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Award Abstract # 0608730
NER: Engineering the Molecule-Electrode Contact with Novel Molecular Tunnel Junctions

NSF Org: ECCS
Division of Electrical, Communications and Cyber Systems
Recipient: UNIVERSITY OF DELAWARE
Initial Amendment Date: June 16, 2006
Latest Amendment Date: June 16, 2006
Award Number: 0608730
Award Instrument: Standard Grant
Program Manager: Rajinder P. Khosla
ECCS
 Division of Electrical, Communications and Cyber Systems
ENG
 Directorate for Engineering
Start Date: July 1, 2006
End Date: June 30, 2008 (Estimated)
Total Intended Award Amount: $99,964.00
Total Awarded Amount to Date: $99,964.00
Funds Obligated to Date: FY 2006 = $99,964.00
History of Investigator:
  • Brian Willis (Principal Investigator)
    brian.willis@uconn.edu
Recipient Sponsored Research Office: University of Delaware
550 S COLLEGE AVE
NEWARK
DE  US  19713-1324
(302)831-2136
Sponsor Congressional District: 00
Primary Place of Performance: University of Delaware
550 S COLLEGE AVE
NEWARK
DE  US  19713-1324
Primary Place of Performance
Congressional District:
00
Unique Entity Identifier (UEI): T72NHKM259N3
Parent UEI:
NSF Program(s): NANOSCALE: EXPLORATORY RSRCH
Primary Program Source: app-0106 
Program Reference Code(s): 0000, 101E, 1676, 9150, OTHR
Program Element Code(s): 167600
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.041

ABSTRACT

The objective of this research is to investigate the influence of nanoelectrode atomic structure on the stability and electronic transport properties of molecular tunnel junctions. The approach is to use atomic layer engineering to control the nanoelectrode microstructure and to measure electrical properties of the molecular tunnel junctions. Experiments will control the atomic structure and chemical bonding in metal-molecule-metal junctions and measure physical, chemical, and electrical properties of the molecular junctions.

The intellectual merits of the proposed research are the science and engineering of active nanostructures. The engineering of molecular devices requires the understanding and control of charge transport through molecules at electrode-molecule junctions. Previous studies have contributed much understanding, but a rudimentary knowledge of how molecules position between nanoelectrodes, and the influence of atomic structure is lacking. The proposed research presents a novel experimental approach that will advance the knowledge of molecular devices.

The broader impacts of the proposed research include technology impacts and the integration of education and research. Technology impacts of the proposed work include the invention of new technologies based on molecular devices. Such technologies may enable active nanostructures that extend computing, electronic memory, bio-chemical sensing, or energy harvesting beyond the limits of modern technologies. The proposed research will generate new scientific understanding that will benefit society through active nanostructures that protect us from threats and improve our quality of living. Education impacts include the integration of undergraduate students in nanotechnology research, and curriculum development to build an educated workforce skilled in the area of nanotechnology.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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R. Gupta and B.G. Willis "Nanometer spaced electrodes using selective area atomic layer deposition" Appl. Phys. Lett , 2007
R. Gupta and B.G. Willis "Nanometer spaced electrodes using selective area atomic layer deposition" Virtual J. Nanoscale Sci. & Technol , 2007

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