Award Abstract # 1505826
Electronic and Magnetic Phenomena in Iron-based Superconductors

NSF Org: DMR
Division Of Materials Research
Recipient: KENT STATE UNIVERSITY
Initial Amendment Date: May 8, 2015
Latest Amendment Date: April 27, 2018
Award Number: 1505826
Award Instrument: Standard Grant
Program Manager: Tomasz Durakiewicz
tdurakie@nsf.gov
 (703)292-4892
DMR
 Division Of Materials Research
MPS
 Directorate for Mathematical and Physical Sciences
Start Date: June 1, 2015
End Date: May 31, 2020 (Estimated)
Total Intended Award Amount: $400,000.00
Total Awarded Amount to Date: $433,350.00
Funds Obligated to Date: FY 2015 = $400,000.00
FY 2016 = $7,000.00

FY 2018 = $26,350.00
History of Investigator:
  • Carmen Almasan (Principal Investigator)
    calmasan@kent.edu
Recipient Sponsored Research Office: Kent State University
1500 HORNING RD
KENT
OH  US  44242-0001
(330)672-2070
Sponsor Congressional District: 14
Primary Place of Performance: Kent State University
Kent
OH  US  44242-0001
Primary Place of Performance
Congressional District:
14
Unique Entity Identifier (UEI): KXNVA7JCC5K6
Parent UEI:
NSF Program(s): CONDENSED MATTER PHYSICS
Primary Program Source: 01001516DB NSF RESEARCH & RELATED ACTIVIT
01001617DB NSF RESEARCH & RELATED ACTIVIT

01001819DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 053Z, 057Z
Program Element Code(s): 171000
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.049

ABSTRACT

Nontechnical description:
Two major themes in condensed matter physics are quantum critical phenomena and unconventional superconductivity. A quantum phase transition takes place at zero temperature and describes a phase transition between competing ground states driven by an external parameter such as chemical composition, pressure, or magnetic field. The recent studies of unconventional superconductors show that superconductivity develops in proximity to a magnetically ordered phase. This raises the possibility of quantum phase transitions in these systems arising from competing types of such orders. The present studies of iron-based superconductors mainly focus on the understanding of the normal state properties of these superconductors and on the mechanism of superconductivity. These studies enhance our fundamental understanding of the extent to which a quantum phase transition controls the finite temperature properties of these superconductors and promise insight into the mutual interplay between superconductivity and magnetism. They could also offer clues about other unconventional superconductors, such as the cuprates, and contribute to a more global understanding of the novel phenomenon of high temperature superconductivity. This highly interdisciplinary project allows graduate and undergraduate students, postdocs, and visitors to benefit from exposure to a diversity of experimental techniques, a variety of different physical systems and phenomena, and forefront topics in condensed matter physics. The diversity of the expertise gained by the participants in this research program is a substantial advantage in today's knowledge based, technology driven economy, being beneficial to a future career in industry, government, or academia. Professional mentoring is provided for the postdoc and graduate students. A female Ph.D. student participates in this project, hence, the project increases diversity within the field. The international collaborations with scientists in Romania and China contribute to the nation's infrastructure for research and education. The principal investigator develops teaching lab modules for a senior laboratory that verifies experimentally counterintuitive physical phenomena learned in Quantum Mechanics. She also addresses the professional development needs of science teachers in grades 6-10 by developing the physical science component of a new physical and life science graduate course. Finally, she provides middle school and high school physics teachers and their students workshops and lab tours.

Technical description:
This proposal addresses a major theme in condensed matter physics: unconventional superconductivity in Fe-based superconductors. The proposed research significantly enhances our fundamental understanding of charge conduction and magnetism of iron pnictides/chalcogenites, addresses issues related with the interplay between magnetism and superconductivity, and contributes to a more global understanding of the novel phenomenon of high temperature superconductivity. The goals of this research are to: (1) study novel electronic quantum states with real-space texture in iron pnictides/chalcogenites superconductors with either an antiferromagnetic Mott insulator or antiferromagnetic spin density wave parent compound; (2) reveal the microscopic coexistence of antiferromagnetism and superconductivity and its evolution with doping; (3) study quantum criticality in order to reveal possible quantum phase transitions induced by control parameters, elucidate the phase boundary between the paramagnetic and antiferromagnetic phases inside the superconducting state, and generate a phase diagram that provides direct evidence for a quantum critical line inside the superconducting phase; (4) study the symmetry of the superconducting gap in order to unambiguously distinguish between different pairing symmetries and reveal any universality in the doping dependence of the gap; (5) reveal the origin of the pseudogap region; (6) facilitate the training of highly qualified personnel through comprehensive and multifaceted research, improve STEM education through educator development at 6-10 grade levels, and perform outreach activities. The methods that are used in these studies are resistivity, magnetoresistivity, current-voltage, torque, and magnetization measurements. Understanding the intrinsic electronic, magnetic, and magnetotransport mechanisms in these complex materials may be a key component in understanding their unique and potentially useful physical properties. With iron pnictides/chalcogenites and cuprates to compare and contrast, the proposed research could contribute to finally uncovering the vital clues that theorists need to solve the mystery of high-temperature superconductivity. More broadly, the results from these basic investigations provide further understanding of the interplay between magnetism and superconductivity of other unconventional superconductors and insight into appropriate doping schemes to facilitate applications to electronic sensors and devices.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 11)
"Orbital and Pauli limiting effects in heavily doped Ba0.05K0.95Fe2As2" Physical Review B , v.92 , 2015 10.1103/PhysRevB.92.174524 Citation Details
Adhikari, R. B. and Kunwar, D. L. and Jeon, I. and Maple, M. B. and Dzero, M. and Almasan, C. C. "Short-range antiferromagnetic correlations in the superconducting state of filled skutterudite alloys Pr1?xEuxPt4" Physical Review B , v.98 , 2018 10.1103/PhysRevB.98.064506 Citation Details
Adhikari, R. B. and Shen, P. and Kunwar, D. L. and Jeon, I. and Maple, M. B. and Dzero, M. and Almasan, C. C. "Magnetic field dependence of the Schottky anomaly in filled skutterudites Pr1xEuxPt4Ge12 Physical Review B , v.100 , 2019 10.1103/PhysRevB.100.174509 Citation Details
Huang, X. Y. and Haney, D. J. and Singh, Y. P. and Hu, T. and Xiao, H. and Wen, Hai-Hu and Dzero, M. and Almasan, C. C. "Universality and unconventional enhancement of flux-flow resistivity in Ba(Fe1?xCox)2 Physical Review B , v.95 , 2017 10.1103/PhysRevB.95.184513 Citation Details
Huang, X. Y. and Singh, Y. P. and Haney, D. J. and Hu, T. and Xiao, H. and Wen, Hai-Hu and Zhang, Shuai and Dzero, M. and Almasan, C. C. "Relationship between critical current and flux-flow resistivity in the mixed state of Ba(Fe1?xCox)2<" Physical Review B , v.96 , 2017 10.1103/PhysRevB.96.094509 Citation Details
Jeon, I. and Ran, S. and Breindel, A. J. and Ho, P.-C. and Adhikari, R. B. and Almasan, C. C. and Luong, B. and Maple, M. B. "Crossover and coexistence of superconductivity and antiferromagnetism in the filled-skutterudite system Pr1?xEuxPt4 Physical Review B , v.95 , 2017 10.1103/PhysRevB.95.134517 Citation Details
Liu, W. and Wu, Y. F. and Li, X. J. and Bud'ko, S. L. and Canfield, P. C. and Panagopoulos, C. and Li, P. G. and Mu, G. and Hu, T. and Almasan, C. C. and Xiao, H. "Pressure-tuned superconductivity and normal-state behavior in Ba(Fe0.943Co0.057)2 Physical Review B , v.97 , 2018 10.1103/PhysRevB.97.144515 Citation Details
Pouse, N. and Jang, S. and White, B. D. and Ran, S. and Adhikari, R. B. and Almasan, C. C. and Maple, M. B. "Temperature versus Sm concentration phase diagram and quantum criticality in the correlated electron system Ce1?xSmxCoIn5 Physical Review B , v.97 , 2018 10.1103/PhysRevB.97.235149 Citation Details
Ran, S. and Schmiedeshoff, G. M. and Pouse, N. and Jeon, I. and Butch, N. P. and Adhikari, R. B. and Almasan, C. C. and Maple, M. B. "Rapid suppression of the energy gap and the possibility of a gapless hidden order state in URu 2?x Re x Si 2" Philosophical Magazine , v.99 , 2019 10.1080/14786435.2019.1600756 Citation Details
Singh, Y. P. and Adhikari, R. B. and Haney, D. J. and White, B. D. and Maple, M. B. and Dzero, M. and Almasan, C. C. "Zero-field quantum critical point in Ce0.91Yb0.09CoIn5" Physical Review B , v.97 , 2018 10.1103/PhysRevB.97.184514 Citation Details
Singh, Y. P. and Adhikari, R. B. and Zhang, S. and Huang, K. and Yazici, D. and Jeon, I. and Maple, M. B. and Dzero, M. and Almasan, C. C. "Multiband superconductivity in the correlated electron filled skutterudite system Pr1?xCexPt4 Physical Review B , v.94 , 2016 10.1103/PhysRevB.94.144502 Citation Details
(Showing: 1 - 10 of 11)

PROJECT OUTCOMES REPORT

Disclaimer

This Project Outcomes Report for the General Public is displayed verbatim as submitted by the Principal Investigator (PI) for this award. Any opinions, findings, and conclusions or recommendations expressed in this Report are those of the PI and do not necessarily reflect the views of the National Science Foundation; NSF has not approved or endorsed its content.

Basic research and technology:

Some of the most interesting physical phenomena include superconductivity, a phenomenon wherein a material has zero electrical resistance and expels small magnetic fields when cooled below a material specific critical temperature, and heavy fermion behavior, in which electrons behave as if they were much more massive than typical electrons by factors of several hundred. Many of the materials that have been responsible for recent advances in physics and technology are rare earth and actinide compounds consisting of three or more elements in which the localized (attached to a specific ion) d-and f-electrons are admixed with conduction electrons (free to move within the metal).  A major goal of our project were to study selected unconventional superconductors, such as iron-based pnictites and chalcogenites and heavy fermions, in order to contribute to a more global understanding of the novel phenomenon of superconductivity that takes place at high temperatures. Specifically, we studied two major themes in condensed matter physics: quantum critical phenomena and unconventional superconductivity. A quantum phase transition takes place at zero temperature and describes a phase transition between competing ground states driven by an external parameter such as chemical composition, pressure, or magnetic field. The recent studies of unconventional superconductors show that superconductivity develops in proximity to a magnetically ordered phase. This raises the possibility of quantum phase transitions in these systems arising from competing types of such orders. We measured physical properties of f-electron materials as functions of temperature, magnetic field, applied pressure, and chemical substitution, yielding important clues that shed light on the underlying mechanism of superconductivity. While other present studies of iron-based superconductors mainly focus on the understanding of the normal state properties of these superconductors and on the mechanism of superconductivity, our studies enhance our fundamental understanding of the extent to which a quantum phase transition controls the finite temperature properties of these superconductors and promise insight into the mutual interplay between superconductivity and magnetism. These studies could also offer clues about other unconventional superconductors, such as the cuprates, and contribute to a more global understanding of the novel phenomenon of high temperature superconductivity. Unveiling what these various materials share in common and what aspects of their behavior are system specific lead to basic scientific insights with important practical relevance to developing functional materials for technological applications.  Our studies of the physics of strongly correlated electron systems impact science and engineering research in many beneficial ways.  

Education, training, and professional development:

These projects provided opportunities for research, teaching, and mentoring, for graduate and undergraduate students.  Since these projects were not overly large and unwieldy, the researchers pursuing them necessarily became trained in a wide array of skills and technologies.  Specifically, these projects have contributed to the development of experimental skills and experience with low-temperature systems, electronics and mechanical design and construction, equipment “debugging”, planning and executing microcomputer interfaces for automated experimental control and data acquisition, and programming including writing special-purpose programs in high-level languages.  Also, these projects has exposed the students to new physics phenomena that are at the forefront of condensed matter physics.  Finally, thedy provided a unique opportunity for developing scientific presentation and writing skills.  All students participated in regular laboratory group as well as departmental meetings.  In addition, they also attended national and international conferences where they presented their work.  Moreover, they contributed to manuscript preparation and writing.

The principal investigator believes that professional development is a fundamental component of the training experience of graduate students.  For this reason, she has invested a lot of time, effort, and dedication towards this goal, and she has strived to provide a stimulating, positive, and constructive experience for all group members.  Specifically, the principal investigator and each group member initially identified his/her career goals and assessed the developmental needs to achieve these goals.  During subsequent monthly meetings, they discussed the progress made toward the identified goals.  Besides these formal meetings, the principal investigator had additional frequent informal discussions with group members on guidance, career development resources, and professional opportunities meant to strengthen a meaningful mentoring relationship. 

Society and the general public:

Students from middle schools and high schools in the surrounding Springfield and Ravenna school districts visited the principal investigator’s laboratory and learned about physics in general, and superconductivity and magnetism in particular, through demonstrations and short lectures given by the group members. In this way, the middle school and high school students were exposed to a research environment and were given a flavor of the science done in the lab and the technology involved in doing it.  We note that these school districts contain schools that have particular needs with respect to physical and life sciences instruction and that 52% and 63%, respectively, of the children served by these school districts are from families with incomes below the poverty line.  

 


Last Modified: 05/05/2021
Modified by: Carmen Almasan

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