Award Abstract # 0315412
In situ Studies of Model Automotive Exhaust Catalysts with High Spatial and Spectroscopic Resolution

NSF Org: CHE
Division Of Chemistry
Recipient: ARIZONA STATE UNIVERSITY
Initial Amendment Date: July 10, 2003
Latest Amendment Date: April 8, 2005
Award Number: 0315412
Award Instrument: Continuing Grant
Program Manager: Zeev Rosenzweig
CHE
 Division Of Chemistry
MPS
 Directorate for Mathematical and Physical Sciences
Start Date: July 15, 2003
End Date: June 30, 2008 (Estimated)
Total Intended Award Amount: $331,000.00
Total Awarded Amount to Date: $331,000.00
Funds Obligated to Date: FY 2003 = $131,000.00
FY 2004 = $100,000.00

FY 2005 = $100,000.00
History of Investigator:
  • Ernst Bauer (Principal Investigator)
    ERNST.BAUER@asu.edu
Recipient Sponsored Research Office: Arizona State University
660 S MILL AVENUE STE 204
TEMPE
AZ  US  85281-3670
(480)965-5479
Sponsor Congressional District: 04
Primary Place of Performance: Arizona State University
660 S MILL AVENUE STE 204
TEMPE
AZ  US  85281-3670
Primary Place of Performance
Congressional District:
04
Unique Entity Identifier (UEI): NTLHJXM55KZ6
Parent UEI:
NSF Program(s): ELECTROCHEMISTRY & SURFACE CHE
Primary Program Source: app-0103 
app-0104 

app-0105 
Program Reference Code(s): 0000, 1401, 1972, OTHR, 7202
Program Element Code(s): 197200
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.049

ABSTRACT

Abstract
CHE-0315412
Bauer/Arizona State

The improvement of the operation of three way catalytic converters for automobile exhaust remediation is the goal of the work carried out by Professor Bauer and his colleagues at Arizona State University. With the support of the Analytical and Surface Chemistry Program, he is applying low energy electron microscopy and x-ray photoemission microscopy to the study of model three way catalysts. In the presence of CO, O2, NO and SO2 reactants, oxide supported noble metal catalysts undergo morphological and compositional changes on the nanometer scale that can be monitored using these methods. Results of these surface kinetic and dynamic studies provide understanding for the improved design of these catalytic systems.

In order to continually reduce the emissions from automobile exhaust, improvements in catalytic converter technology must be made. This research project, supported by the Analytical and Surface Chemistry Program, addresses the detailed dynamics of operation of the commonly used three way catalytic converter. Using state of the art microscopic methods, in situ studies of the reaction process, and direct monitoring of the operational catalyst, Professor Bauer and his coworkers are developing the fundamental understanding needed to improve catalyst design.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Locatelli A, Pabisiak T, Pavlovska A, Mentes T, Aballe L, Kiejna A, Bauer E "One-dimensional Au on TiO2" J. Phys.: Condensed Matter , v.19 , 2007 , p.082202
Mentes T O, Locatelli A, Aballe L, Pavlovska A, Bauer E, Pabisiak T, Kiejna A "Surface modification of oxides by electron-stimulated desorption for growth mode control of metal films: Experiment and DFT calculations" Phys. Rev. B , v.76 , 2007 , p.155413 10.1103/PhysRevB.76.155413
Wu F, Pavlovska A, Smith D A, Culbertson R J, Wilkens B J, Bauer E "Growth and structure of epitaxial CeO2 films on yttria-stabilized ZrO2" Thin Solid Films , v.516 , 2008 , p.4908 10.1016/j.tsf.2007.09.026

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