Award Abstract # 0440226
The Group 5A Pathfinder Elements: Experiments in Magma-Volatile Systems

NSF Org: EAR
Division Of Earth Sciences
Recipient: UNIVERSITY OF MARYLAND, COLLEGE PARK
Initial Amendment Date: December 14, 2004
Latest Amendment Date: December 6, 2007
Award Number: 0440226
Award Instrument: Continuing Grant
Program Manager: Sonia Esperanca
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: January 1, 2005
End Date: June 30, 2008 (Estimated)
Total Intended Award Amount: $0.00
Total Awarded Amount to Date: $229,649.00
Funds Obligated to Date: FY 2005 = $106,030.00
FY 2006 = $123,619.00
History of Investigator:
  • Philip Piccoli (Principal Investigator)
    piccoli@umd.edu
  • Philip Candela (Co-Principal Investigator)
Recipient Sponsored Research Office: University of Maryland, College Park
3112 LEE BUILDING
COLLEGE PARK
MD  US  20742-5100
(301)405-6269
Sponsor Congressional District: 04
Primary Place of Performance: University of Maryland, College Park
3112 LEE BUILDING
COLLEGE PARK
MD  US  20742-5100
Primary Place of Performance
Congressional District:
04
Unique Entity Identifier (UEI): NPU8ULVAAS23
Parent UEI: NPU8ULVAAS23
NSF Program(s): Petrology and Geochemistry
Primary Program Source: app-0105 
app-0106 
Program Reference Code(s): 0000, OTHR
Program Element Code(s): 157300
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Piccoli and Candela will study the behavior of As and Bi in magmatic hydrothermal systems. The chemistry of these elements at high temperature and moderate pressure is poorly known, yet in porphyry ore-deposits they serve as important pathfinder elements-elements used to determine potential targets for mining. To this end, the PIs will perform two types of experiments: 1) Experiments on the partitioning of As and Bi between felsic melts and KCl-NaCl-HCl +/-sulfide brine and vapor at 100 MPa and 800oC (some experiments will be performed in sulfide-saturated systems); 2) Experiments at 1000oC in sealed silica tubes to determine the partitioning of As and Bi between pyrrhotite and Fe-S-O melt.

Piccoli and Candela are collecting fundamental data on the behavior of As and Bi in the crust of the Earth. These data can be used to serve as the basis for studies of their redistribution in the crust and serve as exploration models for porphyry deposits. This research will involve a mix of high school, undergraduate, masters and doctoral students in our research, and graduate students will participate to a large degree in mentoring more junior members of our research team. Additionally, our research team will spearhead (and highlight our research in) our departmental effort for a university open house in the spring, an event that typically draws 60,000 people to the University of Maryland Campus from the local community.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Simon, AC; Frank, MR; Pettke, T; Candela, PA; Piccoli, PM; Heinrich, CA; Glascock, M "An evaluation of synthetic fluid inclusions for the purpose of trapping equilibrated, coexisting, immiscible fluid phases at magmatic conditions" AMERICAN MINERALOGIST , v.92 , 2007 , p.124 View record at Web of Science 10.2138/am.2007.206
Simon, A.C., Pettke, T., Candela, P.A., Piccoli, P. and Heinrich "The partitioning behavior of As and Au in a haplogranite - vapor at magmatic conditions in sulfur-free and sulfur-bearing systems." Geochimica et Cosmochimica Acta. , v.71 , 2007 , p.1764
Simon, AC; Pettke, T; Candela, PA; Piccoli, PM; Heinrich, CA "The partitioning behavior of As and Au in S-free and S-bearing magmatic assemblages" GEOCHIMICA ET COSMOCHIMICA ACTA , v.71 , 2007 , p.1764 View record at Web of Science 10.1016/j.gca.2007.01.00
Simon, AC; Pettke, T; Candela, PA; Piccolli, PM; Heinrich, CA "Copper partitioning in a melt-vapor-brine-magnetite-pyrrhotite assemblage" GEOCHIMICA ET COSMOCHIMICA ACTA , v.70 , 2006 , p.5583 View record at Web of Science 10.1016/j.gca.2006.08.04
Simon, AC; Pettke, T; Candela, P; Piccoli, P; Heinrich, C "Gold and arsenic partitioning at magmatic conditions" GEOCHIMICA ET COSMOCHIMICA ACTA , v.70 , 2006 , p.A591 View record at Web of Science 10.1016/j.gca.2006.06.109
Wilmot, M., Candela, P., Piccoli, P., Simon, A. and McDonough, W. "Examination of the behavior of bismuth in shallow-level hydrothermal ore-systems: Constraints based on hydrothermal experiments at 800C and 100MPa" EOS Transactions of the American Geophysical Union , v.87 , 2006 , p.U41-A04
Wilmot, M., Candela, P., Piccoli, P., Simon, A., and McDonough, W. "Preliminary study of bismuth partitioning in mineral-melt systems." GSA Abstracts with Programs , v.38 , 2006 , p.245

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