Award Abstract # 0550234
Global Atmospheric Chemistry: Uncertainties and Errors; Modes and Parametric Models

NSF Org: AGS
Division of Atmospheric and Geospace Sciences
Recipient: UNIVERSITY OF CALIFORNIA IRVINE
Initial Amendment Date: March 7, 2006
Latest Amendment Date: February 8, 2009
Award Number: 0550234
Award Instrument: Continuing Grant
Program Manager: Anne-Marie Schmoltner
AGS
 Division of Atmospheric and Geospace Sciences
GEO
 Directorate for Geosciences
Start Date: March 15, 2006
End Date: September 30, 2010 (Estimated)
Total Intended Award Amount: $665,606.00
Total Awarded Amount to Date: $665,606.00
Funds Obligated to Date: FY 2006 = $157,208.00
FY 2007 = $161,331.00

FY 2008 = $173,253.00

FY 2009 = $173,814.00
History of Investigator:
  • Michael Prather (Principal Investigator)
    mprather@uci.edu
Recipient Sponsored Research Office: University of California-Irvine
160 ALDRICH HALL
IRVINE
CA  US  92697-0001
(949)824-7295
Sponsor Congressional District: 47
Primary Place of Performance: University of California-Irvine
160 ALDRICH HALL
IRVINE
CA  US  92697-0001
Primary Place of Performance
Congressional District:
47
Unique Entity Identifier (UEI): MJC5FCYQTPE6
Parent UEI: MJC5FCYQTPE6
NSF Program(s): Atmospheric Chemistry
Primary Program Source: app-0106 
app-0107 

01000809DB NSF RESEARCH & RELATED ACTIVIT

01000910DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): EGCH, 1309
Program Element Code(s): 152400
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Research will be continued on the basic properties of chemistry-transport models (CTMs), focusing on: (1) correction of the numerical error in CTMs due to grid resolution, and (2) chemical mode studies that include the derivation of a stratosphere-troposphere coupled chemistry mode and the formulation of a simplified (parametric) model having the same modes as the CTM. A new approach for calculating the numerical errors associated with grid resolution will be developed and tested. The results will be broadly applicable to all CTMs, and will not only characterize the resolution errors but may also be used to help correct them. The existence of global chemical modes in CTMs will be used as a fundamental diagnostic of the models. The tropospheric chemical mode that describes decadal perturbations to methane will be coupled, for the first time in a CTM, with the century-long stratospheric mode involving nitrous oxide and ozone. Global chemical modes will be used to develop reduced-dimension parametric models using sensitivity calculations with a CTM. A reduced-dimension Jacobian will be calculated that completely defines the parametric model and can be compared with the modes of the full CTM.

Broader impacts range from improving the atmospheric chemistry/composition elements in Earth system models to providing more accurate scientific input on global change. The quantification of even one component of uncertainty in projecting atmospheric composition should benefit Earth system models and their policy applications. This project will also help prepare undergraduate students, doctoral students, and post-docs working in atmospheric chemistry with the mathematical skills needed to diagnose and analyze complex Earth system models.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 33)
Prather, M.J., "Lifetimes and time-scales in atmospheric chemistry," Phil. Trans. R. Soc. London series A , v.365 , 2007 , p.1705 10.1098/rsta.2007.2040
Prather, MJ "Tropospheric O-3 from photolysis of O-2" GEOPHYSICAL RESEARCH LETTERS , v.36 , 2009 View record at Web of Science 10.1029/2008GL03685
Prather, M. J. "Tropospheric O3 from photolysis of O2" GRL , 2008
Prather, M.J., "Lifetimes and time-scales in atmospheric chemistry," Phil. Trans. R. Soc. A , v.365 , 2007 , p.1705?1726
A. Ito, J. E. Penner, M. J. Prather, C. P. de Campos, R. A. Houghton, T. Kato, A. K. Jain, X. Yang,G. C. Hurtt, S. Frolking, M. G. Fearon, L. P. Chini, A. Wang, D. T. Price "Can we reconcile differences in estimates of carbon fluxes from land-use change and forestry for the 1990s?" Atmos. Chem. Phys , v.8 , 2008 , p.3291
Anenberg, SC; West, JJ; Fiore, AM; Jaffe, DA; Prather, MJ; Bergmann, D; Cuvelier, K; Dentener, FJ; Duncan, BN; Gauss, M; Hess, P; Jonson, JE; Lupu, A; MacKenzie, IA; Marmer, E; Park, RJ; Sanderson, MG; Schultz, M; Shindell, DT; Szopa, S; Vivanco, MG; Wild "Intercontinental Impacts of Ozone Pollution on Human Mortality" ENVIRONMENTAL SCIENCE & TECHNOLOGY , v.43 , 2009 , p.6482 View record at Web of Science 10.1021/es900518
Gauss, M; Myhre, G; Isaksen, ISA; Grewe, V; Pitari, G; Wild, O; Collins, WJ; Dentener, FJ; Ellingsen, K; Gohar, LK; Hauglustaine, DA; Iachetti, D; Lamarque, JF; Mancini, E; Mickley, LJ; Prather, MJ; Pyle, JA; Sanderson, MG; Shine, KP; Stevenson, DS; Sudo, "Radiative forcing since preindustrial times due to ozone change in the troposphere and the lower stratosphere" ATMOSPHERIC CHEMISTRY AND PHYSICS , v.6 , 2006 , p.575 View record at Web of Science
Hoor, P; Borken-Kleefeld, J; Caro, D; Dessens, O; Endresen, O; Gauss, M; Grewe, V; Hauglustaine, D; Isaksen, ISA; Jockel, P; Lelieveld, J; Myhre, G; Meijer, E; Olivie, D; Prather, M; Poberaj, CS; Shine, KP; Staehelin, J; Tang, Q; van Aardenne, J; van Velt "The impact of traffic emissions on atmospheric ozone and OH: results from QUANTIFY" ATMOSPHERIC CHEMISTRY AND PHYSICS , v.9 , 2009 , p.3113 View record at Web of Science
Hsu, J., M.J. Prather "Stratospheric Variability and Tropospheric Ozone" J. Geophys. Res , 2008
Hsu, J; Prather, MJ "Global long-lived chemical modes excited in a 3-D chemistry transport model: Stratospheric N2O, NOy, O-3 and CH4 chemistry" GEOPHYSICAL RESEARCH LETTERS , v.37 , 2010 View record at Web of Science 10.1029/2009GL04224
Hsu, J; Prather, MJ "Stratospheric variability and tropospheric ozone" JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES , v.114 , 2009 View record at Web of Science 10.1029/2008JD01094
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