Award Abstract # 0342386
Collaborative Research: Gas, Cloudwater, and Rain Hydrogen Peroxide and Methylhydroperoxide Measurements in RICO (Rain in Cumulus Over the Ocean)

NSF Org: AGS
Division of Atmospheric and Geospace Sciences
Recipient: UNIVERSITY OF RHODE ISLAND
Initial Amendment Date: March 15, 2004
Latest Amendment Date: February 14, 2006
Award Number: 0342386
Award Instrument: Continuing Grant
Program Manager: Bradley F. Smull
AGS
 Division of Atmospheric and Geospace Sciences
GEO
 Directorate for Geosciences
Start Date: March 1, 2004
End Date: February 29, 2008 (Estimated)
Total Intended Award Amount: $321,224.00
Total Awarded Amount to Date: $321,224.00
Funds Obligated to Date: FY 2004 = $142,764.00
FY 2005 = $102,872.00

FY 2006 = $75,588.00
History of Investigator:
  • Brian Heikes (Principal Investigator)
    bheikes@uri.edu
Recipient Sponsored Research Office: University of Rhode Island
75 LOWER COLLEGE RD RM 103
KINGSTON
RI  US  02881-1974
(401)874-2635
Sponsor Congressional District: 02
Primary Place of Performance: University of Rhode Island
75 LOWER COLLEGE RD RM 103
KINGSTON
RI  US  02881-1974
Primary Place of Performance
Congressional District:
02
Unique Entity Identifier (UEI): CJDNG9D14MW7
Parent UEI: NSA8T7PLC9K3
NSF Program(s): PHYSICAL METEOROLOGY,
Atmospheric Chemistry,
Physical & Dynamic Meteorology
Primary Program Source: app-0104 
app-0105 

app-0106 
Program Reference Code(s): 0000, 1522, 4444, 9150, OTHR
Program Element Code(s): 152200, 152400, 152500
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

The investigators will contribute to the "Rain in Cumulus over the Ocean" (RICO) experiment by measuring the concentration of hydrogen peroxide and methylhydroperoxide inside and in the vicinity of clouds studied by a research aircraft, the C-130, during flights near Antigua. In combination with other measurements, the measured concentrations will indicate cloud age and the amount of environmental air entrained into the clouds. The broader RICO experiment seeks to study the mechanisms of warm-rain formation, so indications of cloud age can make substantial contributions to the broader experimental objectives by indicating the time available for formation of rain. The study will also characterize the oxidization that occurs in cloud droplets and investigate if substantial production of soluble material occurs as a consequence, causing the residue left upon evaporation of a droplet to be substantially more active as a cloud condensation nucleus than was the original nucleus on which the droplet formed. Furthermore, the two peroxide species are distributed differently in the vertical as a result of precipitation, so their ratio can identify parcels that have been affected by precipitation. These studies will all contribute to better understanding of precipitation processes and the characteristics of trade wind Cumulus clouds.

The work will also make important contributions to the training of graduate and undergraduate students and so help develop future capabilities for research in atmospheric chemistry. The techniques to be developed, if shown to be successful, could become important components of future cloud studies. By improving understanding of how oxidation contributes to the growth and modification of cloud condensation nuclei, the project has the potential to help develop a better understanding of the chemical processes that control the microstructure of clouds and hence the interactions of clouds with the climate system.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Rauber, RM; and 41 others "Rain in Shallow Cumulus Over the Ocean" Bulletin of the American Meteorological Society , v.88 , 2007 , p.1912 10.1175/BAMS-88-12-1912

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