Award Abstract # 0549829
Collaborative Research: Organic Geochemical Investigation of the Rainbow Hydrothermal System, Mid-Atlantic Ridge

NSF Org: OCE
Division Of Ocean Sciences
Recipient: WOODS HOLE OCEANOGRAPHIC INSTITUTION
Initial Amendment Date: February 28, 2006
Latest Amendment Date: August 13, 2008
Award Number: 0549829
Award Instrument: Continuing Grant
Program Manager: Barbara Ransom
bransom@nsf.gov
 (703)292-7792
OCE
 Division Of Ocean Sciences
GEO
 Directorate for Geosciences
Start Date: March 15, 2006
End Date: February 28, 2010 (Estimated)
Total Intended Award Amount: $0.00
Total Awarded Amount to Date: $411,841.00
Funds Obligated to Date: FY 2006 = $143,241.00
FY 2007 = $125,357.00

FY 2008 = $143,243.00
History of Investigator:
  • Jeffrey Seewald (Principal Investigator)
    jseewald@whoi.edu
  • Chris German (Co-Principal Investigator)
Recipient Sponsored Research Office: Woods Hole Oceanographic Institution
266 WOODS HOLE RD
WOODS HOLE
MA  US  02543-1535
(508)289-3542
Sponsor Congressional District: 09
Primary Place of Performance: Woods Hole Oceanographic Institution
266 WOODS HOLE RD
WOODS HOLE
MA  US  02543-1535
Primary Place of Performance
Congressional District:
09
Unique Entity Identifier (UEI): GFKFBWG2TV98
Parent UEI:
NSF Program(s): Marine Geology and Geophysics
Primary Program Source: app-0106 
app-0107 

01000809DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 0000, OTHR
Program Element Code(s): 162000
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

ABSTRACT: Seewald/McCollum (0549829/0550800)

The fate of carbon in submarine hot springs has broad implications for a diverse spectrum of chemical, physical, and biological processes occurring within the oceanic crust and water column. Nevertheless, the composition and source of organic compounds in submarine hydrothermal fluids remains poorly known. As a result, this research investigates the origin of organic compounds at the Rainbow hydrothermal system, which is hosted in ultramafic rocks on the Mid-Atlantic Ridge. The site was chosen because ultramafic rocks may play a pivotal role in the abiotic synthesis of aqueous organic compounds because they contain catalytically active minerals and create reducing chemical environments during reaction with seawater-derived hydrothermal fluids. Gases and organic compounds from Rainbow hydrothermal fluids will be analyzed chemically and isotopically, as will their associated sulfide minerals. In particular analyses will target amino acids, carboxylic acids, ammonia, and high molecular weight hydrocarbons. Geochemical analyses of minerals and other inorganic constituents will also be carried out. Results will be modeled using thermodynamics and interpreted in light of laboratory experiments that will allow interpretation of the origin (abiotic, thermal cracking, mantle degassing, or microbial) of the organic compounds. Broader impacts of this work include education and training of students at Woods Hole Oceanographic Institution and the University of Colorado, as well as engaging students who are under represented in the sciences from Bridgewater State College. The work also fosters international collaboration with the National Oceanographic Centre in the UK by bringing one of its students to Woods Hole to work on the project for an extended stay.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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McCollom T.M. and Seewald J.S. "Abiotic synthesis of organic compounds in deep-sea hydrothermal environments." Chem. Rev. , v.107 , 2007 , p.382
Proskurowski, G., Lilley, M.D., Seewald, J.S., Olson, E.J., Früh-Green, G.L., Lupton, J.E., Sylva, S.P., Kelley, D.S. "Abiogenic Hydrogen and Hydrocarbon Production at the Lost City Hydrothermal Field" Science , v.319 , 2008 , p.604
Reeves E. "Laboratory and field-based investigations of subsurface geochemical" Ph.D. Thesis, MIT/WHOI Joint Program in Chemical Oceanography , 2010 , p.279

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