Award Abstract # 1509912
A BUBBLE GAS SENSOR FOR QUNTITATIVE CHEMICAL ANALYSIS

NSF Org: ECCS
Division of Electrical, Communications and Cyber Systems
Recipient: UNIVERSITY OF UTAH
Initial Amendment Date: June 1, 2015
Latest Amendment Date: June 1, 2015
Award Number: 1509912
Award Instrument: Standard Grant
Program Manager: Shubhra Gangopadhyay
ECCS
 Division of Electrical, Communications and Cyber Systems
ENG
 Directorate for Engineering
Start Date: June 1, 2015
End Date: May 31, 2019 (Estimated)
Total Intended Award Amount: $367,558.00
Total Awarded Amount to Date: $367,558.00
Funds Obligated to Date: FY 2015 = $367,558.00
History of Investigator:
  • Hanseup Kim (Principal Investigator)
    hanseup@ece.utah.edu
Recipient Sponsored Research Office: University of Utah
201 PRESIDENTS CIR
SALT LAKE CITY
UT  US  84112-9049
(801)581-6903
Sponsor Congressional District: 01
Primary Place of Performance: University of Utah
UT  US  84112-8930
Primary Place of Performance
Congressional District:
01
Unique Entity Identifier (UEI): LL8GLEVH6MG3
Parent UEI:
NSF Program(s): CCSS-Comms Circuits & Sens Sys
Primary Program Source: 01001516DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 9150
Program Element Code(s): 756400
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.041

ABSTRACT

Proposal 1509912

Title: A bubble gas sensor for quantitative chemical analysis

PI: Kim, Hanseup

Brief description of project goals:
This project aims to investigate the science of micro-scale fluidic phenomena and develop a high-performance gas sensor.


a) Nontechnical Abstract:
Quantification is one of the most critical parameters in many analytical applications, especially when interfacing with the chemical and biological domains, which feature enormous diversity in elements. Despite remarkable progress, miniature gas sensors still remain incapable of measuring gas quantity precisely because of issues in response drift, saturation, and limited specificity. This project proposes the development of a sensing mechanism that addresses such issues by investigating unexplored fluidic phenomena in the micro-domain and by demonstrating a microfluidic sensor. The proposed research will provide a new paradigm in gas sensing and quantification and will have a broad range of societal impacts in numerous fields, including occupational safety regulation, environmental sciences, personal and community behavioral sciences, homeland security, chemical manufacturing, and health science. In this context, the proposed project will provide a foundation for highly inter-disciplinary research and education, where students are exposed to broadly connected societal values among engineering, science, medicine, social sciences, and public policy. This program will also provide an opportunity to reach out to the K-12 community in collaboration with a local museum; to industry via intellectual property generation directed toward commercialization; and to the undergraduate and graduate students via class development on important advances in novel sensing mechanisms and microfluidics principles.

b) Technical Abstract:
This project aims (1) to establish a novel class of a gas sensing principle by investigating the science of microfluidic bubble formation and (2) to fabricate a bubble-based sensor which improves gas sensing performance by two orders of magnitude in comparison to existing counterparts. Specifically, this project will investigate the microfluidic gas/liquid interface properties of various gas types via microfabricated structures. An optimized prototype of a high performance gas sensor will be microfabricated to demonstrate high-precision gas quantification. By combining the fundamental science studies with experimental data, the proposed research is expected to establish fundamental and comprehensive understanding on bubble formation phenomena in the microfluidic domain, in relation to gas-liquid interfacial parameters. Such an understanding will enable this program to further demonstrate a high-precision micro gas sensor device that is capable of quantifying gas amounts with outstanding dynamic range, resolution, and linearity.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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A. Bulbul and H. Kim "A bubble-based microfluidic gas sensors for gas chromatographs" Lab Chip , v.15 , 2015
A. Bulbul and H. Kim "A bubble-based microfluidic gas sensors for gas chromatographs" Lab-on-Chips , v.15 , 2015
A. Bulbul and H. Kim "PPB level gas quantification by bubble chromatography" In Proc. TRANSDUCERS 2017 , 2017 , p.660
A. Bulbul and H. Kim "PPB level gas quantification by bubble chromatography" In Proc. TRANSDUCERS 2017 , 2017
A. Bulbul, H.-C. Hsieh, and H. Kim "Microfluidic bubble-based gas sensor" In Proc. IEEE MEMS , 2014 , p.226-229
A. Bulbul, K. Kim, and H. Kim "Modeling and evaluation of bubble chromatography" In Proc. IEEE MEMS 2019 , 2019

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

This project demonstrated a new proof of concept sensor, ?bubble chromatography? that first time utilized a bubble as a sensing element.  The developed bubble chromatography was able to amplify the subtle differences in viscosity among gases into size differences in bubbles when gas is directed into a liquid stream to form a series of bubbles through a micro nozzle. To elucidate such operation principles, some important microfludic phenomena were theoretically modelled, including the conversion of viscosity difference into pressure transient and the amplification of pressure transients along a nano-scale channel. The developed bubble chromatography system, consisting of microfluidic channels, a nozzle and a detector, showed that (1) a bubble size was correlated to a gas type; that (2) a bubble size was also correlated to a gas concentration within a bubble; that (3) a continuous bubble flow of multiple gases could generate a chromatogram as the bubbles to their characteristic sizes; and that (4) nano-gram level quantification was enabled due to the discrete nature of bubble formation. The developed bubble chromatography system demonstrated high-sensitivity and -stability as an efficient gas sensor and provided a foundation for an efficient interface between gas and liquid useful for various applications including biological studies.

 


Last Modified: 09/11/2019
Modified by: Hanseup Kim

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