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Award Abstract # 0722699
MRI: Acquisition of an XPS system for Interdisciplinary Research and Education

NSF Org: DMR
Division Of Materials Research
Recipient: BOISE STATE UNIVERSITY
Initial Amendment Date: August 9, 2007
Latest Amendment Date: April 7, 2009
Award Number: 0722699
Award Instrument: Standard Grant
Program Manager: Charles E. Bouldin
DMR
 Division Of Materials Research
MPS
 Directorate for Mathematical and Physical Sciences
Start Date: September 1, 2007
End Date: August 31, 2010 (Estimated)
Total Intended Award Amount: $0.00
Total Awarded Amount to Date: $564,000.00
Funds Obligated to Date: FY 2007 = $564,000.00
History of Investigator:
  • Dmitri Tenne (Principal Investigator)
    dmitritenne@boisestate.edu
  • Darryl Butt (Co-Principal Investigator)
  • Jerry Harris (Co-Principal Investigator)
  • Kevin Feris (Co-Principal Investigator)
  • Tomoko Fujiwara (Co-Principal Investigator)
  • Alex Punnoose (Former Principal Investigator)
Recipient Sponsored Research Office: Boise State University
1910 UNIVERSITY DR
BOISE
ID  US  83725-0001
(208)426-1574
Sponsor Congressional District: 02
Primary Place of Performance: Boise State University
1910 UNIVERSITY DR
BOISE
ID  US  83725-0001
Primary Place of Performance
Congressional District:
02
Unique Entity Identifier (UEI): HYWTVM5HNFM3
Parent UEI: HYWTVM5HNFM3
NSF Program(s): Major Research Instrumentation
Primary Program Source: app-0107 
Program Reference Code(s): 9150, 9161, AMPP
Program Element Code(s): 118900
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.049

ABSTRACT

Non-technical Abstract
This NSR-MRI proposal submitted jointly by Boise State University and Northwest Nazarene University in Idaho is to acquire a multi-user x-ray photoelectron spectroscopy (XPS) unit for shared use by researchers and students at both universities. XPS is a highly sensitive tool that can identify different elements present in a sample and determine their concentrations. Some of the research projects that will significantly benefit from the availability of XPS include efforts to produce magnetic behavior in semiconductors such as silicon, development of new materials to solve biological and biomedical research problems, relative movement of atoms inside a material when subjected to high temperatures, toxic and flammable gas detection, corrosion of surfaces, coating toxic materials with benign molecules, and magnetic materials. The proposed research activities of more than 16 faculty members, 15 postdoctoral fellows/scientists, 32 graduate students, and 80 undergraduate students from physics, chemistry, materials science, biology, electrical engineering, and geosciences will directly benefit from the availability of the XPS system. Being a widely used characterization technique in industry, XPS training will prepare students for industry positions. Availability of the XPS system will support the research activities of the graduate students in the recently started PhD programs in geosciences and electrical engineering, as well as new PhD programs being developed in the areas of materials science and biomolecular sciences at Boise State University.

Technical Abstract
This NSR-MRI proposal submitted jointly by Boise State University and Northwest Nazarene University in Idaho is to acquire a multi-user x-ray photoelectron spectroscopy (XPS) unit for shared use by researchers and students at both universities. XPS is a highly sensitive elemental analysis tool along with capabilities to determine the oxidation states of the elements, chemical bonding, and diffusion of atoms and ions. Some of the crucial research projects that would benefit from the availability of XPS include development of ferromagnetism in semiconductors for spintronics applications, interfacial reactions during oxidation and corrosion, novel magnetic gas sensing, studies of polymer-biomolecule interface, nanosensors, antibacterial agents and nanomedicinal applications using nanoparticles, biomolecular nanowire-based sensors, dye-sensitized solar cells and polymer-based chemical sensors. The proposed research activities of more than 16 faculty members, 15 postdoctoral fellows/scientists, 32 graduate students, and 80 undergraduate students from physics, chemistry, materials science, biology, electrical engineering, and geosciences will directly benefit from the availability of the XPS system. Being a widely used characterization technique in industry, XPS training will prepare students for industry positions. Availability of the XPS system will support the research activities of the graduate students in the recently started PhD programs in geosciences and electrical engineering, as well as new PhD programs being developed in the areas of materials science and biomolecular sciences at Boise State University.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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C. Sun, J. S. Gardner, E. Shurdha, K. R. Margulieux, R. D.Westover, L. Lau, G. Long, C. Bajracharya, C. Wang, A. Thurber, A. Punnoose, R. G. Rodriguez, and J. J. Pak "A High-Yield Synthesis of Chalcopyrite CuInS2 Nanoparticles with Exceptional Size Control" Journal of Nanomaterials , v.2009 , 2009 , p.748567 10.1155/2009/748567
C. Sun, J. S. Gardner, G. Long, C. Bajracharya, A. Thurber, A. Punnoose, R. G. Rodriguez, and J. J. Pak "Controlled Stoichiometry for Quaternary CuIn_xGa_{1-x}S2 Chalcopyrite Nanoparticles from Single-Source Precursors via Microwave Irradiation" Chemistry of Materials , v.22 , 2010 , p.2699 10.1021/cm100456t
K. Feris, C. Otto, J. Tinker, D. Wingett, A. Punnoose, A. Thurber, M. Kongara, M. Sabetian, B. Quinn, C. Hanna, and D. Pink "Electrostatic Interactions Affect Nanoparticle-Mediated Toxicity to Gram-Negative Bacterium Pseudomonas aeruginosa PAO1" Langmuir , v.26 , 2009 , p.4429 10.1021/la903491z
L. M. Johnson, A. Thurber, J. Anghel, M. Sabetian, M. H. Engelhard, D. A. Tenne, C. B. Hanna, and A. Punnoose "Transition metal dopants essential for producing ferromagnetism in metal oxide nanoparticles" Physical Review B , v.82 , 2010 , p.054419 10.1103/PhysRevB.82.054419
Wang, H; Wingett, D; Engelhard, MH; Feris, K; Reddy, KM; Turner, P; Layne, J; Hanley, C; Bell, J; Tenne, D; Wang, C; Punnoose, A "Fluorescent dye encapsulated ZnO particles with cell-specific toxicity for potential use in biomedical applications" JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE , v.20 , 2009 , p.11 View record at Web of Science 10.1007/s10856-008-3541-

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