Award Abstract # 2133576
NSF Engineering Research Center for Advancing Sustainable and Distributed Fertilizer Production (CASFER)

NSF Org: EEC
Division of Engineering Education and Centers
Recipient: TEXAS TECH UNIVERSITY SYSTEM
Initial Amendment Date: August 9, 2022
Latest Amendment Date: August 15, 2024
Award Number: 2133576
Award Instrument: Cooperative Agreement
Program Manager: Dana L. Denick
ddenick@nsf.gov
 (703)292-8866
EEC
 Division of Engineering Education and Centers
ENG
 Directorate for Engineering
Start Date: September 1, 2022
End Date: August 31, 2027 (Estimated)
Total Intended Award Amount: $26,000,000.00
Total Awarded Amount to Date: $13,919,729.00
Funds Obligated to Date: FY 2022 = $3,500,000.00
FY 2023 = $4,500,000.00

FY 2024 = $5,919,729.00
History of Investigator:
  • Gerardine Botte (Principal Investigator)
    gerri.botte@ttu.edu
  • Odemari Mbuya (Co-Principal Investigator)
  • Roger French (Co-Principal Investigator)
  • Ariel Furst (Co-Principal Investigator)
  • Marta Hatzell (Co-Principal Investigator)
  • Yang Shao-Horn (Former Co-Principal Investigator)
  • Yuriy Roman (Former Co-Principal Investigator)
Recipient Sponsored Research Office: Texas Tech University
2500 BROADWAY
LUBBOCK
TX  US  79409
(806)742-3884
Sponsor Congressional District: 19
Primary Place of Performance: Texas Tech University
Lubbock
TX  US  79409-1035
Primary Place of Performance
Congressional District:
19
Unique Entity Identifier (UEI): EGLKRQ5JBCZ7
Parent UEI:
NSF Program(s): ERC-Eng Research Centers,
Advanced Tech Education Prog
Primary Program Source: 01002223DB NSF RESEARCH & RELATED ACTIVIT
01002324DB NSF RESEARCH & RELATED ACTIVIT

01002425DB NSF RESEARCH & RELATED ACTIVIT

01002526DB NSF RESEARCH & RELATED ACTIVIT

01002627DB NSF RESEARCH & RELATED ACTIVIT

04002324DB NSF STEM Education
Program Reference Code(s): 1032, 131E, 132E, 123E, 112E, 1480, 113E, 127E, 128E, 129E, 7680, 9178, SMET
Program Element Code(s): 148000, 741200
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.041, 47.076

ABSTRACT

The NSF Engineering Research Center for Advancing Sustainable and Distributed Fertilizer Production (CASFER) will strive to solve one of the most pressing problems facing humankind: how do we feed the growing world population while protecting and sustaining our environment? By 2050, the world population will exceed 10.5 billion, increasing the demand for food by 70%, with only an additional 10% land available for agriculture. To meet this demand, nitrogen-based fertilizers (NBFs) are required for the formation of plant proteins. Currently, more than 50% of the world population is supported by synthetic NBFs, produced via the Haber-Bosch process (HB) a carbon intensive process, however, the high volatility of prices remains a challenge in the US and developing countries. Furthermore, only 20% of NBFs produced translate into food with 80% lost to the environment creating significant environmental, health, and socioeconomic impact. Therefore, society requires new cost effective, resilient, and secure ways to produce NBFs with minimum environmental and socioeconomic impacts. CASFER will enable resilient and sustainable food production by developing next generation, modular, distributed, and efficient technology for capturing, recycling, and producing decarbonized NBFs. CASFER will create a transformative engineered system that takes the US from nitrogen cycle pollution to a Nitrogen Circular Economy (NCE), from a linear economy to a circular economy with multidimensional social, environmental, and economic growth. CASFER will capture and recycle nitrogen from waste to reach over 50% of the US NBF consumption. Instead of expending resources, energy, and money to deactivate diluted reactive nitrogen from waste streams, nitrogen from waste will be captured and recycled for crop production.

CASFER brings together a diverse leadership and the convergence of a multidisciplinary team drawn from Texas Tech University, Florida A&M University, Georgia Institute of Technology, Case Western Reserve University, and Massachusetts Institute of Technology. CASFER convergence research will advance modeling, monitoring and distributed control; capture and recycling; and modular and distributed production and delivery of NBFs. CASFER will enable an organic but synthetic approach to NBF production, with ingredients, predictability, and reliability designed to stimulate plant growth. CASFER technologies will integrate nanotechnology, electrochemical science, and data science for modularity, synthesis, and separations, and resolve economic pressures, logistics issues, public and industry acceptance, regulatory, and safety issues. CASFER will advance fundamental knowledge in key areas of interfacial processes, separations, catalysis and electrocatalysis, and properties of materials to tolerate heterogenous and harsh environments to enable synthetic chemistry pathways to convert waste into NBF. CASFER will lead to advances in sensor science and multiscale modeling to deliver NBF near point of use by farmers. CASFER Innovation Ecosystem will bring together key industry members, agriculture cooperatives, facilitators, investors, regulatory advisory boards, and Society Visionary Champions to commercialize CASFER research discoveries and maximize benefits to society. CASFER will train the next generation of engineers and technical workforce at the intersection of engineering, agricultural sciences, and environmental science with the skills to advance the NCE. CASFER will empower agents of change and influencers to promote the NCE targeting formal and informal education along the K-gray spectrum. CASFER will engage a diverse range of communities underrepresented in STEM through the NCE by acknowledging the varied backgrounds and experiences of each participant and facilitating their engagement in engineering through multimodal, multilevel entry points and cut across socioeconomic and cultural boundaries. CASFER will establish a fully sustainable innovation ecosystem to expand fundamental knowledge and leverage CASFER platform technologies to recover phosphorous, nutrients, and other resources from waste streams. Through all these activities, CASFER will lead the US toward a Nitrogen Circular Economy, fertilizer independence, an affordable and resilient price range for NBF, while sustaining and preserving the environment.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Daramola, Damilola A. and Hatzell, Marta C. "Energy Demand of Nitrogen and Phosphorus Based Fertilizers and Approaches to Circularity" ACS Energy Letters , v.8 , 2023 https://doi.org/10.1021/acsenergylett.2c02627 Citation Details
Fernández, Carlos A. and Chapman, Oliver and Brown, Marilyn A. and Alvarez-Pugliese, Christian E. and Hatzell, Marta C. "Achieving Decentralized, Electrified, and Decarbonized Ammonia Production" Environmental Science & Technology , v.58 , 2024 https://doi.org/10.1021/acs.est.3c10751 Citation Details
Huang, Po-Wei and Hatzell, Marta C. "Prospects and good experimental practices for photocatalytic ammonia synthesis" Nature Communications , v.13 , 2022 https://doi.org/10.1038/s41467-022-35489-7 Citation Details
Huang, PoWei and Song, Hakhyeon and Yoo, Jaeyoung and Chipoco_Haro, Danae_A and Lee, Hyuck_Mo and Medford, Andrew_J and Hatzell, Marta_C "Impact of Local Microenvironments on the Selectivity of Electrocatalytic Nitrate Reduction in a BPMMEA System" Advanced Energy Materials , v.14 , 2024 https://doi.org/10.1002/aenm.202304202 Citation Details
Lim, Jeonghoon and Chen, Yu and Cullen, David A. and Lee, Seung Woo and Senftle, Thomas P. and Hatzell, Marta C. "PdCu Electrocatalysts for Selective Nitrate and Nitrite Reduction to Nitrogen" ACS Catalysis , 2022 https://doi.org/10.1021/acscatal.2c04841 Citation Details
Lim, Jeonghoon and Cullen, David A. and Stavitski, Eli and Lee, Seung Woo and Hatzell, Marta C. "Atomically Ordered PdCu Electrocatalysts for Selective and Stable Electrochemical Nitrate Reduction" ACS Energy Letters , v.8 , 2023 https://doi.org/10.1021/acsenergylett.3c01672 Citation Details
Liu, Yu-Hsuan and Huang, Po-Wei and Hatzell, Marta C. "A rotating ring disc electrode study of photo(electro)catalyst for nitrogen fixation" Faraday Discussions , 2023 https://doi.org/10.1039/D2FD00168C Citation Details
Song, Hakhyeon and Chipoco Haro, Danae A. and Huang, Po-Wei and Barrera, Luisa and Hatzell, Marta C. "Progress in Photochemical and Electrochemical CN Bond Formation for Urea Synthesis" Accounts of Chemical Research , v.56 , 2023 https://doi.org/10.1021/acs.accounts.3c00424 Citation Details
Varanasi, Sai A. and Fernández, Carlos A. and Hatzell, Marta C. "Energy Management and Economic Considerations of Intermittent Photovoltaic-Driven Electrochemical Ammonia Production" Energy & Fuels , v.37 , 2023 https://doi.org/10.1021/acs.energyfuels.3c02123 Citation Details

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