Award Abstract # 1553878
CAREER: Characterizing the Physical/Chemical Evidence of Volcanic Lightning

NSF Org: EAR
Division Of Earth Sciences
Recipient: UNIVERSITY OF ALABAMA
Initial Amendment Date: February 12, 2016
Latest Amendment Date: September 18, 2019
Award Number: 1553878
Award Instrument: Continuing Grant
Program Manager: Jennifer Wade
jwade@nsf.gov
 (703)292-4739
EAR
 Division Of Earth Sciences
GEO
 Directorate for Geosciences
Start Date: March 1, 2016
End Date: February 28, 2023 (Estimated)
Total Intended Award Amount: $433,918.00
Total Awarded Amount to Date: $465,928.00
Funds Obligated to Date: FY 2016 = $207,947.00
FY 2017 = $32,010.00

FY 2018 = $89,560.00

FY 2019 = $136,411.00
History of Investigator:
  • Kimberly Genareau (Principal Investigator)
    kdgenareau@as.ua.edu
Recipient Sponsored Research Office: University of Alabama Tuscaloosa
801 UNIVERSITY BLVD
TUSCALOOSA
AL  US  35401-2029
(205)348-5152
Sponsor Congressional District: 07
Primary Place of Performance: University of Alabama Tuscaloosa
Tuscaloosa
AL  US  35401-2029
Primary Place of Performance
Congressional District:
07
Unique Entity Identifier (UEI): RCNJEHZ83EV6
Parent UEI: TWJWHYEM8T63
NSF Program(s): Petrology and Geochemistry,
EDUCATION AND HUMAN RESOURCES,
Instrumentation & Facilities,
EAR-Earth Sciences Research
Primary Program Source: 01001617DB NSF RESEARCH & RELATED ACTIVIT
01001718DB NSF RESEARCH & RELATED ACTIVIT

01001819DB NSF RESEARCH & RELATED ACTIVIT

01001920DB NSF RESEARCH & RELATED ACTIVIT

01002021DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 1045
Program Element Code(s): 157300, 157500, 158000, 689800
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.050

ABSTRACT

Volcanic eruptions and lightning strikes are two of the most impressive and destructive natural phenomena, but much is still unknown about the fundamental processes that allow these events to occur. An emerging new line of research is seeking to determine the complex relationship between explosive volcanism and lightning, specifically: The effect of lightning discharge on the textural and chemical properties of volcanic ash and the resulting signature of volcanic lightning occurrence in the geologic record. In addition to the formation of fulgurites as a result of cloud-to-ground lightning strikes, lightning-induced volcanic spherules (LIVS) form in the atmosphere from the physical transformation of volcanic ash particles into spheres of glass due to the high heat generated during lightning discharge. This project will characterize the physiochemical evidence of volcanic lightning by: 1) identifying LIVS in natural ash fall deposits and analyzing their textural/chemical properties using established methods; 2) performing a series of triggered lightning experiments on manufactured ash samples of known composition and grain size to characterize the physical/chemical effects of volcanic lightning on the samples using various analytical methods; 3) establishing a research team of graduate, undergraduate, and high school students to perform the experiments and analyze the samples; and 4) developing grade school curricula for teaching natural hazards in local schools in order to engage students in the Earth sciences. Fundamental questions addressed by this project, and the integral educational component that involves learners of all ages, may result in potentially transformative concepts the geosciences, atmospheric sciences, and hazard assessment. Textural and geochemical data acquired on the samples will provide evidence for volcanic lightning in the geologic record, allowing researchers to identify these events during eruptions that preceded or eluded human documentation. Results will also reveal the role that lightning plays in altering the chemical characteristics of the local environment. Additionally, the triggered lightning experiments, conducted on manufactured ash samples of known composition, will allow video documentation of fulgurite formation. Through scientific and community presentations, this project will build further interest in volcanology, atmospheric dynamics, and the complex interplay between these natural phenomena, not only in the scientific community, but also in schools and amongst the general public.

The primary goal of this project is to characterize the physical/chemical evidence of volcanic lightning occurrence in tephra deposits, which will aid in understanding the frequency of volcanic lightning in the geologic record, contributing to advancing scientific knowledge of volcano-atmosphere interactions, which is an emerging new line of scientific research. Ash fall deposits from numerous volcanic eruptions in Alaska will be analyzed, as volcanic lightning was documented during these explosive events and samples were provided by the Alaska Volcano Observatory. Triggered lightning experiments will be conducted at the International Center for Lightning Research and Testing (ICLRT) on manufactured ash samples (pseudo-ash samples) of known composition and grain size. The established analytical methods that will be utilized for this project include: 1) Scanning electron microscope (SEM), transmission electron microscope (TEM), and electron spin resonance (ESR) examination of lightning-induced volcanic spherules (LIVS) present in natural ash samples to determine their textural and chemical characteristics; 2) ESR, Mossbauer, and titration analyses of both natural, unmodified ash and pre-experimental pseudo-ash; and 3) SEM, TEM, ESR, Mossbauer, and titration analyses of LIVS and fulgurites produced in the triggered lightning experiments. A research team of graduate, undergraduate, and high school students will perform the experiments and analyze the samples. The various analyses, when conducted on the pseudo-ash samples prior to and following the triggered lightning experiments, will allow a direct means to determine the effect of lightning discharge on the morphological transformation, general chemistry, and oxidation/Fe valence state of exposed materials. The natural ash samples will allow a chemical comparison between normal (i.e., unmodified) ash and any LIVS present in the deposits. Following publication of results, the videos of triggered lightning experiments will be displayed on the University of Alabama?s Tephra Lab website, on YouTube, and showcased in the Alabama Museum of Natural History, along with samples of both natural fulgurites and fulgurites created in the triggered lightning experiments. Fundamental questions addressed by this project, and the integral educational component that involves learners of all ages, may result in potentially transformative concepts the geosciences, atmospheric sciences, and hazard assessment. Textural and geochemical data acquired on the samples will provide evidence for volcanic lightning in the geologic record, allowing researchers to identify these events during eruptions that preceded or eluded human documentation. Results will also reveal the role that lightning plays in altering the chemical characteristics of the local environment. Additionally, the triggered lightning experiments, conducted on manufactured ash samples of known composition, will allow video documentation of fulgurite formation. Through scientific and community presentations, this project will build further interest in volcanology, atmospheric dynamics, and the complex interplay between these natural phenomena, not only in the scientific community, but also in schools and amongst the general public.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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Cimarelli, C. and Genareau, K. "A review of volcanic electrification of the atmosphere and volcanic lightning" Journal of Volcanology and Geothermal Research , 2021 , p.107449
Genareau, K., Woods, T. W., Park, C., & Feinberg, J. "Lightning Effects on Airborne Mineral Dust: An Overview" 103rd American Meteorological Society Meeting , 2023
K. Genareau, P. Gharghabi, J. Gafford, M. Mazzola "The elusive evidence of volcanic lightning" Scientific Reports , v.7 , 2017 , p.15508
Kimberly Genareau, Kristi Wallace, Pedram Gharghabi, and James Gafford "Lightning Effects on the Grain Size Distribution of Volcanic Ash" Geophysical Research Letters , v.46 , 2019 , p.3133 10.1029/2018GL081298
Kimberly Genareau, Pedram Gharghabi, and Joni Klüss "Influence of Shock Propagation on Lightning Evidence in Volcanic Ashfall Deposits" Earth and Planetary Science Letters , v.535 , 2020 , p.116124 10.1016/j.epsl.2020.116124
Kimberly Genareau, Taylor W. Woods, and Robert M. Comas "Volcanic Lightning Evidence in Ashfall Deposits: Intra-Cloud or Cloud-to-Ground Discharges?" AGU Fall Meeting, abs. V13E-0220 , 2019
Kimberly Genareau, Yang-Ki Hong, Woncheol Lee, Minyeong Choi, Mojtaba Rostaghi-Chalaki, Pedram Gharghabi, James Gafford, and Joni Klüss "Effects of Lightning on the Magnetic Properties of Volcanic Ash" Scientific Reports , v.9 , 2019 , p.4726
Taylor W. Woods, Kimberly Genareau, and Joni Kluss "Alteration of Volcanic Ash Glass Chemistry due to Lightning" Journal of Volcanology and Geothermal Research , 2021 , p.107340
Taylor W. Woods, Kimberly Genareau, and Robert M. Comas "Chemical Alteration of Volcanic Ash Due to Simulated Lightning" AGU Fall Meeting, abs. V12B-08 , 2019
Woods, T. W., Genareau, K., Park, C., Feinberg, J., Won, H., & Hong, Y.-K. "Destruction and Creation of Minerals in Lightning-Affected Atmospheric Dusts" 103rd American Meteorological Society Meeting , 2023

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

Results of this project have revealed the effects of lightning on the structure, grain size distribution, chemical composition, and magnetic properties of exposed volcanic ash particles through a series of simulated lightning experiments and analyses.  Current impulse experiments were conducted at peak currents ranging from 7 kA to 100 kA in magnitude, which spans much of the range of values measured for volcanic lightning during explosive eruptions. Post-experimental analyses of exposed volcanic ash samples reveal several important changes to sample properties.  First, the grain size distribution of the ash is altered.  Particles initially < 32 m in diameter (the experimental starting materials) are melted and/or fused together to produce a variety of shapes, including individual spherules, spherule aggregates, hair-like morphologies, plate-like morphologies, and pumice-like textures. While pre-experimental ash grains are angular in shape and contain well-defined micro-mineral structures, the post-experimental grains contain only amorphous glass with zones of element enrichment indicative of the pre-existing crystals.  The structure of these elemental enrichment zones suggest small-scale convection in a molten fluid state.  There are also unique changes to the magnetic properties of the samples based upon the starting composition of the materials. The post-experimental analyses of samples, conducted using scanning electron microscopy, energy dispersive spectroscopy, Raman spectroscopy, and vibrating sample magnetometry, reveal the unique chemical and magnetic signatures imparted by lightning on volcanic ash particles.

 

This project has supported several graduate and undergraduate research assistants, who have been trained on the operation of electron microscopes, laser diffractometers, resistance meters, and various X-ray instruments to analyze experimental samples.  Scientific results have been published in numerous peer-reviewed journals and presented at several different conferences. Posters describing the scientific results of this project were designed, printed, and distributed to public schools in the state of Alabama for broader education of grade school students on lightning effects.  Triggered lightning experiments were recorded for public viewing through The University of Alabama Tephra Lab website. Sample images were provided on the Tephra Lab Instagram page, and a museum display describing the effects of lightning, and including various fulgurite samples from around the world, was installed in the Alabama Museum of Natural History on the University campus.  Results pose significant implications for how particular microanalyses can reveal lightning occurrence in the tephra record and how the physical, chemical, and magnetic changes induced by lightning may change the impact of lightning-affected ash samples on infrastructure and the environment. 

 

 


Last Modified: 06/26/2023
Modified by: Kimberly D Genareau

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