk chemistry of soils and charcoals, (3) saturated permeability, (4) soil water potential, and (5) soil tensile strength. Our ultimate goal is to develop a conceptual model of the soil-charcoal-water system.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

Note:  When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

(Showing: 1 - 10 of 28)
Sun, Hao; Hockaday, William C.; Masiello, Caroline A.; Zygourakis, Kyriacos "Multiple Controls on the Chemical and Physical Structure of Biochars" INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH , v.51 , 2012 , p.3587-3597
Barnes, Rebecca T and Gallagher, Morgan E and Masiello, Caroline A and Liu, Zuolin and Dugan, Brandon "{Biochar-Induced Changes in Soil Hydraulic Conductivity and Dissolved Nutrient Fluxes Constrained by Laboratory Experiments}" PLoS ONE , v.9 , 2014 , p.e108340 10.1371/journal.pone.0108340.s001
Brewer, Catherine E and Chuang, Victoria J and Masiello, Caroline A and Gonnermann, Helge and Gao, Xiaodong and Dugan, Brandon and Driver, Laura E and Pietro Panzacchi and Zygourakis, Kyriacos and Davies, Christian A "{New approaches to measuring biochar density and porosity}" Biomass and Bioenergy , v.66 , 2014 , p.176--185 10.1016/j.biombioe.2014.03.059
Brewer, C. E., Chuang, V. J., Masiello, C. A., Gonnermann, H., Gao, X., Dugan, B., Driver, L.E., Pnzacchi, P., Zyougrakis, K., Davies, C. "New approaches to measuring biochar density and porosity" Biomass and Bioenergy , 2014
C. Santín, S.H. Doerr, T. Dittmar, C.A. Masiello, E.S. Kane, M. Ohlson, J.M. de la Rosa, C.M. Preston "Towards a global assessment of pyrogenic carbon from vegetation fires" Global Change Biology , 2015
D.B. Wiedemeier, S. Abiven, W.C. Hockaday, M. Keiluweit, M. Kleber, C.A. Masiello, A.V. McBeath, P.S. Nico, L.A. Pyle, M.P. Schneider, R.J. Smernik, G.L.B. Wiesenberg, M.W.I. Schmidt "Aromaticity and degree of aromatic condensation of char" Organic Geochemistry , v.78 , 2015 , p.135 10.1016/j.orggeochem.2014.10.002
H. Sun, C.E. Brewer, C.A. Masiello, K. Zygourakis "Nutrient transport in soils amended with biochar: A transient model with two stationary phases and intraparticle diffusion" Industrial Engineering and Chemical Research , v.54 , 2015 , p.4123 10.1021/ie503893t
Kinney, T J and Masiello, C A and Dugan, B and Hockaday, W C and Dean, M R and ZYGOURAKIS, K and Barnes, R T "{Hydrologic properties of biochars produced at different temperatures}" Biomass and Bioenergy , v.41 , 2012 , p.34--43 10.1016/j.biombioe.2012.01.033
Kinney, T J and Masiello, C A and Dugan, B and Hockaday, W C and Dean, M R and ZYGOURAKIS, K and Barnes, R T "{Hydrologic properties of biochars produced at different temperatures}" Biomass and Bioenergy , v.41 , 2012 , p.34--43
Kinney, T. J., Masiello, C. A., Dugan, B., Hockaday, W. C., Dean, M. R., Zygourakis, K., & Barnes, R. T. "Hydrologic properties of biochars produced at different temperatures" Biomass and Bioenergy , v.41 , 2012 , p.34-43 10.1016/j.biombioe.2012.01.033
LeCroy, Chase and Masiello, Caroline A and Rudgers, Jennifer A and Hockaday, William C and Silberg, Jonathan J "{Nitrogen, biochar, and mycorrhizae: Alteration of the symbiosis and oxidation of the char surface}" Soil Biology and Biochemistry , v.58 , 2013 , p.248--254 10.1016/j.soilbio.2012.11.023
(Showing: 1 - 10 of 28)

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

Charcoal is a natural component of almost all soils, and when it is present in high concentrations it provides important benefits, increasing soils' ability to store water, and sometimes changing soil texture and soil biology in ways that are helpful for both agricultural and natural ecosystems.  Prior to this grant, little was understood about the physical mechanisms that allowed charcoal to provide helpful ecosystem services like soil water storage and soil carbon storage. Even without this information, many businesses and environmental groups were going forward with soil charcoal amendment (called biochar when made commercially and sustainably for intentional soil use).  Businesses, farmers, and environmentalists hope that biochar will improve soil performance and sequester carbon.

Prior to the work done in this grant, very large variations had been observed in soil hydrological properties when charcoal was added, with sometimes opposite results occurring in different soils, or with different charcoals.  The focus of this grant was the development of generalizable models to help better understand how charcoal acts to change soil properties, especially properties associated with water and carbon.

This research project focused on charcoal physical properties.  We were particularly interested in soil hydraulic conductivity (a measure of the rate at which water drains through soils), because this property plays such an important role in retaining water in soil in environments prone to drought, and conversely in removing water from landscapes prone to flooding.  We showed that charcoal amendment can both increase and decrease soil saturated hydraulic conductivity, with the direction of change dependent on the amending soil, the size of the charcoal particles, and the internal porosity of the charcoal particles.  Separately we characterized how charcoal internal porosity varies with production conditions (biomass source and pyrolysis temperature).  These results suggest that it will be possible for businesses to produce biochar in particle sizes and porosities targeted for specific needs, like helping farms survive drought and helping urban environments reduce flooding.

Two other physical properties that we studied were charcoal density and porosity, because the density and porosity of charcoal are key controllers of its landscape and hydrologic behavior. Density is important because materials with densities less than 1 g/cm3 are prone to floating and may be lost from soils to rivers after heavy rainfall.  Porosity (the percent of a sample’s volume that is open space) is important because charcoal's internal pores create space for water and microbes, and can sometimes act to divert and/or slow water flow through soils.  We showed that charcoals made from wood have porosities ranging from 55-85% (Brewer et al., 2014), and that charcoal density varies widely.

In this grant we accomplished the following:

1. Developed fast, cheap, safe techniques to measure charcoal density and porosity,

2. characterized these properties in the lab and in the field,

3. related them to saturated hydraulic conductivity and soil water potential, and

4. examined how they varied with environmental conditions.

We have collaborated with four local businesses and two energy companies during this project.

To date this proposal has resulted in 15 published papers, with 2 additional papers in review and 3 in preparation.

Brewer, C. E., Chuang, V. J., Masiello, C. A., Gonnermann, H., Gao, X., Dugan, B., et al. (2014). New approaches to measuring biochar density and porosity. Biomass and Bioenergy, 66(c), 176–185. http://doi.org/10.1016/j.biombioe.2014.03.059.


Last Modified: 12/31/2015
Modified by: Caroline A M...

Please report errors in award information by writing to: awardsearch@nsf.gov.

Print this page

Back to Top of page