Award Abstract # 0403960
Collaborative Research: Assessing the Variability and Modification of Age, Character and Reactivity of Organic Carbon Delivered by Rivers and Estuaries to an Ocean Margin

NSF Org: EAR
Division Of Earth Sciences
Recipient: UNIVERSITY OF MASSACHUSETTS
Initial Amendment Date: June 3, 2004
Latest Amendment Date: June 11, 2007
Award Number: 0403960
Award Instrument: Standard Grant
Program Manager: Enriqueta Barrera
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: September 15, 2004
End Date: August 31, 2008 (Estimated)
Total Intended Award Amount: $0.00
Total Awarded Amount to Date: $229,650.00
Funds Obligated to Date: FY 2004 = $225,339.00
FY 2007 = $4,311.00
History of Investigator:
  • Steven Petsch (Principal Investigator)
    spetsch@umass.edu
Recipient Sponsored Research Office: University of Massachusetts Amherst
101 COMMONWEALTH AVE
AMHERST
MA  US  01003-9252
(413)545-0698
Sponsor Congressional District: 02
Primary Place of Performance: University of Massachusetts Amherst
101 COMMONWEALTH AVE
AMHERST
MA  US  01003-9252
Primary Place of Performance
Congressional District:
02
Unique Entity Identifier (UEI): VGJHK59NMPK9
Parent UEI: VGJHK59NMPK9
NSF Program(s): EDUCATION AND HUMAN RESOURCES,
BE-UF: CARBON CYCLE
Primary Program Source: app-0104 
app-0107 
Program Reference Code(s): 1389, 1689, 4444, 7285, 7306, 9178, 9251, EGCH, SMET
Program Element Code(s): 157500, 730600
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Collaborative Research: Assessing the Variability and Modification of Age, Character and Reactivity of Organic Carbon Delivered by Rivers and Estuaries to an Ocean Margin

Abstract
Riverine transport of organic carbon (OC) is a significant flux in the global C budget, representing major terms for both terrestrial losses and marine inputs. Rivers and estuaries are also dynamic systems where terrestrial OC is transformed chemically and isotopically prior to its export to the ocean margins. The global C budget currently assumes that riverine flux represents the excess of terrestrial ecosystem net primary production over decomposition. New data, however, show that rivers discharging to the NW Atlantic margin exhibit a broad range in OC ages, from modern to >5,000 yrs B.P., with particulate OC (POC) often being much older than dissolved OC (DOC). Therefore, part of the OC residing in continental reservoirs on 103-108 year timescales is being remobilized, but the extremely limited dataset precludes quantitative estimates of the transfer of different-aged OC pools from land to the oceans.
A major question to be addressed in this proposal is "How much OC of young, old, and ancient ages is mobilized in rivers, and is the processing of DOC and POC in specific rivers and estuaries prior to discharge to the ocean dependent on OC ages and source characteristics?" This will be addressed by examining a regional subset of river/estuarine systems using isotopic (D14C, d13C), organic biomarker (kerogen, microbial fatty acids, plant lignin, and hydrocarbons), and modeling approaches. The systems chosen for study will cover a spectrum of land-use, lithology, size and discharge in the northeastern U.S. Different stages of the rivers' hydrographs will be sampled to assess the key roles of runoff and residence times as controlling factors. Results from this project will be important for understanding how land-derived OC fuels the intense net heterotrophy of rivers and estuaries, for constraining the losses of soil OC via river/estuarine transport, and for interpreting the chemical and isotopic signatures of OC in ocean margins due to both OC sources and processing.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Longworth, BE; Petsch, ST; Raymond, PA; Bauer, JE "Linking lithology and land use to sources of dissolved and particulate organic matter in headwaters of a temperate, passive-margin river system" GEOCHIMICA ET COSMOCHIMICA ACTA , v.71 , 2007 , p.4233 View record at Web of Science 10.1016/j.gca.2007.06.05
Raymond, PA; Bauer, JE; Caraco, NF; Cole, JJ; Longworth, B; Petsch, ST "Controls on the variability of organic matter and dissolved inorganic carbon ages in northeast US rivers" MARINE CHEMISTRY , v.92 , 2004 , p.353 View record at Web of Science 10.1016/j.marchem.2004.06.03
Schillawski, S; Petsch, S "Release of biodegradable dissolved organic matter from ancient sedimentary rocks" GLOBAL BIOGEOCHEMICAL CYCLES , v.22 , 2008 View record at Web of Science 10.1029/2007GB00298

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