Award Abstract # 0408986
Sulfate 17O Anomalies in Cenozoic Volcaniclastic Deposits in the Northern High Plains, North America

NSF Org: EAR
Division Of Earth Sciences
Recipient: LOUISIANA STATE UNIVERSITY
Initial Amendment Date: May 27, 2004
Latest Amendment Date: May 27, 2004
Award Number: 0408986
Award Instrument: Standard Grant
Program Manager: Sonia Esperanca
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: June 1, 2004
End Date: May 31, 2007 (Estimated)
Total Intended Award Amount: $200,000.00
Total Awarded Amount to Date: $200,000.00
Funds Obligated to Date: FY 2004 = $200,000.00
History of Investigator:
  • Huiming Bao (Principal Investigator)
    bao@lsu.edu
Recipient Sponsored Research Office: Louisiana State University
202 HIMES HALL
BATON ROUGE
LA  US  70803-0001
(225)578-2760
Sponsor Congressional District: 06
Primary Place of Performance: Louisiana State University
202 HIMES HALL
BATON ROUGE
LA  US  70803-0001
Primary Place of Performance
Congressional District:
06
Unique Entity Identifier (UEI): ECQEYCHRNKJ4
Parent UEI:
NSF Program(s): Petrology and Geochemistry,
EPSCoR Co-Funding
Primary Program Source: app-0104 
04000405DB NSF Education & Human Resource
Program Reference Code(s): 9150, 9196, EGCH
Program Element Code(s): 157300, 915000
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

The PI proposes to examine the hypothesis that a series of extreme dry fogs probably delivered a large quantity of sulfate to the northern High Plains, North America, during the peak of the Great Basin volcanism ~ 28 million years ago. The hypothesis is based on a unique type of stable isotope signature, an array of positive sulfate 17O anomalies found in Oligocene volcanic ash beds in the region. This discovery and the proposed interpretation have generated interest, as well as debates on the possibility of past abnormal atmospheric events being recorded by rocks versus alternative explanations of the sulfate 17O anomalies. The PI and his students will (1) map out the spatial heterogeneity of sulfate deposition and isotope compositions at the type locality of the Gering Formation, (2) examine the sedimentological, mineralogical, and diagenetic factors that resulted in the preservation of the anomalous sulfate in the Gering Formation, (3) study a depositional sequence of normal playa sulfate at Wolf Butte, Nebraska, to compare to the abnormal sequence in Scotts Bluff, Nebraska, and (4) establish a temporal pattern of volcanic sulfate deposition in a neighboring locality: Badlands National Park, South Dakota. The aim of these tasks will be to provide sedimentological and geochemical evidence to constrain particular chemical pathways, deposition mode, climatic condition, and diagenetic processes that may be responsible for the 17O-anomalous sulfate in many of the ash beds in the northern High Plains. This project will provide students opportunities to learn a broad spectrum of Earth science, as well as provide the general public educational materials at popular national monuments and parks. If indeed a series of extreme dry fogs occurred in the past, studying these unusual geological events will help civilization prepare for the next big one.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Bao HM* "Purifying synthetic barite for oxygen isotope measurement by dissolution and reprecipitation in a chelating solution" Analytical Chemistry , v.78 , 2006 , p.304
Bao HM* "Sulfate in modern playa settings and in ash beds in hyperarid deserts: Implication on the origin of 17O-anomalous sulfate in an Oligocene ash bed" Chemical Geology , v.214 , 2005 , p.127
Howell, K. J. and Bao, HM "Caliche as a geological repository for atmospheric sulfate" Geophysical Research Letters , v.33 , 2006 ISI:000239215800008
Jenkins, KA; Bao, HM "Multiple oxygen and sulfur isotope compositions of atmospheric sulfate in Baton Rouge, LA, USA" ATMOSPHERIC ENVIRONMENT , v.40 , 2006 , p.4528 View record at Web of Science 10.1016/j.atmosenv.2006.04.01
Loope, DB; Mason, JA; Bao, HM; Kettler, RM; Zanner, CW "Deformation structures and an alteration zone linked to deposition of volcanogenic sulphate in an ancient playa (Oligocene of Nebraska, USA)" SEDIMENTOLOGY , v.52 , 2005 , p.123 View record at Web of Science 10.1111/j.1365-3091.2004.00689.

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